Kinetics of two-step anionic polymerization

This article deals with the kinetics of two-step anionic polymerization by way of a non-steady state method. Several molecular parameters can be evaluated using the formulae developed. A bimodal molecular weight distribution function for the resulting polymer is derived from the set of kinetic differential equations, which is in agreement with the experimental data reported.     

Structure and composition of guanidine acrylate, guanidine methacrylate, their homopolymers, and copolymers with diallyldimethylammonium chloride

Structures and compositions of the monomers guanidine acrylate and guanidine methacrylate, their homopolymers, and copolymers with diallyldimethylammonium chloride enriched in acrylate comonomer units were determined. It was shown that ampholytic copolymers, owing to their ionic nature, contained comonomeric guanidine acrylate or methacrylate units and diallyldimethylammonium chloride units, as well as the acrylate comonomer with the diallyl counterion and polymeric acrylate and diallyl ion pairs. It follows from IR and ¹H NMR data that guanidine methacrylate has the same structure (with two hydrogen bonds) in the solid state and in solutions. Guanidine acrylate structures in the solid state and in dimethylsulfoxide are identical and analogous to guanidine methacrylate structure in this solvent. In water, the guanidine acrylate structure has another type of hydrogen bonding (with one hydrogen bond, where the proton is shifted toward the guanidine group). These features of hydrogen bonding of guanidine acrylate and guanidine methacrylate are also retained in their homopolymers and copolymers with diallyldimethylammonium chloride. It was shown that the thermal stability of the copolymers was higher than that of their homopolymers, confirming the formation of intramolecular ion pairs of oppositely charged units of ampholytic copolymers. Moreover, the thermal stability of guanidine methacrylate-diallyldimethylammonium chloride copolymers is higher than that of guanidine acrylate-diallyldimethylammonium chloride copolymers.     

Permeation of Zidovudine and Probenecid from Oily Bases Containing Alcohols Through Rat Skin

Permeation of zidovudine (3'-azido-3'-deoxythymidine, AZT) and probenecid from oily bases containing an alcohol through rat skin was examined. Isopropyl myristate (IPM), as an oily vehicle, showed a penetration enhancing effect for AZT and probenecid. Ethanol, n-propanol, and n-butanol were used as additives in IPM and were examined for their own permeation and the enhancing effect on the permeation of AZT and probenecid. The skin permeation of AZT and probenecid from IPM was enhanced by addition of the alcohol in IPM. The degree of the enhancement was decreased with increasing lipophilicity of the alcohol used. me permeation rate of the drug from those systems was shown to be governed by penetration-enhancing effects of the oily base and alcohol, and the penetration of the alcohol itself through the skin.     

Modeling Power Supply Noise in Delay Testing

Excessive power supply noise during test can cause overkill. This article discusses two models for supply noise in delay testing and their application to test compaction. The proposed noise models avoid complicated power network analysis, making them much faster than existing power noise analysis tools. can cause performance degradation and     

Hydrogen reduction kinetics of electrometallurgical slime

The interaction of hydrogen with the zinc-containing electrometallurgical slime of the Severstal’ metallurgical works has been studied. The sequence of transformations in the slime heated to 1100°C in hydrogen or air has been established. The experimental and calculated weight losses coincide. Some of the carbonates are shown to decompose in the temperature range 300–700°C, and most iron and zinc oxides are reduced to a metal. In the temperature range 650–850°C, zinc is almost completely sublimated. At temperatures above 800°C, complex oxides are reduced and calcium and magnesium carbonates and sulfates are likely to decompose. Experimental digital data on the zinc sublimation rate are processed by the least squares method with approximating equations used in thermal analysis. The kinetics of nonisothermal zinc sublimation is comprehensively analyzed using a unique procedure developed for taking into account the background of a peak and the effect of accompanying processes. An equation for the calculation of the zinc sublimation rate under experimental conditions (fluidized bed) is given and tested.     

Thin-film nickel coatings on fiber materials

Vacuum deposition of thin films onto fiber materials is a promising method of obtaining electromagnetic screens. We have studied the structure and the electromagnetic properties of machine-knitted fabric coated with nickel by means of magnetron sputtering. When the fabric is irradiated from the metal-coated side, the reflection coefficient is higher by a factor of 1.4 as compared to the case when the same source of electromagnetic radiation is situated on the opposite side (facing the uncoated surface), while the absorption coefficient in both cases is the same.     

Single-Threaded vs. Multithreaded: Where Should We Focus?

Today, with the increasing popularity of multicore processors, one approach to optimizing the processor's performance is to reduce the execution times of individual applications running on each core by designing and implementing more powerful cores. Another approach, which is the polar opposite of the first, optimizes the processor's performance by running a larger number of applications on a correspondingly larger number of cores, albeit simpler ones. The difference between these two approaches is that the former focuses on reducing the latency of individual applications or threads (it optimizes the processor's single-threaded performance), whereas the latter focuses on reducing the latency of the applications' threads taken as a group (it optimizes the processor's multithreaded performance). The panel, from the 2007 Workshop on Computer Architecture Research Directions, discusses the relevant issues.     

Occlusion-resistant camera design for acquiring active environments.

In this article, we present a detailed theoretical analysis and a prototype implementation of a family of cameras designed with the explicit goal of detecting and removing interfering dynamic occluders in real time, during live capture, as opposed to fixing the resulting artifacts a posteriori. Such an early-acquisition approach improves efficiency: more valid samples are acquired faster without worrying about moving occluders. One option for designing a camera to be unaffected by moving occluders is to sample through the occluder, but true x-ray-like vision is technically impractical. Another option is to sample around the occluder using a camera with a large effective aperture, but such an approach requires a bulky acquisition device. Yet another possibility of sampling around an occluder is to rely on second and higher order reflected rays that indirectly sample surfaces not directly visible. However, devising an acquisition device sufficiently sensitive and efficient to capture large environments using reflected rays will remain challenging for the foreseeable future.     

Simultaneous a posteriori detection and identification of a predetermined number of quasi-periodic fragments in a sequence based on their segments

An a posteriori (off-line) approach to the simultaneous detection and identification of quasi-periodic fragments in a numerical sequence using their segments is analyzed. The solution of the problem is proposed for the case when the number of the desired fragments is known. The following assumptions are made. (i) Each desired fragment of the numerical sequence coincides with an element of the given alphabet of the reference sequences that have equal lengths (i.e., number of elements). (ii) Only a segment (part) of the desired fragment can be processed; unprocessable parts of the fragment are interpreted as lost data. (iii) The numbers of the elements in the sequence that correspond to the beginning of the desired fragment and the boundaries of the segment in the fragment represent deterministic (rather than random) quantities; the boundaries of the segments are different for different fragments; and the desired fragments are quasi-periodic in the sequence. (iv) Gaussian uncorrelated noise impedes the observation of the sequence that contains quasi-periodic segments of the reference sequences. It is demonstrated that the essence of the problem under study lies in the verification of a set of hypotheses on the mean value of a random Gaussian vector (the power of this set exponentially increases with an increase in the dimension of the vector—the sequence length). An effective a posteriori algorithm that provides for maximum-likelihood detection and identification is validated. The estimates of the time and space complexity are related to the parameters of the problem. The results of the numerical simulation are presented. This work was supported by the Russian Foundation for Basic Research, project no. 03-01-00036 and 06-01-00058. Aleksandr V. Kel’manov. Born April 25, 1952. Graduated from Izhevsk State Technical University in 1974. Received candidate’s degree in 1980 and doctoral degree in 1994. Leading researcher of the Sobolev Institute of Mathematics, Siberian Division, Russian Academy of Sciences. Scientific interests: mathematical methods for pattern recognition; discrete optimization; effective algorithms for the analysis and recognition of random sequences; algorithms for the solution of applied problems; and methods and algorithms for the processing, recognition, and synthesis of voice signals. Author of more than 120 papers. Sergei A. Khamidullin. Born March 28, 1952. Graduated from Novosibirsk State University in 1974. Received candidate’s degree in 1997. Senior researcher of the Sobolev Institute of Mathematics, Siberian Division, Russian Academy of Sciences. Scientific interests: mathematical methods for pattern recognition; discrete optimization; effective algorithms for the analysis and recognition of random sequences; algorithms for the solution of applied problems; and methods and algorithms for the processing, recognition, and synthesis of voice signals. Author of more than 80 papers.     

Effect of pulse duration and size of interelectrode interval on electric-spark spraying. I. Effect of pulse duration and size of interelectrode interval on rate of electric-spark transfer

The influence exerted by electric-spark spraying on the kinetics of mass transfer and the physicomechanical properties of coatings is investigated. It is shown that electric-spark spraying is determined by the dynamic properties of the cathode jets, which depend on the electrical parameters of the spark discharge, the size of the interelectrode interval, and the physical properties of the coatings, which vary during spraying.