Synthesis of Light Hydrocarbons from Biogas and Hydrogen: Investigation of a Fe-Mn-K/MgO Catalyst

Fischer-Tropsch synthesis of the CO₂ in biogas aims at producing light hydrocarbons and increasing its calorific value for feeding into the grid. Fe catalysts with Mn and K as promoters are supposed to yield high amounts of light hydrocarbons. Using a Fe-Mn-K/MgO catalyst, a parameter screening and long-term experiments were carried out. The catalyst shows, within the examined range, the highest selectivity to C₂–C₄ hydrocarbons at 450 °C, 8 bar(a), and a gas hourly space velocity of 350 h⁻¹. Calcination of the catalyst resulted in a significant drop of activity and an almost complete loss of selectivity to hydrocarbons. Admixture of steam to the reactant gas lowers the tendency to carbon deposition but also promotes the water-gas shift reaction and results in lower yields of hydrocarbons.     

In vivo occupancy of the striatal dopamine uptake complex by various inhibitors does not predict their effects on locomotion

We have recently found that allogenic bone marrow transplantation (BMT) can be used to treat lupus nephritis in NZB x NZW F1 (B/W F1) and BXSB mice. To elucidate why and how glomerular damage is repaired, serial renal biopsies were carried out using B/W F1 mice before, and after BMT. Donor-derived B cells and macrophages with normal functions developed two weeks after BMT, whereas donor-derived functional T cells were generated after seven weeks of BMT. Visceral epithelial cells as well as macrophages in the glomeruli were activated (probably by T cell-derived lymphokines) at this time; they showed marked phagocytic activity, resulting in clearance of immune complexes (ICs) and repair of damaged basement membranes. These results suggest that normal T cell functions, which have the capacity to activate macrophages and epithelial cells, are essential in repairing IC-mediated glomerular damage.     

Raman studies of structural rearrangements induced in human plasma lipoprotein carotenoids by malondialdehyde

Raman and resonance Raman spectra of plasma lipoproteins ± malondialdehyde were studied at concentrations which block the normal receptor-mediated uptake by cells. The strong resonance Raman bands at about 1010, 1162 and 1530 cm⁻¹, due to the presence of carotenoids in the lipoproteins, are envisaged as structural probes. High resolution resonance Raman spectra of the 1500–1600 cm⁻¹ region reveal multiple features suggesting the coexistence of several structural populations of β-carotene whose precise assignment is complex. When plasma lipoproteins are reacted with malondialdehyde, a complex change occurs in the resonance Raman banding of β-carotene in the 1500–1600 cm⁻¹ region. Malonaldehyde (MDA) also modifies the acoustical region (70–200 cm⁻¹ of low density lipoprotein (LDL) lipids. We suggest that malondialdehyde association with plasma lipoproteins alters the lipid structure via apoprotein or apoprotein/lipid associations.     

Mistracking in successive PCM/ADPCM transcoders

An analysis is presented of the causes of the accumulation of quantizing noise found in the transient state for successive CCITT adaptive differential pulse-code-modulation (ADPCM) transcoders connected synchronously. By decoupling the predictor and quantizer effect it is proved that, owing to a self-stabilization phenomenon, narrowband inputs cause local instabilities in the predictor of the jointly adaptive autoregressive moving-average-prediction/quantization used in the ADPCM 32-kb/s algorithm. Despite the assured global stability, these local instabilities are not synchronized at the encoder and its preceding decoder, and a mistracking occurs which creates quantizing noise accumulation. The tracking is then shown to be very sensitive to predictor/quantizer interaction. The discontinuities introduced in the standardized adaptive quantizer extend the mistracking problem to wideband inputs. A smoothed quantizer with reduced inauspicious interaction is proposed to remedy the problem     

Exploiting partial or complete geometrical symmetry in 3D symmetric Galerkin indirect BEM formulations

Procedures based on group representation theory, allowing the exploitation of geometrical symmetry in symmetric Galerkin BEM formulations, are investigated. In particular, this investigation is based on the weaker assumption of partial geometrical symmetry, where the boundary has two disconnected components, one of which is symmetric; e.g. this can be very useful for defect identification problems. The main development is expounded in the context of 3D Neumann elastostatic problems, considered as model problems; and then extended to SGBIE formulations for Dirichlet and/or scalar problems. Both Abelian and non‐Abelian finite symmetry groups are considered. The effectiveness of the present approach is demonstrated through numerical examples, where both partial and complete symmetry are considered, in connection with both Abelian and non‐Abelian symmetry groups. Copyright © 2003 John Wiley & Sons, Ltd.