Non‐equilibrium concepts lead to a unified explanation of the formation of chondrules and chondrites

Abstract— Calculations of the formation of seven types of chondrules in Semarkona from a gas of solar composition were performed with the FACT computer program to predict the chemistries of oxides (including silicates), developed by the authors and their colleagues. The constrained equilibrium theory was used in the calculations with two nucleation constraints suggested by nucleation theory. The first constraint was the blocking of Fe and other metal gaseous atoms from condensing to form solids or liquids because of very high surface free energies and high surface tensions of the solid and liquid metals, respectively. The second constraint was the blocking of the condensation of solids and the formation of metastable liquid oxides (including silicates) well below their liquidus temperatures. Our laboratory experiments suggested subcooling of type IIA chondrule compositions of 400 degrees or more below the liquidus temperature. The blocking of iron leads to a supersaturation of Fe atoms, so that the partial pressure of Fe (p_Fe) is larger than the partial pressure at equilibrium (p_Fe(eq)). The supersaturation ratio S = p_Fe/p_Fe(eq) becomes larger than 1 and increases rapidly with a decrease in temperature. This drives the reaction Fe + H₂O ? H₂ + FeO to the right. With S = 100, the activity of FeO in the liquid droplet is 100 times as large as the value at equilibrium. The FeO activities are a function of temperature and provide relative average temperatures of the crystallization of chondrules. Our calculations for the LL3.0 chondrite Semarkona and our study of some non‐equilibrium effects lead to accurate representations of the compositions of chondrules of types IA, IAB, IB, IIA, IIAB, IIB, and CC. Our concepts readily explain both the variety of FeO concentrations in the different chondrule types and the entire process of chondrule formation. Our theory is unified and could possibly explain the formation of chondrules in all chondritic meteorites as well as provide a simple explanation for the complex chemistries of chondrites, and especially for type 3 chondrites.     

Line-of-sight magnetic flux imbalances caused by electric currents

Several physical and observational effects may contribute to the significant imbalances of magnetic flux that are often observed in active regions. We consider an effect not previously treated: the influence of electric currents in the photosphere. Electric currents can cause a line-of-sight flux imbalance because of the directionality of the magnetic field they produce. Currents associated with magnetic flux tubes produce larger imbalances than do smoothly-varying distributions of flux and current. We estimate the magnitude of this effect for current densities, total currents, and magnetic geometry consistent with observations. The expected imbalances lie approximately in the range 0–15%, depending on the character of the current-carrying fields and the angle from which they are viewed. Observationally, current-induced flux imbalances could be indicated by a statistical dependence of the imbalance on angular distance from disk center. A general study of magnetic flux balance in active regions is needed to determine the relative importance of other - probably larger -effects such as dilute flux (too weak to measure or rendered invisible by radiative transfer effects), merging with weak background fields, and long-range connections between active regions.Operated for the National Science Foundation by the Association of Universities for Research in Astronomy.     

Observation and preliminary analysis of a recent Jovian satellite phenomenon

The occultation of Io by Ganymede as observed on 10 June 1985 is reported. The middle of the occultation minimum was found to occur at 14h 14m 5.7s UT. In the plane perpendicular to the line of sight the centres of the two satellite disks passed to within ~ 2530 km of each other, at a relative velocity, in this plane, of about 11 kms^–1. The values of these last two quantities, however, depend on what assumptions are made about the light distribution over io's disk.     

The intracluster iron distribution around 4C+55.16

We report on the metal distribution in the intracluster medium around the radio galaxy 4C+55.16     observed with the Chandra X-ray Observatory . The radial metallicity profile shows a dramatic change at 10 arcsec (∼50 kpc) in radius from half solar to twice solar at inner radii. Also found was a plume-like feature located at ∼3 arcsec to the south-west of the centre of the galaxy, which is mostly accounted for by a strong enhancement of iron L emission. The X-ray spectrum of the plume is characterized by the metal abundance pattern of Type Ia supernovae (SNeIa), i.e. large ratios of Fe to α elements, with the iron metallicity being unusually high at     solar (90 per cent error). How the plume has been formed is not entirely clear. The inhomogeneous iron distribution suggested in this cluster provides important clues to understanding the metal enrichment process of the cluster medium.     

Coulometric TCO2 analyses for marine studies; an introduction

Progress in the introduction of coulometry for the analysis of total carbon dioxide (TCO₂) in marine waters is described. An extractor—stripper removes CO₂ that is measured coulometrically by the quantity of electricity (coulombs) used to electrogenerate OH^? ions for the titration of the acid formed by the reaction of CO₂ and ethanolamine. The equivalence point is detected photometrically with thymolphthalein as the indicator, and Faraday's Law relates coulombs to equivalents of titrant generated and CO₂ determined so that there are no standard curves needed or titrants to standardize or store. Accuracy was determined by adding gelatin capsules containing 100–1500 μg C of pure CaCO₃ into the stripper, and accuracies of better than ± 1 μg C were achieved. The best precision for natural seawater (± 1 standard error) of ± 0.5 μmol l^?1 was found for 17 samples of Bermuda coastal waters having a mean TCO₂ of 2007.2 μmol l^?1 (0.05% CV). Sources of error and precautions are discussed. This method, which has been used successfully at sea, can be used to study a variety of marine phenomena involving TCO₂.     

Cosmological constraints from the X-ray gas mass fraction in relaxed lensing clusters observed with Chandra

We present precise measurements of the X-ray gas mass fraction for a sample of luminous, relatively relaxed clusters of galaxies observed with the Chandra observatory, for which independent confirmation of the mass results is available from gravitational lensing studies. Parametrizing the total (luminous plus dark matter) mass profiles using the model of Navarro, Frenk & White, we show that the X-ray gas mass fractions in the clusters asymptote towards an approximately constant value at a radius r ₂₅₀₀, where the mean interior density is 2500 times the critical density of the Universe at the redshifts of the clusters. Combining the Chandra results on the X-ray gas mass fraction and its apparent redshift dependence with recent measurements of the mean baryonic matter density in the Universe and the Hubble constant determined from the Hubble Key Project, we obtain a tight constraint on the mean total matter density of the Universe,     , and measure a positive cosmological constant,     . Our results are in good agreement with recent, independent findings based on analyses of anisotropies in the cosmic microwave background radiation, the properties of distant supernovae, and the large-scale distribution of galaxies.     

Cosmological constraints from Chandra X-ray observations of galaxy clusters

Chandra X-ray observations of rich, dynamically relaxed galaxy clusters allow the properties of the X-ray gas and the total gravitating mass to be determined precisely. Here, we discuss how Chandra observations may be used as a powerful tool for cosmological studies. By combining Chandra X-ray results on the X-ray gas mass fractions in clusters with independent measurements of the Hubble constant and the mean baryonic matter density of the universe, we obtain a tight constraint on the mean total matter density of the universe, Ο_m, and an interesting constraint on the cosmological constant, Ο_Λ. Using these results, together with the observed local X-ray luminosity function of the most X-ray luminous galaxy clusters, a mass-luminosity relation determined from Chandra and ROSAT X-ray data and weak gravitational lensing observations, and the mass function predicted by numerical simulations, we obtain a precise constraint on the normalization of the power spectrum of density fluctuations in the nearby universe,σ₈. We compare our results with those obtained from other, independent methods. This revised version was published online in July 2006 with corrections to the Cover Date.     

The Atacama Cosmology Telescope

The proposed Atacama Cosmology Telescope (ACT) project is described. This multi-institution collaboration aims to produce arcminute-resolution and micro-Kelvin sensitivity maps of the microwave background temperature over 200 square degree of the sky in three frequency bands. We give a brief overview of the scientific motivations for such a map, followed by a design outline of our 6-m custom telescope, an overview of our proposed bolometer array detector technology, and site considerations and scan strategy. We also describe associated optical and X-ray galaxy cluster surveys.     

Magma sources for Mesozoic anorogenic granites of the White Mountain magma series,New England,USA

The magma sources for granitic intrusions related to the Mesozoic White Mountain magma series in northern New England, USA, are addressed relying principally upon Nd isotopes. Many of these anorogenic complexes lack significant volumes of exposed mafic lithologies and have been suspected of representing crustal melts. Sm–Nd and Rb–Sr isotope systematics are used to evaluate magma sources for 18 felsic plutons with ages ranging from about 120 to 230 Ma. The possibility of crustal sources is further examined with analyses of representative older crust including Paleozoic granitoids which serve as probes of the lower crust in the region. Multiple samples from two representative intrusions are used to address intrapluton initial isotopic heterogeneities and document significant yet restricted variations (<1 in _Nd). Overall, Mesozoic granite plutons range in _Nd [T] from +4.2 to -2.3, with most +2 to 0, and in initial ⁸⁷Sr/⁸⁶Sr from 0.7031 to 0.709. The isotopic variations are roughly inversely correlated but are not obviously related to geologic, geographic, or age differences. Older igneous and metamorphic crust of the region has much lower Nd isotope ratios with the most radiogenic Paleozoic granitoid at _Nd [180 Ma] of -2.8. These data suggest mid-Proterozoic separation of the crust in central northern New England. Moreover, the bulk of the Mesozoic granites cannot be explained as crustal melts but must have large mantle components. The ranges of Nd and Sr isotopes are attributed to incorporation of crust by magmas derived from midly depleted mantle sources. Crustal input may reflect either magma mixing of crustal and mantle melts or crustal assimilation which is the favored interpretation. The results indicate production of anorogenic granites from mantle-derived mafic magmas.