Photoelastic Effects in Phosphate Glasses

The stress-optical coefficients of RO-Pz05 glasses (R = Mg, Ca, Sr, Ba, and Zn) were measured, and the photoelasticity mechanisms were analyzed based on the equation expressing the relation among the photoelastic constants, the elastic moduli, and the refractive index of glasses. No simple relation was found between the stress-optical coefficient and the elastic modulus, indicating that the factor (p – q), where p and q are the Neumann strain-optical coefficients, is important. The change of (p – q) with glass composition is governed mainly by changes in the effect of the atoms, rather than the lattice. The atomic effect increases with decreasing radius of the divalent cation, except for Zn²⁺. The ZnO-containing glasses exhibit extraordinarily large atomic effects. The photo-elasticity mechanism is discussed in relation to the nature of the chemical bonds.     

基于灰色神经网络的传感器分段标定

针对大量程高精度传感器不能一次完成标定实验的情况,提出一种将优化灰色GM(1,1)模型与BP神经网络相结合来预测分段标定过程中特征值缺失的方法,从而实现传感器的分段标定。首先,根据实验数据建立传统灰色GM(1,1)模型,对待标定传感器和标准传感器的测量值进行缺失数据的预测;然后,为弱化传统灰色GM(1,1)模型序列变化的幅度,提高模型的预测精度,利用中心逼近的思想对传统的GM（1,1）模型进行优化;最后,利用BP神经网络对优化的灰色GM(1,1)残差序列进行修正,以较高的精度实现对分段标定过程中缺失特征值的预测。结果表明,待标定传感器和标准传感器组合预测模型的平均残差分别为0.023%和0.401%,证明了组合预测模型的有效性。所提出方法为解决大量程高精度传感器分段标定时静态特性曲线的拟合提供了一种新思路。     

Compositional Trends in Photoelastic Constants of Borate Glasses

The stress-optical coefficients of binary and ternary borate glasses were measured and the factor ( p·q ), where p and q are the Neumann strain-optical coefficients, was determined. As a modifier oxide was added to B₂O₃ glass, the stress-optical coefficient decreased monotonically. It was found that the stress-optical coefficient is determined mainly by the elastic modulus, but the factor ( p·q ) becomes significant when the content and polarizability of the modifier cation are high. It was also found that the factor ( p·q ) decreases when the content and polarizability of the modifier cation increase. The ( p·q ) was divided into the lattice effect and the atomic effect, and their compositional dependences were discussed.     

食用油和脂防酸的介电特性

研究了食用油和脂肪酸的介电特性.油脂和脂肪酸的介电常数ε′在频率100Hz～500kHz之间显示了稳定性和最大值,从500kHz～1MHz显示了显著降低的趋势.脂肪酸的ε′随着双键的数量或分子链长度的增加而增加.油脂的ε′主要取决于C18不饱和脂肪酸的影响.结合偏最小二乘法(PLS)分析,介电分光图谱可以预测油脂中主要的脂肪酸成分.油脂的ε′随着温度增加而减少,随着水分含量的增加而增加.     

Photoelastic Effects in Silicate Glasses

The photoelasticity of R_nO_mSiO₂(R_nO_m=Li₂O, Na₂O, K₂O, and ZnO), Li₂O-Al₂O₃-SiO₂, Na₂O-Al₂O₃-SiO₂, and Na₂O-ZnO-SiO₂ glasses was analyzed on the basis of the following equation relating the stress-optical coefficient and the strain-optical coefficient:
where C is the stress-optical coefficient, n is the refractive index, G is the shear modulus, pI2and pI1are the Pockels strain-optical coefticients, and p and q are the Neumann strain-optical coefficients. No simple relation was found between the stress-optical coefficient and the shear modulus, and the factor (p−q) was found to be an essential factor deter- mining the stress-optical coefficient of silicate glasses. It was found that (p−q) decreases markedly with increasing content of modifier oxide, and that the change of (p − q) with composition is governed by the change of the atomic effect, while the lattice effect does not change as much. It is argued that the bridging oxygen with covalent bonds increases the atomic effect and the nonbridging oxygen with ionic bonds reduces the atomic effect.