The Reproductive Cycle of Ophioderma brevispinum (Echinodermata: Ophiuroidea)

Abstract. .The reproductive cycle of the brittlestar Ophioderma brevispinum is described using histological and organ index data for a population in Massachusetts, U.S.A. The cycle consists of a one month mid-summer spawning phase followed by gametogenesis and gradual gonadal growth during the winter, and greatly accelerated gonadal growth from May to June. At the end of the spawning season, oogonia proliferate near the base of the ovary, and a continuous layer of spermatogonia lines the testis. As oocytes grow to a maximum diameter of 350 um, yolk granules accumulate and the cytoplasm becomes less basophilic. Prior to spawning, the testis becomes branched and sulcate, and a whorl of spermatozoa produced by columns of spermatids accumulates in the lumen. Comparisons between the reproductive cycles of different populations of O. brevispinum and its congeners support the hypothesis that temperature may be a critical exogenous factor, but definitely not the only factor, in the initiation and duration of the growth and spawning phases of the ophiuroid reproductive cycle.     

Anaerobic diagenesis within Recent, Pleistocene, and Eocene marine carbonate frameworks

Porewaters from a variety of Recent, Pleistocene, and Eocene lithified marine carbonate frameworks displayed similar chemical characteristics: highly depleted concentrations of dissolved oxygen (>20 μM), elevated levels of dissolved methane (25-5000 nM), and near-seawater sulphate levels. These porewaters also had low pH values (7·5-7·9), and contained elevated concentrations of sulphide (4–10 μM), dissolved inorganic carbon (2·05–2·46 mM), and inorganic nutrients. Hydrocarbon composition data indicate that the methane is biogenic, whereas the methane δ¹³C values (–47·4 ± 2·7%0) suggest that it has been subject to oxidation. The porewater dissolved inorganic carbon δ¹³C values varied from –0·6 to –39%0, suggesting input of carbon dioxide from organic matter oxidation. We conclude that anaerobic diagenesis involving bacterial degradation of organic matter is a common process in lithified marine carbonates and hypothesize that it may be an important factor controlling their carbonate geochemistry.     

The diagenesis of the late Dinantian Derbyshire-East Midland carbonate shelf, central England

Carbonate cements in late Dinantian (Asbian and Brigantian) limestones of the Derbyshire carbonate platform record a diagenetic history starting with early vadose meteoric cementation and finishing with burial and localized mineral and oil emplacement. The sequence is documented using cement petrography, cathodoluminescence, trace element geochemistry and C and O isotopes. The earliest cements (Pre-Zone 1) are locally developed non-luminescent brown sparry calcite below intrastratal palaeokarsts and calcretes. They contain negligible Fe, Mn and Sr but up to 1000 ppm Mg. Their isotopic compositions centre around δ¹⁸O =?8.5‰, δ¹³C=?5.0‰. Calcretes contain less ¹³C. Subsequent cements are widespread as inclusion-free, low-Mg, low-Fe crinoid overgrowths and are described as having a‘dead-bright-dull’cathodoluminescence. The‘dead’cements (Zone 1) are mostly non-luminescent but contain dissolution hiatuses overlain by finely detailed bright subzones that correlate over several kilometres. Across‘dead'/bright subzones there is a clear trend in Mg (500–900 ppm), Mn (100–450 ppm) and Fe (80-230 ppm). Zone 1 cements have isotopic compositions centred around δ¹⁸O =?8.0‰ and δ¹³C=?2.5‰. Zone 2 cement is bright, thin and complexly subzoned. It is geochemically similar to bright subzones of Zone 1 cements. Dull Zone 3 cement pre-dates pressure dissolution and fills 70% or more of the pore space. It generally contains little Mn, Fe and Sr but can have more than 1000 ppm Mg, increasing stratigraphically upwards. The δ¹⁸O compositions range from ?5.5 to ?15‰ and the δ¹³C range is ?1 to + 3.2^0/00. Zone 4 fills veins and stylolite seams in addition to pores. It is synchronous with Pb, Ba, F ore mineralization and oil migration. Zone 4 is ferroan with around 500 ppm Fe, up to 2500 ppm Mg and up to 1500 ppm Mn. Isotopic compositions range widely; δ¹⁵O =?2.7 to ?9‰ and δ¹³C=?3.8 to+2.50‰. Unaltered marine brachiopods suggest a Dinantian seawater composition around δ¹⁵O = 0‰ (SMOW), but vital isotopic effects probably mask the original δ¹³C (PDB) value. Pre-Zone 1 calcites are meteoric vadose cements with light soil-derived δ¹³C and light meteoric δ¹⁸O. An unusually fractionated‘pluvial’δ¹⁵O(SMOW) value of around — 6‰ is indicated for local Dinantian meteoric water. Calcrete δ¹⁸O values are heavier through evaporation. Zone 1 textures and geochemistry indicate a meteoric phreatic environment. Fe and Mn trends in the bright subzones indicate stagnation, and precipitation occurred in increments from widespread cyclically developed shallow meteoric water bodies. Meteoric alteration of the rock body was pervasive by the end of Zone 1 with a general resetting of isotopic values. Zone 3 is volumetrically important and external sources of water and carbonate are required. Emplacement was during the Namurian-early Westphalian by meteoric water sourced at a karst landscape on the uplifted eastern edge of the Derbyshire-East Midland shelf. The light δ¹⁸O values mainly reflect burial temperatures and an unusually high local heat flow, but an input of highly fractionated hinterland-derived meteoric water at the unconformity is also likely. Relatively heavy δ¹³C values reflect the less-altered state of the source carbonate and aquifer. Zone 4 is partly vein fed and spans burial down to 2000 m and the onset of tectonism. Light organic-matter-derived δ¹³C and heavy δ¹⁸O values suggest basin-derived formation water. Combined with textural evidence of geopressures, this relates to local high-temperature ore mineralization and oil migration. Low water-to-rock ratios with host-rock buffering probably affected the final isotopic compositions of Zone 4, masking extremes both of temperature and organic-matter-derived CO₂.     

The application of cathodoluminescence to interpreting the diagenesis of an ancient calcrete profile

A laterally extensive calcrete profile has been identified in the Late Asbian (Lower Carboniferous) shallow marine shelf limestones of the Llangollen area, North Wales. The upper surface of the profile is defined by a laterally discontinuous palaeokarstic surface and by laminated calcareous crusts which developed within the underlying limestone. The profile contains a unique series of early pore-filling vadose cements which only occur down to 1 m below the palaeokarstic surface. Cathodoluminescence reveals that these cements pre-date the late pore-filling meteoric phreatic cements which occur throughout local Asbian lithologies. A spar cement stratigraphy has been established for the calcrete profile. Subaerial vadose cements comprise two generations of non-luminescent cement, followed by a brightly luminescent generation which occasionally shows an acicular habit. This needle-fibre calcite represents the final stage of vadose cementation. Precipitation of vadose cements was contemporary with subaerial alteration and micritization of the limestone. Textures, visible only with cathodoluminescence, provide evidence of recurrent periods of fabric dissolution. The most extensive phase of dissolution occurred immediately after the precipitation of the non-luminescent subaerial vadose cements. Several different textures have been recorded, each reflecting the morphology of a partially dissolved substrate. Dissolution textures are generally confined to the walls of the larger pores and to early brecciation fractures. These probably acted as fluid pathways in the calcrete during early subaerial diagenesis. Much of the non-marine micrite in the calcrete profile appears as needle-fibre calcite under cathodoluminescence. This acicular calcite was probably formed in response to localized supersaturation of meteoric pore fluids caused by periods of near-surface evaporation. Since needle-fibre luminescence is strongly variable, these ambient conditions are not believed to have directly controlled the activator ion concentrations of cementing pore waters. Needle-fibre calcite is considered to be a cement precipitate which has almost completely recrystallized to micrite, probably during the late stages of subaerial diagenesis. Two generations of subaerial micrite which define a ‘micrite stratigraphy’, have been distinguished under cathodoluminescence. Reconstructing the diagenetic history of this ancient calcrete profile has revealed that subaerial alteration was multistaged, with many diagenetic processes acting simultaneously during a single phase of emergence.     

Polyphase erosion of subaerial omission surfaces in the Late Dinantian of Anglesey, North Wales

The Lower Carboniferous of Anglesey consists of bioclastic carbonates and subsidiary terrigenous siliciclastics built as a cyclic succession against the northern flank of the contemporary Welsh landmass. Cycle boundaries are marked by subaerial erosive features that are unlike the normal Late Dinantian palaeokarst association, and one such surface, at Red Wharf Bay, shows remarkable evidence of polyphase erosion indicating at least three distinct periods of karstification and one of fluvial channelling. Each erosive period was succeeded by an interval of lithification during which newly arrived siliciclastic sediment was stabilized. Diagenetic textures in the underlying limestones reveal no evidence of this complex surface history, and seen in cathodoluminescence the earliest pore filling cements evidently post-date the entire emergent episode. The karsts occupy positions adjacent to channels and are attributable to overbank flooding rather than atmospheric weathering. Autocyclic mechanisms may be responsible for the polyphase development but the overall control of sedimentary cyclicity is considered to have been eustatic.     

Micro-zircon: origin and evolution during metamorphism

The size and distribution of zircon within a garnet-mica-schist from the Scottish Highlands were assessed using scanning electron microscopy. The study reveals that abundant 0.2–3.0 μm sized zircon is preferentially concentrated within garnet and biotite porphyroblasts. The micro-zircon has grown during regional metamorphism and represents >90% of the total number of zircon in the schist. It is texturally distinct from a few larger detrital zircon grains in the schist that commonly preserve evidence of dissolution, and more rarely, small metamorphic outgrowths. The sequential incorporation of zircon in porphyroblasts allows prograde changes in the morphology of the zircon population to be identified. Zircon is reactive and soluble, and responds to medium-grade metamorphism in a series of dissolution and crystallization events, linked to possible changes in fluid composition. Deformation also has a significant influence on the distribution of zircon, allowing inclusions previously trapped within biotite to react. About 8 × 10⁶ micro-zircon occur as inclusions within a typical individual 5-mm garnet porphyroblast and their presence must be considered prior to trace-element or isotopic analysis of such metamorphic phases.     

VARIABILITY IN THE CHEMICAL COMPOSITION OF IN SITU SUBGLACIAL MELTWATERS

Meltwaters collected from boreholes drilled to the base of the Haut Glacier d'Arolla, Switzerland have chemical compositions that can be classified into three main groups. The first group is dilute, whereas the second group is similar to, though generally less concentrated in major ions, than contemporaneous bulk glacial runoff. The third group is more concentrated than any observed bulk runoff, including periods of flow recession. Waters of the first group are believed to represent supraglacial meltwater and ice melted during drilling. Limited solutes may be derived from interactions with debris in the borehole. The spatial pattern of borehole water levels and borehole water column stratification, combined with the chemical composition of the different groups, suggest that the second group represent samples of subglacial waters that exchange with channel water on a diurnal basis, and that the third group represent samples of water draining through a ‘distributed’ subglacial hydraulic system. High NO⁻₃ concentrations in the third group suggest that snowmelt may provide a significant proportion of the waters and that the residence time of the waters at the bed in this particular section of the distributed system is of the order of a few months. The high NO⁻₃ concentrations also suggest that some snowmelt is routed along different subglacial flowpaths to those used by icemelt. The average SO²⁻₄: (HCO⁻₃ + SO²⁻₄) ratio of the third group of meltwaters is 0.3, suggesting that sulphide oxidation and carbonate dissolution (which gives rise to a ratio of 0.5) cannot provide all the HCO⁻₃ to solution. Hence, carbonate hydrolysis may be occurring before sulphide oxidation, or there may be subglacial sources of CO₂, perhaps arising from microbial oxidation of organic C in bedrock, air bubbles in glacier ice or pockets of air trapped in subglacial cavities. The channel marginal zone is identified as an area that may influence the composition of bulk meltwater during periods of recession flow and low diurnal discharge regimes. © 1997 by John Wiley & Sons, Ltd.     

Pn波的形成及其衰减特征——对加拿大地盾的研究

尽管P_n波品质因子（P_nQ）对上地幔流变性质研究及核试验监测有着深刻含义,迄今它仍然是一个难以准确测定的地震参量.这是因为除了众所周知的影响所有短周期Q的干扰因素外,在所有主要的区域震相中,地震工作者对P_n波的传播模式及几何扩散函数G=d^-k中的扩散率指数k了解最少.不同的研究者任意地假定不同的常数k,因此常算出非常不同的P_nQ值（例如文献[1]、[2]）.实际上,理论研究已表明,k随频率而变,变化的形式取决于上地幔的速度结构.本文介绍用一推广的逆向双台法同时测定加拿大东部的P_nQ和k值.我们的结果表明:1.加拿大东部的P_n波是由一系列的干涉潜波叠加而形成;2.视P_nQ（散射和固有非弹性的综合效应）随频率而增加,在15Hz处接近2000.