白云鄂博矿区周围火成碳酸岩岩墙地质特征

首次填出白云鄂博矿区周围火成碳酸岩岩墙的分布图,深入系统地研究了岩墙的地质产状、主矿物类型、岩石结构、人工重砂矿物组成、稀土元素含量等特征。反映了白云鄂博矿区周围火成碳酸岩岩墙的岩浆演化分异过程存在差异。对于研究白云鄂博矿区铁与稀土的矿化提供了物质来源的证据。     

福建省海洋非法采砂行为管控初探

天然海砂是一种海洋矿产资源，由于在城市建设中使用十分广泛，海砂成为仅次于石油天然气的海洋第二大矿产资源。但近年来由于大量无度开采海砂，对海洋生态环境、海上航行安全以及建筑物安全都造成极大的破坏和影响。对此，各地执法部门进行了一系列打击非法采挖海砂专项行动，虽取得一定成效，但违法采挖海砂的猖獗势头依然未能得到遏制。文章从目前海砂市场的供求现状以及非法采挖海砂造成的问题出发，对执法部门打击非法采挖海砂未能取得预期效果的原因进行分析，并提出合理规划海砂合法开采、加大非法采砂惩处力度、合力完善治砂长效机制、用现代信息技术助力采砂监管等4个方面的解决思路，规范海洋采砂行为，使市场需求和环境保护得到兼顾。     

Scandium-Bearing Minerals in the Bayan Obo Nb-REE-Fe Deposit, Inner Mongolia, China

Aegirine, “perrierite‐(Ce)”, and ferrocolumbite, occurring in the Bayan Obo Nb‐REE‐Fe deposit in Inner Mongolia, China, contain appreciable amounts of scandium. The Sc₂O₃ content in aegirine (sample TS‐15) was 0.34–1.81 wt% (with one exceptionally high value of 3.45%) with an average value of 1.19%. The Sc₂O₃ content of “perrierite‐(Ce)” (TS‐20) was 2.82–3.64% with an average value of 3.26%. In the ferrocolumbite samples (TS‐16, TS‐23), the Sc₂O₃ content was 0.20–0.25% with an average value of 0.22% in sample TS‐16, and 0.56–1.04% with an average value of 0.67% in sample TS‐23. These data provide the basic information for future possible recovery of scandium as a by‐product from the deposit.     

黄河矿晶体结构的重新测定及空间群对称的讨论

黄河矿 BaCe(CO₃)₂F(a=0.5072(1)nm,c=3.846(1)nm;V=856.8×10^-3nm³;Z=6)晶体结构的重新测定,采用中心对称空间群 R3m-D_3d⁵,基于337个可观察的单晶 X 射线数据(I>2σ₁)和30个可变参数,R=0.031。原子坐标和均方根振幅(据各向异性位移参数计算,O.013-0.025nm)表明,没有必要降低对称性,即没有必要采用相应的非中心对称空间群或其它次群。黄河矿的结构中,原子形成似层状排列,且垂直于 c 轴;碳酸根通过 Ba 与 Ce 的联结形成三维结构。C(1)O₃,和 C(2)O₃,中的 C 原子偏离三个氧组成的平面,其偏离的距离分别为0.0066(15)nm 和 0.0029(15)nm。     

贵州二叠纪——三叠纪古气候和古海洋环境的地球化学研究

通过对贵州二叠纪和三叠纪地层沉积岩相、古生物组合、稀土元素、碳氧同位素和微量元素地球化学综合研究,发现贵州二叠纪、早一中三叠世和晚三叠世三个地质时期古气候和古海洋环境有明显差别。其中二叠纪为潮湿的热带海洋性气候,海水相对氧化,盐度正常,平均温度为53℃;早一中三叠世为干燥的大陆性气候,海水相对还原,盐度较高,平均温度为38℃;晚三叠世又转变为潮湿的气候,海水相对氧化,盐度正常,平均温度为44℃。,结合泛大陆演化特征,讨论了造成气候变化的原因。     

硬玉和透辉石的光吸收谱和颜色

本文报道若干天然硬玉和透辉石的光吸收谱,并在配位场分析的基础上讨论其致色原因。铁离子和铬离子均可使硬玉和透辉石呈现绿色。铬含量低但铁含量较高的样品(如Di-17)呈暗绿色。透辉石(Di-17)的偏振光吸收谱表明,这些样品的颜色与Fe~(2+)(M_1)→Fe~(3+)(M_1)荷移跃迁和配体→金属荷移跃迁密切相关。翠绿色样品含铬量相对地较高,其频色主要取决于Cr~(3+)离子在可见区内的自旋允许跃迁。红色和黄色硬玉的颜色与很强的配体→金属荷移吸收有关。     

Fe-rich Li-bearing magnesionigerite-6N6S from Xianghualing tin-polymetallic orefield, Hunan Province, P.R. China

The Fe-rich Li-bearing magnesionigerite-6N6S occurs in the Xianghualing tin-polymetallic ore field, Linwu County, Hunan Province, Peoples Republic of China. It was found near the outer contact zone of the Laizhiling granite body and in the Middle-Upper Devonian carbonate rocks of Qiziqiao Formation. The mineral formed during the skarn stage. Its empirical formula is Sn_1.81Li_0.67(Fe_1.43Zn_1.19 Mn_0.41)_Σ3.03(Al_14.89Mg_1.46 Ti_0.11Si_0.01)_Σ16.47O₃₀(OH)₂. The structure for magnesionigerite-6N6S was solved and refined in space group R-3?m, with a?=?5.7144(8), c?=?55.446(11) Å, V?=?1568.0(4) ų, to R1?=?0.0528. Based on the structural refinement of single crystal diffraction data the formula of magnesionigerite-6N6S is Sn_1.80Li_0.97(Fe_1.89Zn_0.91) _Σ2.80 (Al_14.60Mg_1.63 Ti_0.20)_Σ16.43O₃₀(OH)₂ with Z?=?3. Fe-rich Li-bearing magnesionigerite-6N6S contains 0.74 wt.% Li₂O. The idealized charge-balanced composition of magnesionigerite-6N6S may be expressed by bivalent and trivalent cations: (Mg²⁺)₄(Al³⁺)₁₈O₃₀(OH)₂. The simplified general formula for the 6N6S polysomes in the nigerite and högbomite groups can be given as A _x B_18-x O₃₀(OH)₂, x?=?~4, where A?=?Mg²⁺, Fe²⁺, Zn²⁺; B?=?Al³⁺, Sn⁴⁺, Ti⁴⁺, Li⁺, □.     

Erratum to: Hydrogen bonding in goldichite,KFe(SO4)2⋅4H2O: structure refinement

Mineralogy and Petrology -     

长江中游黄盖湖富营养化趋势分析及原因诊断

为评估黄盖湖富营养状况和变化趋势并诊断主要成因,以2015～2021年环境监测站点水质数据和2021年秋季的4次全湖加密监测数据为基础,采用综合营养状态指数（TLI（Σ））评价了黄盖湖富营养化程度及变化趋势,使用污染指数法评价了黄盖湖表层沉积物污染程度,基于沉积物与水体间氮磷的相关关系和入湖河流水质状况,初步推断了黄盖湖富营养化的主要原因。结果表明,2015 2021年黄盖湖TLI（Σ）依次为44.14、45.91、42.39、49.79、49.01、49.62和52.77,呈逐年升高的趋势,由中营养状态转变为轻度富营养状态,夏、秋季富营养化程度高于冬、春季;TLI(SD)、TLI(TN)和TLI(TP)贡献率分别为28%、18%和16%,营养盐浓度增加和透明度降低是黄盖湖水体富营养化的主要驱动因子。沉积物TP和TN平均含量分别为791和2691 mg/kg,为重度污染,有较高的释放风险。表层沉积物与表层水体之间TN相关性较弱,TP相关性较强,但受风速、水深等因素影响较大,湖面风速较高时浅水区域表层沉积物中P更容易释放至上覆水。入湖河流的外源输入以及风浪作用下沉积物再悬浮导致的营养盐浓...     

REE Geochemical Study of the Permian—Triassic Marine Sedimentary Environment in Guizhou Province

This paper deals with the REE geochemical characteristics of Permian-Triassic marine carbonate rocks in Guizhou Province.It is found that there are two broad categories of strati-graphic units in the region studied in accordance with their ΣREE contents and REE distribu-tion patterns: one is characterized by LREE enrichment and slight Ce depletion,with the REE distribution patterns similar to those of North American shales,and the other featrures relative HREE enrichment and relatively remarkable Ce depletion,with the REE distribution patterns close to those of pelagic sediments.In terms of their different ΣREE contents,five types of stratigraphic units can be distinguished.Incorporation of detrital minerals,REE complexing ca-pability,oxidation-reduction conditions of the media are the main factors affecting the REE com-position and REE distribution patterns of marine carbonate rocks in the region studied.In the light of REE geochemical characteristics of carbonate rocks,coupled with sedimentary facies analysis,this paper discusses the characteristics of the Permian-Triassic marine sedimentary environment in Guizhou Province and its evolutional rules.