Geochemical Characteristics,Origin, and Evolution of Ore‐Forming Fluids of the Khut Copper Skarn Deposit,West of Yazd in Central Iran

The Khut copper skarn deposit is located at about 50 km northwest of Taft City in Yazd province in the middle part of the Urumieh‐Dokhtar magmatic arc. Intrusion of granitoid of Oligocene–Miocene age into carbonate rocks of the Triassic Nayband Formation led to the formation of marble and a calcic skarn. The marble contains high grade Cu mineralization that occurs mainly as open space filling and replacement. Cu‐rich sulfide samples from the mineralized marble are also anomalous in Au, Zn, and Pb. In contrast, the calcic skarn is only weakly anomalous in Cu and W. The calcic skarn is divided into garnet skarn and garnet–pyroxene skarn zones. Paragenetic relationships and microthermometric data from fluid inclusions in garnet and calcite indicate that the compositional evolution of skarn minerals occurred in three main stages as follows. (i) The early prograde stage, which is characterized by Mg‐rich hedenbergite (Hd_53.7Di_42.3–Hd_86.1Di_9.5) with Al‐bearing andradite (69.8–99.5 mol% andradite). The temperature in the early prograde skarn varies from 400 to 500°C at 500 bar. (ii) The late prograde stage is manifested by almost pure andradite (96.2–98.4 mol% andradite). Based on the fluid inclusion data from garnet, fluid temperature and salinity in this stage is estimated to vary from 267 to 361°C and from 10.1 to 21.1 wt% NaCl equivalent, respectively. Pyrrhotite precipitation started during this stage. (iii) The retrograde stage occurs in an exoskarn, which consists of an assemblage of ferro‐actinolite, quartz, calcite, epidote, chlorite, sphalerite, pyrite, and chalcopyrite that partially replaces earlier mineral assemblages under hydrostatic conditions during fracturing of the early skarn. Fluids in calcite yielded lower temperatures (T < 260°C) and fluid salinity declined to ～8 wt% NaCl equivalent. The last stage mineralization in the deposit is supergene weathering/alteration represented by the formation of iron hydroxide, Cu‐carbonate, clay minerals, and calcite. Sulfur isotope data of chalcopyrite (δ³⁴S of +1.4 to +5.2‰) show an igneous sulfur source. Mineralogy and mineral compositions of the prograde assemblage of the Khut skarn are consistent with deposition under intermediately oxidized and slightly lower fS₂ conditions at shallow crustal levels compared with those of other typical Fe‐bearing Cu–Au skarn systems.     

Chemical composition of rock-forming minerals in gold-related granitoid intrusions,southwestern New Brunswick,Canada: implications for crystallization conditions,volatile exsolution,and fluorine-chlorine activity

Chemical composition of rock-forming minerals in Appalachian Siluro-Devonian granitoid intrusions, southwestern New Brunswick, was systematically determined by electron microprobe. The mineral chemical data together with petrographic examination was used to test magmatic equilibration and to constrain crystallization conditions, volatile exsolution, and fluorine-chlorine activity of fluids associated with these intrusions. Mineralogical distinction between Late Silurian to Early Devonian granodioritic to monzogranitic series (GMS) and Late Devonian granitic series (GS) rocks is evident, although both are subsolvus I-type to evolved I-type granitoids. Oxidized to reduced GMS rocks consist of quartz, plagioclase (An>10), K-feldspar, biotite, apatite, titanite, zircon, monazite, ± hornblende, ± pyroxene, ± magnetite, ± ilmenite, and ± sulfide. GS rocks comprise quartz, K-feldspar, plagioclase (An<10), mica group minerals, zircon, monazite, apatite, sulfide, ± ilmente, ± magnetite, ± topaz, ± columbite, and ± xenotime. Inter-intrusion and intra-intrusion variations in mineral chemistry are interpreted to reflect petrogenetic processes (e.g., assimilation and fractional crystallization) during granitoid evolution. Although magmatic equilibration among rock-forming minerals are disturbed by subsolidus hydrothermal processes, GMS rocks appear to have higher magmatic temperatures, variable levels of emplacement, a range of (i.e., reduced intrusions 10^−16.7∼10^−13.4 and oxidized intrusions 10^−14.0∼10^−10.5 bars), and relatively low f _HF/f _HCl ratios (10^−3.0∼10^−1.0) in exsolved fluids, compared to GS rocks. Reduced GMS intrusions bear higher gold potential and thus may be prospective targets for intrusion-related gold systems. Electronic Supplementary Material Supplementary material is available for this article at     

The Miduk porphyry Cu deposit,Kerman, Iran: A geochemical analysis of the potassic zone including halogen element systematics related to Cu mineralization processes

Miduk hypogene and supergene porphyry Cu–Mo mineralization occurs within the Miocene porphyritic quartz–diorite and host Eocene plagioclase–hornblende phyric andesitic pyroclastic and flow sequence. Both the host rocks were extensively altered by hydrothermal fluids to dominantly potassic, phyllic, and argillic with interstitial to distal propylitic types.     

Felsic magmatic phases and the role of late-stage aplitic dykes in the formation of the world-class Cantung Tungsten skarn deposit, Northwest Territories, Canada

A field and petro-chemical classification of felsic magmatic phases (FMPs) at the world-class Cantung W skarn deposit was undertaken to document the evolution of magmatism and the relationships between different FMPs, metasomatism, and mineralization. Early FMPs include moderately differentiated (Zr/Hf = 18–26, Ti/Zr = 14–15) biotite monzogranitic plutons and early biotite-rich granitic dykes, and compositionally similar quartz–feldspar porphyry dykes. Late, highly fractionated (Zr/Hf = 8–17, Ti/Zr = 3–13) FMPs sourced from a deeper monzogranitic intrusion include: (1) leucocratic biotite- or tourmaline-bearing dykes derived from localized entrapments of residual magma; and, (2) sub-vertical NE-trending aplitic dykes derived from a larger segregation of residual fluid- and incompatible element-enriched magma. The aplitic dykes have textures, morphologies, spatial associations, and a pervasive calcic metasomatic mineral assemblage (Ca-plagioclase + quartz or clinozoisite) indicative of syn-mineralization emplacement. Very late-stage overpressuring and initiation of sub-vertical fractures into the overlying plutonic carapace and country rocks by supercritical magmatic fluid led to an interaction with calcareous country rocks that resulted in an increased aCa²⁺ in the fluid and the concurrent precipitation of W skarn. Residual magma also ascended with, and quenched in equilibrium with the magmatic fluid to from the aplitic dykes, then was metasomatized by the fluid as it interacted with calcareous country rocks. Overall, highly fractionated and moderately to very highly undercooled FMPs at Cantung provide evidence for a large and evolving felsic magmatic system at depth that segregated and maintained a stable fluid- and incompatible element-enriched residual magma until the latest stages of crystallization. The detailed study of FMPs associated with magmatic-hydrothermal mineral deposits allow us to refine our understanding of these mineralizing systems and better define metallogenic and exploration models for intrusion-related mineralization.     

UNIQUE ASPECTS OF MODELING IRRIGATI0N-INDUCED SOIL EROSION

llNTRODUCTIONIrrigationisimp0rtanttof00dpr0ducti0nthr0ughoutthew0rld.Irrigati0nisused0naboutl5theworld'scropland(KendalIandPimentel,l994)and5%ofthew0rld'sfoodproductionland,whichincludesrangelandandpermanentcr0pland(FAO,l998).However,irrigatedlandproducesmorethan30%ofthew0rld'sf0od(Tribe,1994),whichis2l/2timesasmuchperunitareacomparedt0n0n-irrigatedproducti0n(KendallandPimentel,1994).IntheUnitedStates,approximatelyl5theharvestedcr0plandisirrigated,butalmost40thet0talcr0pvalue…     

Porphyry to epithermal transition in the Agua Rica polymetallic deposit, Catamarca, Argentina: An integrated petrologic analysis of ore and alteration parageneses

Agua Rica (27°26′S–66°16′O) is a world class Cu–Au–Mo deposit located in Catamarca, Argentina. In the E–W 6969400 section examined, the Seca Norte and the Trampeadero porphyries that have intruded the metasedimentary rock are cut by interfingered igneous and hydrothermal heterolithic and monolithic breccias, and sandy dikes. Relic biotite and K-feldspar of the early potassic alteration (370° to > 550 °C) with Cu (Mo–Au) mineralization are locally preserved and encapsulated in a widespread, white mica + quartz + rutile or anatase halo (phyllic alteration) with pyrite + covellite that suggests fluids with temperatures ≤ 360 °C and high f(S₂). The Trampeadero porphyry and the surrounding metasedimentary rock with phyllic alteration have molybdenite in stringers and B-type quartz veinlets and the highest Mo grades (> 1000 ppm).Multistage advanced argillic alteration overprinted the earlier stages. Early andalusite ± pyrite ± quartz is preserved in the roots of the argillic halo rimmed by an alumina–silica material and white micas. This alteration assemblage is considered to have been formed at temperatures ≥ 375 °C from condensed magmatic vapor. At higher levels, pyrophyllite replaces muscovite and illite in clasts of hydrothermal breccias in the center and east sector of the study section, suggesting temperatures of 280 to 360 °C. Clasts of vuggy silica in the uppermost levels of the central breccia, indicates that at lower temperatures (< 250 °C), fluids reached very low pH (pH < 2). In this early stage of the advanced argillic alteration, hydrothermal fluids seem to have not precipitated sulfides or sulfosalts.Hydrothermal brecciation was concurrent with fluid exsolution (↑? V), which precipitated intermediate-temperature advanced argillic alunite (svanbergite + woodhouseite) ± diaspore ± zunyite as breccia cement along with abundant covellite + pyrite + enargite ± native sulfur ± kuramite at intermediate depths and in lateral transitional zones to unbrecciated rocks. This mineral assemblage indicates temperatures near 300 °C, oxidized and silica-undersaturated hydrothermal fluids with high sulfur fugacity to prevent gold precipitation. Multiple generations of pyrite, emplectite, colusite, Pb- and Bi-bearing sulfosalts, and native sulfur with Au and Ag, accompanied by alunite introduction in the upper level breccias, probably occurred at lower temperatures, but still high sulfur and oxygen activity. An independent Zn and Pb (as galena) mineralization stage locally coincides with Au–Ag and sulfosalts, and advanced at depth, controlled by fractures and overprinting much of the previous mineralization. A later paragenesis of veinlets of alunite + woodhouseite + svanvergite + pyrite ± enargite that cut the phyllic halo suggests temperatures ~ 250 °C and without woodhouseite + svanvergite, temperatures ~ 200 °C. Kaolinite occurs in the phyllic halo as a late mineral in clots and in veinlets thus, in this zone, the fluid had cooled enough for its formation.     

Mineralogy and geochemistry of Nb-, Ta-, Sn-, U-, Th-, and Zr-bearing granitic rocks from Abu Rusheid shear zones,South Eastern Desert,Egypt

Granite-hosted,Nb-,Ta-,Sn-,U-,Th-,and Zr(Hf)-bearing mineralization from the Abu Rusheid shear zones occurs about 97 km southwest of the town of Marsa Alam,South Eastern Desert,Egypt.The SSE-trending brittle-ductile Abu Rusheid shear zones crosscut the peralkalic granitic gneisses and cataclastic to mylonitic rocks(mylonite,protomlyonite,and ultramylonite).The northern shear zone varies in width from 1 to 3 m with a strike length of >500 m,and the southern shear zone is 0.5 to 8 m wide and >1 km long.These shear zones locally host less altered lamprophyre and locally sheared granitic aplite-pegmatite dykes.The rare-metal minerals,identified from the peralkalic granitic gneisses and cataclastic to mylonitic rocks are associated with muscovite,chlorite,quartz,fluorite,pyrite,magnetite,and rare biotite that are restricted to the Abu Rusheid shear zones;these are columbite-tantalite and pyrochlore(var.betafite) in the northern shear zone and ferrocolumbite in the southern shear zone.Cassiterite occurs as inclusions in the columbite-tantalite minerals.U-and Th-minerals(uraninite,thorite,uranothorite,ishikawaite,and cheralite) and Hf-rich zircon coexist.Magmatic(?) zircon contains numerous inclusions of rutile,fluorite,U-Th and REE minerals,such as uranothorite,cheralite,monazite,and xenotime.Compositional variations in Ta/(Ta+Nb) and Mn/(Mn+Fe) in columbite range from 0.07-0.42 and 0.04-0.33,respectively,and Hf contents in zircon from 1.92-6.46 of the two mineralized shear zones reflect the extreme degree of magmatic fractionation.Four samples of peralkalic granitic gneisses and cataclastic to mylonitic rocks from the southern shear zone have very low TiO2(0.02 wt%-0.04 wt%),Sr [(15-20)×10-6],and Ba [(47-78)×10-6],with high Fe2O3T(0.94 wt%-1.99 wt%),CaO(0.14 wt%-1.16 wt%),alkalis(9.2 wt%-10.1 wt%),Rb [(369-805)×10-6],Zr [(1033-2261)×10-6],Nb [(371-913)×10-6],U [(51-108)×10-6],Th [(36-110)×10-6],Ta [(38-108)×10-6],Pb [(39-364)×10-6],Zn [(21-424)×10-6],Y [(8-304)×10-6],Hf [(29-157)×10-6],and ∑REE [(64-304)×10-6],especially HREE [(46-167)×10-6].Three samples from the northern shear zone also have very low TiO2(0.03 wt%),Sr [(11-16)×10-6],and Ba [(38-47)×10-6],with high Fe2O3T(1.97 wt%-2.91 wt%),CaO(0.49 wt%-1.01 wt%),alkalis(7.2 wt%-8.3 wt%),Rb [(932-978)×10-6],Zr [(1707-1953)×10-6],Nb [(853-981)×10-6],Ta [(100-112)×10-6],U [(120-752)×10-6],Th [(121-164)×10-6],Pb [(260-2198)×10-6],Zn [(483-1140)×10-6],Y [(8-304)×10-6],Hf [(67-106)×10-6],and ∑REE [(110-231)×10-6],especially HREE [(91-177)×10-6].The very high Rb/Sr(57.5-88.9),and low Zr/Hf(16.9-25.6),Nb/Ta(7.7-9.8),and Th/U(0.21-1.01) are consistent with very frac-tionated fluorine-bearing granitic rocks that were altered and sheared.The field evidence,textural relations,and compositions of the ore minerals suggest that the main mineralizing event was magmatic(629+/-5 Ma,CHIME monazite),with later hydrothermal alteration and local remobilization of the high-field-strength elements.     

Martian meteorite Dhofar 019: A new shergottite

Abstract— Dhofar 019 is a new martian meteorite found in the desert of Oman. In texture, mineralogy, and major and trace element chemistry, this meteorite is classified as a basaltic shergottite. Olivine megacrysts are set within a groundmass composed of finer grained olivine, pyroxene (pigeonite and augite), and maskelynite. Minor phases are chromite‐ulvöspinel, ilmenite, silica, K‐rich feldspar, merrillite, chlorapatite, and pyrrhotite. Secondary phases of terrestrial origin include calcite, gypsum, celestite, Fe hydroxides, and smectite. Dhofar 019 is most similar to the Elephant Moraine (EETA) 79001 lithology A and Dar al Gani (DaG) 476/489 shergottites. The main features that distinguish Dhofar 019 from other shergottites are lack of orthopyroxene; lower Ni contents of olivine; the heaviest oxygen‐isotopic bulk composition; and larger compositional ranges for olivine, maskelynite, and spinel, as well as a wide range for pyroxenes. The large compositional ranges of the minerals are indicative of relatively rapid crystallization. Modeling of olivine chemical zonations yield minimum cooling rates of 0.5‐0.8 °C/h. Spinel chemistry suggests that crystallization took place under one of the most reduced conditions for martian meteorites, at an fO₂ 3 log units below the quartz‐fayalite‐magnetite (QFM) buffer. The olivine megacrysts are heterogeneously distributed in the rock. Crystal size distribution analysis suggests that they constitute a population formed under steady‐state conditions of nucleation and growth, although a few grains may be cumulates. The parent melt is thought to have been derived from partial melting of a light rare earth element‐ and platinum group element‐depleted mantle source. Shergottites, EETA79001 lithology A, DaG 476/489, and Dhofar 019, although of different ages, comprise a particular type of martian rocks. Such rocks could have formed from chemically similar source(s) and parent melt(s), with their bulk compositions affected by olivine accumulation.     

Characteristics of Mineralizing Fluids of the Darreh‐Zerreshk and Ali‐Abad Porphyry Copper Deposits,Central Iran,Determined by Fluid Inclusion Microthermometry

The Darreh‐Zereshk (DZ) and Ali‐Abad (AB) porphyry copper deposits are located in southwest of the Yazd city, central Iran. These deposits occur in granitoid intrusions, ranging in composition from quartz monzodiorite through granodiorite to granite. The ore‐hosting intrusions exhibit intense hydrofracturing that lead to the formation of quartz‐sulfide veinlets. Fluid inclusions in hydrothermal quartz in these deposits are classified as a mono‐phase vapor type (Type I), liquid‐rich two phase (liquid + vapor) type (Type IIA), vapor‐rich two phase (vapor + liquid) type (Type IIB), and multi‐phase (liquid + vapor + halite + sylvite + hematite + chalcopyrite and pyrite) type (Types III). Homogenization temperatures (Th) and salinity data are presented for fluid inclusions from hydrothermal quartz veinlets associated with potassic alteration and other varieties of hypogene mineralization. Ore precipitation occurred between 150° to >600°C from low to very high salinity (1.1–73.9 wt% NaCl equivalent) aqueous fluids. Two stages of hydrothermal activity characterized are recognized; one which shows relatively high Th and lower salinity fluid (Type IIIa; Th_(L‐V) > Tm_(NaCl)); and one which shows lower Th and higher salinity (Type IIIb; Th_(L‐V) < Tm_(NaCl)). The high Th_(L‐V) and salinities of Type IIIa inclusions are interpreted to represent the initial existence of a dense fluid of magmatic origin. The coexistence of Type IIIb, Type I and Type IIB fluid inclusions suggest that these inclusions resulted either from trapping of boiling fluids and/or represent two immiscible fluids. These processes probably occurred as the result of pressure fluctuations from lithostatic to hydrostatic conditions under a pressure of 200 to 300 bar. Dilution of these early fluids by meteoritic water resulted in lower temperatures and low to moderate salinity (<20 wt% NaCl equiv.) fluids (Type IIA). Fluid inclusion analysis reveals that the hydrothermal fluid, which formed mineralized quartz veinlets in the rocks with potassic alteration, had temperatures of ～500°C and salinity ～50 wt% NaCl equiv. Cryogenic SEM‐EDS analyses of frozen and decrepitated ore‐bearing fluids trapped in the inclusions indicate the fluids were dominated with NaCl, and KCl with minor CaCl₂.