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冲击法测螺线管磁场实验的改进 总被引:1,自引:0,他引:1
冲击法测螺线管磁场实验的改进韩字璞,师善雨(河北师范学院物理系石家庄050091)影响冲击法测螺线管轴向磁感应强度实验精度的因素很多,其主要。素。脉冲电。作用时间的长短,其次是电路中各线圈位置的摆放及其他等.如何减小和消除这些因素的影响,提高测量准确... 相似文献
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The syntheses of chirai calix[4]arene derivatives bearing amino acid residue at the lower rim or upper rim by three different methods were reported. 相似文献
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自从2001年Ohzuku T和Makimura Y报导LiNi1/3Co1/3Mn1/3O2正极材料以来,其一直被认为是最有可能取代LiCoO2的新型锂离子二次电池正极材料之一。氢氧化物共沉淀法是最常用的一种合成LiNi1/3Co1/3Mn1/3O2材料的方法,通过混合氢氧化物共沉淀法可以获得有着均一分布且具有很高的振实密度的球形LiNi1/3Co1/3Mn1/3O2。 相似文献
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N-甲基丙烯酰-N′-嘧啶基哌嗪及其聚合物敏化的丙烯腈光聚合 总被引:1,自引:2,他引:1
The photopolymerization of acrylonitrile (AN) sensitized by N-methacrylyl-N'-pyrimidi-nopiperazine (MPMP) and its polymer, P(MPMP) was studied kinetically. It was found that the photopolymerization rate of AN sensitized by monomeric MPMP is proportional to 0.35th power of MPMP concentration and 0.85th power of AN concentration, respectively. In the case sensitized by Polymeric MPMP, P(MPMP) is proportional to 0.30th power of P(MP-MP) concentration and 1.0 power of AN concentration, respectively. The overall activation energies for photopolymerization sensitized with MPMP and P(MPMP) were determined to be 4.71Kcal/mol and 4.58Kcal/mol,respectively.From the fluorescence analysis for P(AN) senstitized by either MPMP or P(MPMP),it was confirmed that MPMP and P(MPMP) not only sensitized the photopolymerization of AN but also entered into the P(AN) chains. 相似文献
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The photopolymerization of acrylonitrile sensitized by N-methyl-N-(2-methacryloyloxye-thyl)aniline (MEMA) was studied kinetically. The photopolymerization rate of AN in DMF by using MEMA as sensitizer is proportional to 0.32 th power of MEMA concentration and 1.20 th power of AN concentration. The overall activation energy for the polymerization was found to be 4.82 Kcal/Mol. From the fluorescence analysis of obtained polyacrylonitrile sensitized by MEMA, it was confirmed that MEMA not only joined the inition but also entered into the polyacrylonitrile chains. The initiation mechanism was proposed tentatively. 相似文献
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N-甲基丙烯酰-N′-嘧啶基哌嗪及其聚合物的荧光光谱研究 总被引:6,自引:5,他引:6
A novel acrylic monomer bearing pyrimidino-moiety, N-methacrylyl-N'-pyrimidinopipe-razine (MPMP) was synthesized by the reaction of N-pyrimidinopiperazine and methacrylyl chloride in the presence of triethylamine. Both absorption and fluorescence spectum for the monomer and its polymer were recorded. It was observed that the fluorescence intensity of monomeric MPMP was slightly lower than that of its polymer. The monomer did not dramatically appear its structural self-quenching effect as we have reported previously. The fluores-cence of the polymer,P(MPMP) culd be quenched by electron-deficient quenchers such as methacrylonitrile,acrylonitrile,fumaronitrile; methyl acrylate and methyl methacrylate. The Stern-Volmer constants of those quenchers for P(MPMP) were determined. 相似文献