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Summary ?The rare earth, major and trace element geochemistry of Jurassic deep marine manganese shales allow insight into their environment
of deposition. We present data of 24 samples from the Northern Calcareous Alps (Eastern Alps), collected from Late Jurassic
strata of the Tennengebirge and from Early Jurassic strata of the Karwendel Mts. Whereas major and trace element geochemistry
is controlled by the detrital input, rare earth element data and the relationship between total organic carbon and (pyritic)
sulfur can be used to constrain the origin of the manganese accumulation. The data of this study are compatible with a hydrogenous
precipitation of manganese by strongly varying redox-conditions at the sediment–water interface of a slope basin.
Received December 21, 2001; revised version accepted February 18, 2002 相似文献
3.
Toru?Iwata Keiko?Yoshikawa Katsutoshi?Nishimura Yoshihisa?Higuchi Takao?Yamashita Shigeru?Kato Eiji?OhtakiEmail author 《Journal of Oceanography》2004,60(6):995-1000
The measurements of the vertical transport of CO2 were carried out over the Sea of Japan using the specially designed pier of Kyoto University on September 20 to 22, 2000. CO2 fluxes were measured by the eddy correlation and aerodynamic techniques. Both techniques showed comparable CO2 fluxes during sea breeze conditions: −0.001 to −0.08 mg m−2s−1 with the mean of −0.05 mg m−2s−1. This means that the measuring site satisfies the fetch requirement for meteorological observations under sea breeze conditions. Moreover, the eddy diffusivity coefficient used in the aerodynamic technique is found to be consistent with the coefficient used in the eddy correlation technique. The present result leads us to conclude that the aerodynamic technique may be applicable to underway CO2 flux measurements over the ocean and may be used in place of the bulk technique. The important point is the need to maintain a measuring accuracy of CO2 concentration difference of the order of 0.1 ppmv on the research vessels or the buoys. 相似文献
4.
Scaling analysis of deposition from turbidity currents 总被引:3,自引:0,他引:3
Many oil-bearing sedimentary deposits are formed by the settling of particles from turbidity currents. Modeling sedimentary processes that form these turbidites enables the calculation of properties such as extent, depth, porosity and permeability of hydrocarbon-bearing reservoirs. This paper estimates the extent and thickness of turbidites from the initial conditions of the turbidity flow. This is achieved by the application of scaling analysis of the partial differential equations that govern the dynamics of and deposition from turbidity currents. We apply the results of scaling analysis to five modern submarine fans. The predicted and actual values of the dimensions of the fan deposits match well. We then compare the derived results against tabulated sizes of ancient turbidites. The comparisons are good as long as we correctly identify the flow regimes in which the deposition took place. The good agreements observed in the two cases show that the estimates obtained using scaling analysis can provide useful first-guess values for the dimensions of the deposits. 相似文献
5.
Takushi?NikiEmail author Taiki?Fujinaga Mariyo?F.?Watanabe Junji?Kinoshita 《Journal of Oceanography》2004,60(5):913-917
Solid-phase microextraction (SPME) is a simple, sensitive and less destructive method for the determination of dimethylsulfide
(DMS) in seawater. Combined with detection by gas chromatography-mass spectrometry (GC-MS), the method had sufficient sensitivity
(minimum detectable concentration of DMS was 0.05 nM), and practical levels of reproducibility (relative standard deviation
≤7%) and linearity (r
2 > 0.995) over a wide concentration range (0.5 to 910 nM). The protocol developed was applied to a Sagami Bay water sample
to determine concentrations of DMS and DMSP, and in situ DMSP-lyase activity. 相似文献
6.
Maik Grunwald Olaf Dellwig Gerd Liebezeit Bernhard Schnetger Rainer Reuter Hans-Jürgen Brumsack 《Marine Chemistry》2007
In autumn 2002 a time-series station was installed in the tidal inlet between the Islands of Langeoog and Spiekeroog (Southern North Sea, NW Germany) to continuously measure physical, chemical, and meteorological parameters, even during extreme weather conditions (gale-force storms, drifting ice). Inside the pole of the station sensor tubes are installed in direction of the prevailing tidal currents. The tubes are equipped with hydrographic sensors (pressure, temperature, conductivity) and allow retrieval of water for nutrient analysis by automated instruments located inside the pole. Dissolved methane and the nutrients ammonia, nitrite, nitrate, phosphate, and silicate are measured at the station. 相似文献
7.
A new extended Gibbs thermodynamic potential of seawater 总被引:1,自引:0,他引:1
Rainer Feistel 《Progress in Oceanography》2003,58(1):43-114
A new and extended Gibbs thermodynamic potential function of seawater is proposed to overcome generally known weaknesses of the International Equation of State of Seawater 1980 and its associated formulas (EOS80). It is valid for applied pressures up to 100 MPa (10,000 dbar), temperatures from −2-40°C, and practical salinities up to 42. At ambient pressure, it is applicable in heat capacity and density up to salinity 50. It includes the triple point of water for reference and is, over its range of validity, fully consistent with the current 1995 international scientific pure water standard, IAPWS95. In conjunction with an improved Gibbs potential of ice, it provides freezing temperatures of seawater for pressures up to 50 MPa (5000 dbar). It is compiled from an extensive set of experimental seawater data, rather than being derived from EOS80 equations. Older seawater data were specifically recalibrated for compatibility with the recent pure water standard. By this procedure, experimental high-pressure densities proved consistent with sound speeds confirmed by deep-sea travel time measurements. Temperatures of maximum density are described within their experimental uncertainty. For very low salinities, Debye-Hückel limiting laws are recompiled using latest physical and chemical constants. The potential function is expressed in the 1990 International Temperature Scale ITS-90. 相似文献
8.
Márian Urban Rainer Thomas Vratislav Hurai Patrik Koneèný Martin Chovan 《Mineralium Deposita》2006,40(8):867-873
CO2 inclusions with density up to 1,197 kg m−3 occur in quartz–stibnite veins hosted in the low-grade Palaeozoic basement of the Gemericum tectonic unit in the Western Carpathians. Raman microanalysis corroborated CO2 as dominant gas species accompanied by small amounts of nitrogen (<7.3 mol%) and methane (<2.5 mol%). The superdense CO2 phase exsolved from an aqueous bulk fluid at temperatures of 183–237°C and pressures between 1.6 and 3.5 kbar, possibly up to 4.5 kbar. Low thermal gradients (∼12–13°C km−1) and the CO2–CH4–N2 fluid composition rule out a genetic link with the subjacent Permian granites and indicate an external, either metamorphogenic (oxidation of siderite, dedolomitization) or lower crustal/mantle, source of the ore-forming fluids.According to microprobe U–Pb–Th dating of monazite, the stibnite-bearing veins formed during early Cretaceous thrusting of the Gemeric basement over the adjacent Veporic unit. The 15- to 18-km depth of burial estimated from the fluid inclusion trapping PT parameters indicates a 8- to 11-km-thick Upper Palaeozoic–Jurassic accretionary complex overlying the Gemeric basement and its Permo-Triassic autochthonous cover. 相似文献
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