Sustainable ammonia production through process synthesis and global optimization

Current ammonia production technologies have a significant carbon footprint. In this study, we present a process synthesis and global optimization framework to discover the efficient utilization of renewable resources in ammonia production. Competing technologies are incorporated in a process superstructure where biomass, wind, and solar routes are compared with the natural gas-based reference case. A deterministic global optimization-based branch-and-bound algorithm is used to solve the resulting large-scale nonconvex mixed-integer nonlinear programming problem (MINLP). Case studies for Texas, California, and Iowa are conducted to examine the effects of different feedstock prices and availabilities. Results indicate that profitability of ammonia production is highly sensitive to feedstock and electricity prices, as well as greenhouse gas (GHG) restrictions. Under strict 75% GHG reductions, biomass to ammonia route is found to be competitive with natural gas route, whereas wind and solar to ammonia routes require further improvement to compete with those two routes. © 2018 American Institute of Chemical Engineers AIChE J, 65: e16498 2019     

Performance evaluation of a submerged membrane bioreactor for the treatment of brackish oil and natural gas field produced water

Produced water, which is co-produced during oil and gas manufacturing, represents one of the largest sources of oily wastewaters. Therefore, treatment of this produced water may improve the economic viability and lead to a new source of water for beneficial use. In this study a submerged hollow fiber membrane bioreactor (MBR) has been studied experimentally for the treatment of brackish oil and natural gas field produced water. This type of wastewater is also characterized with relatively moderate to high amount of salt, oil and total petroleum hydrocarbons (TPH). However, the bacteria which are growing in conventional activated sludge and MBR cannot survive at these strict conditions, therefore acclimation of the bacteria is of vital importance. The performance of the biological system, membrane permeability, the rate and extent of TPH biodegradability have been investigated under different sludge age and F/M ratios. The results obtained by gas chromatography analyses showed that the MBR system could be very effective in the removal of TPH from produced water and a significant improvement in the effluent quality was achieved.     

Effect of hybrid nanofluids mixture ratio on the performance of a photovoltaic thermal collector

Solar photovoltaic-thermal (PV/T) collectors, are hybrid collectors used to convert solar radiation into usable thermal and electrical energy. Recently, the field of research on PV/T is has focused on improving the efficiency of the PV/T collector by replacing the conventional heat transfer fluids (HTFs) with nanofluids. This article investigates the effect of hybrid nanofluids mixture ratio on the useful energy and overall efficiency of a PV/T collector operating with Al₂O₃-ZnO water nanofluid as the HTF. Experiments to measure the thermophysical properties of the hybrid nanofluids were conducted for various temperatures, volume concentrations, and mixture ratios, furthermore, accurate correlation models were proposed. Metrological data and energy output readings collected from the PV solar farm at Cyprus International University were used to validate our model. The study observed that at the optimum mixture ratio (0.47 of Al₂O₃ in the hybrid), the electrical, thermal, and exergy efficiencies of the PV/T collector are 13.8%, 55.9%, and 15.13% respectively. Also, the cell temperature drops by 21% when the mass flow rate is 0.1 kg/s as compared to when it is 0.01 kg/s. Finally, the study concludes that by using the Al₂O₃-ZnO hybrid nanofluid an overall peak thermal efficiency of 91% can be attained, and this represents a 34% enhancement in the collector's performance when compared to water.     

Unravel the potential of zinc oxide nanoparticle-carbonized sawdust matrix for removal of lead(Ⅱ) ions from aqueous solution

Zinc oxide nanoparticles(ZnOnp) are molecular nanoparticles synthesized by a chemical precipitation method from zinc nitrate tetrahydrate and sodium hydroxide.Carbonized sawdust(CSD) was prepared from sawdust obtained from a local wood mill.The matrix of both provides a better material as an adsorbent.The present study applied the functionality of ZnOnp,CSD,and ZnOnp-CSD matrix as adsorbent materials for the removal of Pb(Ⅱ) ions from aqueous solution.The method of batch process was employed to investigate the potential of the adsorbents.The influence of pH,contact time,initial concentration of adsorbate,the dosage of adsorbents,and the temperature of adsorbate-adsorbent mixture on the adsorption capacity were revealed.The adsorption isotherm studies indicate that both Freundlich and Langmuir isotherms were suitable to express the experimental data obtained with theoretical maximum adsorption capacities(q_m) of 70.42,87.72,and 92.59 mg·g~(-1) for the adsorption of Pb(Ⅱ) ions onto ZnOnp,CSD,and ZnOnp-CSD matrix,respectively.The separation factors(R_L) calculated showed that the use of the adsorbents for the removal of Pb(Ⅱ) ions is a feasible process with R_L 1.The thermodynamic parameters obtained revealed that the processes are endothermic,feasible,and spontaneous in nature at 25-50℃.Evaluation of the kinetic model elected that the processes agreed better with pseudo-second order where the values of rate constant(k_2) obtained for the adsorption of Pb(Ⅱ) ions onto ZnOnp,CSD,and ZnOnp-CSD matrix are 0.00149,0.00188,and 0.00315 g·mg~(-1)·min~(-1),respectively.The reusability potential examined for four cycles indicated that the adsorbents have better potential and economic value of reuse and the ZnOnp-CSD matrix indicates improved adsorbent material to remove Pb(Ⅱ) ions from aqueous solution.     

Influence of inulin and demineralised whey powder addition on the organic acid profiles of probiotic yoghurts

In this study, the effect of the different concentrations of inulin and demineralised whey (d‐whey) powder on the chemical characteristics and organic acid profiles of probiotic yoghurts were investigated. Analysis of chemical composition was performed on the first day, while pH and organic acid profiles were carried out during storage. The results indicated that different proportions of inulin and d‐whey powder significantly influenced the levels of the organic acids, produced while the duration of storage affected the orotic, pyruvic, citric, lactic and acetic acid levels. There was a direct relationship between the level of d‐whey powder and organic acid (except for butyric acid) concentration in the probiotic yoghurt.     

Determination of certain quality characteristics,thermal and sensory properties of ice creams produced with dried Besni grape (Vitis vinifera L.)

In this study, the effect of adding dried Besni grape (BG) at different concentrations on the physico‐chemical characteristics, colour values, total phenolic and flavonoid contents, glass transition (), melting (), freezing (T_f) and melting (T_m) point temperatures, and sensory properties of ice creams was investigated. Generally, the addition of BG caused a statistically significant (P < 0.01) increase in total solids, ash, fat, viscosity, first dripping times, complete melting times and a* colour values, while it decreased protein, pH, overrun, L*, b*, , , T_f and T_m values. The colour scores of ice cream samples showed a statistically significant increase (P < 0.05) with the increment of BG concentration, while the effects of BG addition on texture, resistance to melting, flavour, gumming structure and overall acceptability scores were not statistically significant.