硅酸盐水泥水化动力学模型与试验方法研究进展

水泥水化过程决定水泥基材料强度、耐久性等诸多性能，深入理解水泥水化机理具有重要的科学意义和工程价值。本工作回顾了硅酸盐水泥水化动力学模型的最新研究进展，评述了GEMS热力学计算、HymoStruc3D和CEMHY3D等水化数值模拟方法及其局限性，总结了准弹性中子散射和核磁共振等先进测试手段在研究水泥水化过程中水态演变和孔结构发展中的具体应用，提出了该领域未来研究的趋势和挑战。     

浅析提高煤质的意义及主要途径

针对商品煤质量在激烈的煤炭市场竞争中所处的重要地位，结合实际分析了提高煤质不仅关系到国民经济全局，影响着人们生活环境，还左右着煤炭企业自身的存在和可持续发展等问题。并立足现有的设施装备和科技水平，提出了提高煤质的基本途径。     

Rheological behaviors of fresh cement pastes with polycarboxylate superplasticizer

The rheologicalbehaviors of fresh cement paste with polycarboxylate superplasticizer were systematically investigated.Influentialfactors including superplasticizer to cement ratio(Sp/C),water to cement ratio(w/c),temperature,and time were discussed.Fresh cement pastes with Sp/Cs in the range of 0 to 2.0% and varied W/Cs from 0.25 to 0.5 were prepared and tested at 0,20 and 40 °C,respectively.Flowability and rheologicaltests on cement pastes were conducted to characterize the development of the rheologicalbehavior of fresh cement pastes over time.The exprimentalresults indicate that the initialflowability and flowability retention over shelf time increase with the growth in superplasticizer dosage due to the plasticizing effect and retardation effect of superplasticizer.Higher temperature usually leads to a sharper drop in initialflowability and flowability retention.However,for the cement paste with high Sp/C or w/c,the flowability is slightly affected by temperature.Yield stress and plastic viscosity show similar variation trends to the flowability under the abovementioned influentialfactors at low Sp/C.In the case of high Sp/C,yield stress and plastic viscosity start to decline over shelf time and the decreasing rate descends at elevated temperature.Moreover,two equations to roughly predict yield stress and plastic viscosity of the fresh cement pastes incorporating Sp/C,w/c,temperature and time are developed on the basis of the existing models,in which experimentalconstants can be extracted from a database created by the rheologicaltest results.     

Mechanical properties of silica aerogels prepared from a mixture of TEOS and organo-alkoxysilanes of type R1SiX3

Silica aerogels were prepared from a mixture of tetraethylorthosilicate and organo- alkoxysilanes. The effects of organo-alkoxysilanes on the mechanical properties of the silica aerogels were studied. The flexibility of silica aerogels was significantly improved by incorporation of organo-alkoxysilanes. When MTES and TEOS were combined as precursors of silica areogels, with the increased amount of MTES, the apparent elastic modulus and apparent compressive strength monotonously rose. At the same organo- alkoxysilanes to TEOS ratio, the size of alkyl groups of the organo-alkoxysilanes had little effect on the mechanical properties. In series of MTES and TEOS, the lowest elastic modulus of silica skeleton and the highest compressive strength of silica skeleton were observed at MTES to TEOS ratio of around 50：50. At a certain organo-alkoxysilanes to TEOS ratio, the elastic modulus of silica skeleton increased and the compressive strength of silica skeleton decreased with the size increase of the alkvl grouns.     

移动无线电业务需要更多的频谱

无线电与电子设备协会欧洲会议主席呼吁增加移动无线电业务的使用频率。他认为,无线频谱中的1000MHz频段应划分给移动无线电使用。他在一次马可尼基金费赞助的会议上问道:“我们为什么不能在世界范围内同意一项民远目标——把30～1000MHz的频谱只供移动无线电应用?”他还主张,固定通信业务应当让给有线或光纤通信,或者使用与移动无线通信频率无关的频率,这样可以保证移动无线电的优点能充分发挥。这位主席认为,这样做也许要花二十多年的时间。     

Sincgars-V系列电台的设计特点

美国国防部选中ITT公司的Sincgars—V系列电台作为美军新一代战术通信电台,ITT公司认为该产品中选的原因主要是:(1)具有适合现代战场通信所需的电子反对抗能力;(2)具备美军三军联合战术通信系统要求的系统配套能力;     

乳化沥青聚苯颗粒新型保温砂浆的研制

为降低成本以制备适用于乡村建筑节能的保温材料,对以廉价乳化沥青替代可再分乳胶粉制备保温砂浆的可行性进行了研究,并研究了乳化沥青聚苯颗粒保温砂浆的各项性能.结果表明,以乳化沥青部分或全部替代可再分散乳胶粉制备保温砂浆可行,且砂浆的干密度、体积稳定性和耐水性还有所改善.所研制的乳化沥青聚苯颗粒保温砂浆随着聚苯颗粒添加量的增大,干密度、抗压强度、压剪粘结强度和导热系数逐渐降低,线性收缩率和吸水率逐渐增大,而软化系数略有降低,除干密度和导热系数外各项性能均满足JG 158-2004标准对胶粉聚苯颗粒保温砂浆的要求.     

聚羧酸减水剂的研究进展

聚羧酸减水剂进一步发展,已经不仅仅是学术界的科学研究问题,也不仅仅是工程界的工程应用和经验性总结的问题,而是需要学术界和工程界共同提出问题、并从理论上解释其机理,最后从减水剂的分子设计合成、生产制备、工程应用提出普适性的解决措施,才能为聚羧酸减水剂的进一步发展打开一道大门.     

苯丙乳液改性砂浆的微观结构与性能(英文)

用2种具有不同性质的苯丙乳液来研究聚合物对砂浆各种性能的影响,测量了不同聚合物掺量下,聚合物改性砂浆的流动性及力学性能.通过测量砂浆凝结硬化过程中绝热温升来研究聚合物对砂浆中水泥水化过程的影响.用扫描电子显微镜观察了聚合物改性砂浆的微观结构.结果表明:由于聚合物成膜及其与水泥水化产物的相互作用.砂浆的力学性能得到显著改善.聚合物的性质不同,对砂浆性能的影响作用不同.环境扫描电子显微镜对新拌水泥浆的原位观察证实了乳液聚合物粒子在水泥颗粒上的迅速吸附,为解释聚合物对新拌砂浆流动性能的改善以及对水泥水化的延滞作用提供了直接证据.     

水泥-沥青胶凝材料动态力学行为的初步研究

研究了不同沥青含量（A/C）的水泥-沥青复合胶凝材料7d龄期的动态黏弹性力学行为。选择3种温度环境（？25℃、25℃和75℃）,采用动态黏弹谱仪测试了3种不同A/C的水泥-沥青胶凝材料（简称为CAB）在频率范围0.1Hz~100Hz的动态力学性能,获得了不同温度下储存模量、损耗模量及损耗角随加载频率变化的基本规律。基于...