The competitive behavior for O2 and CO2 reaction during char oxy-fuel combustion: effects of temperature and inherent minerals

Journal of Thermal Analysis and Calorimetry - Coal O2/CO2 combustion is a promising carbon capture and storage technology for coal-fired power plant. Char consumption rate prediction is essential...     

准各向同性高电流密度导体弯曲特性研究

提出了一种准各向同性高工程电流密度高温超导导体的有限元模型,利用该有限元模型计算了导体在不同弯曲半径下的应变分布以及临界电流衰减程度,并对导体样品进行了弯曲实验。实验结果和仿真结果基本一致,基于该有限元模型进一步计算了导体的不同参数对弯曲半径的影响。该研究为准各向同性高工程电流密度高温超导导体在聚变磁体领域的应用提供了参考依据。     

镧对Al-Sn-Bi牺牲阳极电化学性能的影响

通过恒电流法和失重法研究了加入La对Al-Sn-Bi阳极电化学性能的影响,对比分析了阳极的电化学溶解特征。结果表明:不同含量La对Al-Sn-Bi牺牲阳极的电位影响较小;电流效率比未加La的阳极有不同程度的提高,其中Al-Sn-Bi-0.1La的电流效率增幅较大;La可改善阳极的腐蚀形貌,使得表面溶解均匀,同时降低阳极腐蚀速率,提高其耐蚀性,其中含量0.1%La效果明显。     

BEHAVIOR AS t→∞ OF THE SOLUTIONS OF THE LINEAR SYSTEM OF ELASTIC THEORY ON NON－STAR－SHAPED EXTERIOR DOMAINS

（刘德辅）ＢＥＨＡＶＩＯＲＡＳｔ→∞ＯＦＴＨＥＳＯＬＵＴＩＯＮＳＯＦＴＨＥＬＩＮＥＡＲＳＹＳＴＥＭＯＦＥＬＡＳＴＩＣＴＨＥＯＲＹＯＮＮＯＮ－ＳＴＡＲ－ＳＨＡＰＥＤＥＸＴＥＲＩＯＲＤＯＭＡＩＮＳ￥ＬｉｕＤｅｆｕ（Ｄｅｐｔ．ｏｆＡｐｐｌＭａｔｈ．，Ｂｅｉ...     

大型对称不定箭形线性方程组的分解方法

1 引言 首先考虑2×2矩阵 显然当k>1/2时,矩阵K是对称正定的,且K可以分解成Cholesky因子:当k=1/2时,K为奇异矩阵;而当k<1/2时,K为对称不定矩阵,这时K有广义Cholesky分解式:并且这种分解是稳定的,一般地我们给出定义 定义1.1 设有矩阵K∈R~((m+n)×(m+n)),若总存在排列矩阵P∈R~((m+n)×(m+n))和对称正定矩阵H∈R~(m×n)、G∈R(m×m)使得则称矩阵K为对称拟定(Symmetric quasidefinite)矩阵。     

Heat and mass transfer characteristics of simulated high moisture flue gases

The heat transfer process occurring in a condensing heat exchanger where noncondensible gases are dominant in volume is different from the condensation heat transfer of the water vapor containing small amount of noncondensible gases. In the process the mass transfer due to the vapor condensation contributes an important part to the total heat transfer. In this paper, the Colburn-Hougen method is introduced to analyze the heat and mass transfer process when the water vapor entrained in a gas stream condenses into water on the tube wall. The major influential factors of the convective-condensation heat transfer coefficient are found as follows: the partial pressure of the vapor p _v , the temperature of the outer tube wall T _w , the mixture temperature T _g , Re and Pr. A new dimensionless number Ch, which is defined as condensation factor, has been proposed by dimensional analysis. In order to determine the relevant constants and investigate the convection-condensation heat and mass transfer characteristics of the condensing heat exchanger of a gas fired condensing boiler, a single row plain tube heat exchanger is designed, and experiments have been conducted with vapor-air mixture used to simulate flue gases. The experimental results show that the convection-condensation heat transfer coefficient is 1.52 times higher than that of the forced convection without condensation. Based on the experimental data, the normalized formula for convention-condensation heat transfer coefficient is obtained. A heat transfer area m² - Ch condensation factor - c _p specific heat at constant pressure, J/(kg·K) - G mass flux Kg/(m²·s) - h heat transfer coefficient W/(m²·K) - J J-factor - Nu Nusselt number - pa pressure - Pr Prandtl number - Q heat transfer rate - q heat flux W/m² - r latent heat, kJ/kg - Re Reynolds number - Sc Schmidt number - T temperature, C or K - heat conductivity m W/(m·K) - density, kg·m³ - g gas - h moistened hot air - i interface - v vapor - w water     

An investigation on near wall transport characteristics in an adiabatic upward gas–liquid two-phase slug flow

The near-wall transport characteristics, inclusive of mass transfer coefficient and wall shear stress, which have a great effect on gas–liquid two-phase flow induced internal corrosion of low alloy pipelines in vertical upward oil and gas mixing transport, have been both mechanistically and experimentally investigated in this paper. Based on the analyses on the hydrodynamic characteristics of an upward slug unit, the mass transfer in the near wall can be divided into four zones, Taylor bubble nose zone, falling liquid film zone, Taylor bubble wake zone and the remaining liquid slug zone; the wall shear stress can be divided into two zones, the positive wall shear stress zone associated with the falling liquid film and the negative wall shear stress zone associated with the liquid slug. Based on the conventional mass transfer and wall shear stress characteristics formulas of single phase liquid full-pipe turbulent flow, corrected normalized mass transfer coefficient formula and wall shear stress formula are proposed. The calculated results are in good agreement with the experimental data. The shear stress and the mass transfer coefficient in the near wall zone are increased with the increase of superficial gas velocity and decreased with the increase of superficial liquid velocity. The mass transfer coefficients in the falling liquid film zone and the wake zone of leading Taylor bubble are lager than those in the Taylor bubble nose zone and the remaining liquid slug zone, and the wall shear stress associated falling liquid film is larger than that associated the liquid slug. The mass transfer coefficient is within 10⁻³ m/s, and the wall shear stress below 10³ Pa. It can be concluded that the alternate wall shear stress due to upward gas–liquid slug flow is considered to be the major cause of the corrosion production film fatigue cracking.     

Effect of vapor condensation on forced convection heat transfer of moistened gas

The forced convection heat transfer with water vapor condensation is studied both theoretically and experimentally when wet flue gas passes downwards through a bank of horizontal tubes. Extraordinarily, discussions are concentrated on the effect of water vapor condensation on forced convection heat transfer. In the experiments, the air–steam mixture is used to simulate the flue gas of a natural gas fired boiler, and the vapor mass fraction ranges from 3.2 to 12.8%. By theoretical analysis, a new dimensionless number defined as augmentation factor is derived to account for the effect of condensation of relatively small amount of water vapor on convection heat transfer, and a consequent correlation is proposed based on the experimental data to describe the combined convection–condensation heat transfer. Good agreement can be found between the values of the Nusselt number obtained from the experiments and calculated by the correlation. The maximum deviation is within ±6%. The experimental results also shows that the convection–condensation heat transfer coefficient increases with Reynolds number and bulk vapor mass fraction, and is 1∼3.5 times that of the forced convection without condensation.     

N-(4-取代苯基-噻唑-2-基)香豆素类亚胺化合物的合成及抑菌活性研究

由含不同取代基的水杨醛与乙酰乙酸乙酯在哌啶存在下反应,得到乙酰基香豆素中间体,再与氨基硫脲缩合,得到含香豆素基的缩氨基硫脲化合物,继而与a-溴代芳基酮发生缩合反应,合成了9个未见报道的新的N-(4-取代苯基-噻唑-2-基)香豆素类亚胺化合物,其结构用IR,1HNMR和HRMS进行了确证,初步生物活性测定实验证明部分目标化合物具有良好的抑菌活性.     

Kinetics calculation on the shear viscosity in hot QEDat finite density

The shear viscosity of QED plasma at finite temperature and density is calculated by solving Boltzmann equation with variational approach. The result shows the small chemical potential enhances the viscosity in leading-log order by adding a chemical potential quadratic term to the viscosity for the pure temperature environment. Arrival of the final proofs: 25 November 2005 PACS: 52.25.Fi, 05.20.Dd, 11.10.Wx