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1.
The copreheat-treatment of non-fusible and slightly fusible coals with A240 and hydrogenated A240 under high temperature-short contact-time conditions around 500 °C has been examined in an attempt to produce a formed coke with better anisotropic development. These conditions shortened the copreheat-treatment time and provided better anisotropic development in the resultant coke after carbonization. Effectiveness of short contact-time has been discussed in terms of the extent of depolymerization of coal molecules suitable for anisotropic development, this being related to coal liquefaction under similar conditions. 相似文献
2.
The diffusional behavior of multi-arm star-shaped p(tBMA) was investigated in a concentration range from dilute to semidilute region with 1H pulsed field gradient spin-echo NMR (PFGSE-NMR). An 142-arm star-shaped p(tBMA) showed two diffusional mode, which reflected the coexistence of liquid ordering phase and liquid phase near the ordering transition. On the other hand, for star-shaped p(tBMA) with 55 arms showed a single diffusional relaxation in all concentration ranges during observation time. In the semidilute region, the relationship between the diffusion coefficient against the polymer concentration was affected strongly not only the arm number but also liquid ordering structure. 相似文献
3.
Mitsuo Miyazawa Tomohiko Takahashi Kazuki Sakata Isao Horibe 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2008,83(7):1006-1011
BACKGROUND: The biotransformation of sesquiterpenoids, which are a large class of naturally occurring compounds, using microorganisms as a biocatalyst to produce useful novel organic compounds was investigated. The biotransformation of sesquiterpenoids, (+)‐aromadendrene ( 1 ), (−)‐alloaromadendrene ( 2 ) and (+)‐ledene ( 3 ) has been investigated using Aspergillus wentii as a biocatalyst. Results: Compound 1 was converted to (−)‐(10S,11S)‐10,13,14‐trihydroxyaromadendrane ( 4 ). Compound 2 was converted to (+)‐(1S,11S)‐1,13‐dihydroxyaromadendrene ( 5 ) and (−)‐5,11‐epoxycadin‐1(10)‐en‐14‐ol ( 6 ). Compound 3 was converted to compound 6 , (+)‐(10R,11S)‐10,13‐dihydroxyaromadendr‐1‐ene ( 7 ) and (+)‐(10S,11S)‐10,13‐dihydroxyaromadendr‐1‐ene ( 8 ). The structure of the metabolic products has been elucidated on the basis of their spectral data. CONCLUSION: Compound 1 gave only one product that was hydroxylated at C‐10, C‐13 and C‐14. By contrast, compounds 2 and 3 gave a number of products, one of which was common. The differences in oxidation of 1–3 are due to the configuration of the C‐1 position. Compounds 4–8 were new compounds. Copyright © 2008 Society of Chemical Industry 相似文献
4.
Norihito Kijima Kenichi Morie Shoichi Nagata Isao Shimono 《Journal of Low Temperature Physics》1996,105(5-6):1511-1516
A strontium tantalum sulfide, SrTa2S5, has a hexagonal structure with lattice constants of a =3.32 and c=24.1 Å. With decreasing temperature the electrical resistivity decreases monotonically and exhibits an abrupt superconducting transition at 3.16 K (midpoint). The diamagnetic susceptibility is observed below Tc. The magnetic susceptibility is nearly independent of temperature above Tc and shows Pauli paramagnetism. 相似文献
5.
Evaluation of Slow Crack Growth Resistance in Ceramics for High-Temperature Applications 总被引:1,自引:0,他引:1
The slow (subcritical) crack growth (SCG) resistance of Si3 N4 and SiC ceramics has been evaluated by a stepwise loading test on bending bars precracked by Vickers indentation. Three highly refractory materials were selected for the evaluation: i.e., (1) high-purity Si3 N4 sintered by hot isostatic pressing (HIP) without additives and (2,3) α - and β - SiC pressureless sintered with B and C addition. Under the hypothesis of linear elastic behavior at high temperature, which was found satisfied in the present materials, the SCG resistance was expressed in terms of initial stress intensity factor critical for SCG failure within a predetermined lifetime. The present method was found useful in shortening the testing time and consistent with other traditional fatigue tests (e.g., static-fatigue test): It is recommended as a screening test for materials under research and development. Among the materials tested in the present study, the highest SCG resistance up to 1440°C was found in the high-purity Si3 N4 without additives. 相似文献
6.
Analysis of characteristic odors from human male axillae 总被引:7,自引:0,他引:7
Xiao -nong Zeng James J. Leyden Henry J. Lawley Kiyohito Sawano Isao Nohara George Preti 《Journal of chemical ecology》1991,17(7):1469-1492
A number of studies concerning the analysis of axillary odors have assumed that the characteristic odor produced in the axillae is due to volatile steroids and isovaleric acid. Organoleptic evaluation of Chromatographic eluants from axillary extracts was employed to isolate the region in the chromatogram where the characteristic odor eluted. The odor of the dissolved eluant was eliminated when it was treated with base, suggesting that acids make up the characteristic axillary odor. Subsequent extraction of the pH-adjusted axillary extract in conjunction with organoleptic evaluation of the Chromatographic eluant, preparative gas chromatography, and analysis by GC-MS as well as GC-FTIR showed the presence of a number of C6 to C11 straight-chain, branched, and unsaturated acids as important contributors to the axillary odor. The major odor component is (E)-3-methyl-2-hexenoic acid. Three homologous series of minor components are also important odor contributors; these consist of the terminally unsaturated acids, the 2-methyl-C6 to -C10 acids and the 4-ethyl-C5 to -C11 acids. These types of acids have not been reported previously as components of the human axillary secretions and have not been proposed previously as part of the principal odor components in this area. 相似文献
7.
Recent developments of high-performance NEOMAX magnets 总被引:6,自引:0,他引:6
For further improvement in achieving extremely high magnetic properties of Nd- Fe- B sintered magnets, extensive investigation
has been done to densify the magnet up to the theoretical value, to increase the volume fraction of the Nd
2Fe14B matrix phase, and to achieve a high degree of alignment. By controlling chemical composition and the amount of constituent
phases,improving particle size distribution, and adopting the isostatic pressing method to get better alignment of fine particles,
we have succeeded in obtaining a high-performance magnet having residual flux density (Br) of 1.495 T (14.95 kG), maximum energy product [(BH)max] of 431 kj/m3 (54.2 MGOe), and intrinsic coercivity (iHc) of 845 kA/m (10.62 kOe). 相似文献
8.
Takakazu Yamamoto Kouichi ShiraishiMahmut Abla Isao YamaguchiL.“Bert” Groenendaal 《Polymer》2002,43(3):711-719
Neutral and non-doped poly(3,4-ethylenedioxythiophene), PEDOTh(Ni), and its hexyl derivative, PEDOTh-C6(Ni), have been prepared by organometallic dehalogenation polycondensation of 2,5-dichloro-3,4-ethylenedioxythiophene and its hexyl derivative with a zerovalent nickel complex. PEDOTh-C6(Ni) was soluble in organic solvents and 1H NMR data indicated that it had an Mn of 11,000. MALDI-TOF mass analysis of PEDOTh(Ni) gave Mn and Mw of about 1700 and 2400, respectively. PEDOTh-C6(Ni) showed a UV-Vis absorption peak at 546 nm in CHCl3. Electrochemical oxidation of PEDOTh-C6(Ni) started at about −0.40 V vs Ag+/Ag and gave a peak at 0.20 V vs Ag+/Ag. Chemical and electrochemical oxidation (or p-doping) of PEDOTh-C6(Ni), both in solutions and in a solid state, led to weakening of the original π-π∗ peaks and rise of new peak(s) in a region of 800-1500 nm. The p-doping of PEDOTh-C6(Ni) caused not only a decrease in the intensity of 1H NMR signals of the bridging ethylene hydrogens but also a decrease in that of the hexyl side chain, suggesting a strong interaction of the p-dopant with the side chain. NMR data of poly(3-methoxythiophene-2,5-diyl) also supported an assumption that p-doping brings about a severe change in electronic state of the substituent attached to the polythiophene main chain. PEDOTh(Ni) had a density of 1.71 g cm−3; the molecular packing mode of PEDOTh(Ni) is discussed based on the density of the polymer and its XRD data. 相似文献
9.
XIII. Yeast sequencing reports. Cloning and sequencing of the NES24 gene of Saccharomyces cerevisiae
We have cloned NES24 using a temperature-sensitive nes24-1 mutant as a host and sequenced a 3162 bp XhoI-EcoRI DNA fragment containing the NES24 gene. Computer analysis revealed that this segment contains a 1806 bp open reading frame which is needed for complementation of the nes24-1 mutation. We found SUP8 in the region upstream of the NES24 gene, placing the NES24 gene on chromosome XIII. A protein homology search indicated that NES24 encodes a new protein. The disruption of the NES24 gene resulted in temperature-sensitive growth. The sequence has been deposited in DDBJ/EmBL/GenBank data bases under Accession Number D15052. 相似文献
10.
Ohba A. Ohbayashi S. Shiomi T. Takano S. Anami K. Honda H. Ishigaki Y. Hatanaka M. Nagao S. Kayano S. 《Solid-State Circuits, IEEE Journal of》1991,26(4):507-512
A 7-Mb BiCMOS ECL (emitter coupled logic) SRAM was fabricated in a 0.8 μm BiCMOS process. An improved buffer with a high-level output of nearly V CC is adopted to eliminate the DC current in the level converter circuit, and the PMOS transistor has a wide operating margin in the level converter. The configurable bit organization is realized by using a sense-amplifier switch circuit with no access degradation. A wired-OR demultiplexer for the ×1 output, having the same critical path as the ×4 output circuit, allows for the same access time between the two modes. The ×1 or ×4 mode is electrically selected by the external signal. A simplified programming redundancy technology, shift redundancy, is utilized. Address programming is performed by cutting only one fuse in the shift redundancy. The RAM operates at the ECL-10K level with an access time of 7 ns. and the power dissipation at 50 MHz is 600 mW for the × mode 相似文献