全文获取类型
收费全文 | 516篇 |
免费 | 33篇 |
学科分类
工业技术 | 549篇 |
出版年
2023年 | 5篇 |
2022年 | 5篇 |
2021年 | 32篇 |
2020年 | 15篇 |
2019年 | 17篇 |
2018年 | 10篇 |
2017年 | 9篇 |
2016年 | 18篇 |
2015年 | 23篇 |
2014年 | 23篇 |
2013年 | 42篇 |
2012年 | 40篇 |
2011年 | 28篇 |
2010年 | 23篇 |
2009年 | 25篇 |
2008年 | 12篇 |
2007年 | 33篇 |
2006年 | 20篇 |
2005年 | 13篇 |
2004年 | 16篇 |
2003年 | 17篇 |
2002年 | 12篇 |
2001年 | 7篇 |
2000年 | 4篇 |
1999年 | 10篇 |
1998年 | 17篇 |
1997年 | 17篇 |
1996年 | 11篇 |
1995年 | 7篇 |
1994年 | 9篇 |
1993年 | 4篇 |
1992年 | 2篇 |
1991年 | 4篇 |
1990年 | 2篇 |
1989年 | 1篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1986年 | 2篇 |
1985年 | 4篇 |
1979年 | 2篇 |
1977年 | 1篇 |
1975年 | 1篇 |
1972年 | 1篇 |
1971年 | 2篇 |
排序方式: 共有549条查询结果,搜索用时 672 毫秒
91.
Arrigo I Catalfamo P Cavallari L Di Pasquale S 《Journal of hazardous materials》2007,147(1-2):513-517
Important pumice quarries are located on the island of Lipari (Italy) where an intense activity of extraction, transformation and trade of pumice takes place. Nevertheless, the finest fraction amounting to about 60% of mined pumice is discarded and disposed off in open-sky pits. This implies economic losses for mining industries and environmental problems for neighbouring villages. In order to find a sustainable use of this waste, we resumed and improved an old extractive process with aqueous sodium alkali, where a sodium silicate concentrated solution was produced together with an unextracted residue partially converted into zeolite P in Na+ form and now we are searching for suitable applications of this residue. In this paper, we relate about its use as a low cost water softening agent on the basis of results obtained from several tests both in batch systems and column. They show that, at room temperature, the residue works well with calcium and badly with magnesium, whereas, at 60 degrees C, also the affinity toward Mg ions increases to acceptable levels. Repeated regenerations of the residue with concentrated NaCl solutions do not appreciably compromise the performance. The limits for the possible use as water softening agent are defined. 相似文献
92.
93.
Valentina Nania Guido Enrico Pellegrini Laura Fabrizi Giulio Sesta Patrizia De Sanctis Dario Lucchetti Mauro Di Pasquale Ettore Coni 《Food chemistry》2009
Perfluorooctanoic acid (PFOA) and perfluorooctane sulphonate (PFOS) are environmental contaminants belonging to a chemical group known as perfluorinated compounds (PCFs). The United States Environmental Protection Agency (US EPA) considers both compounds to be carcinogenic. The goal of the present study was to evaluate the contamination levels of PFOS and PFOA in edible fish of the Mediterranean Sea. Twenty six fish muscles, 17 fish livers, five series of cephalopods (each composed of ten specimens) and thirteen series of bivalves (each composed of about 50 specimens) were used for the investigation. A fast sample treatment, followed by an LC–ESI–MS/MS method is described for the identification, and quantification of PFOA and PFOS in fish. The method was in-house-validated through the determination of precision, accuracy, specificity, calibration curve, decision limit (CCα), and detection capability (CCβ). The results showed PFOA and PFOS levels in fishes and molluscs lower than those reported for analogue matrices in different geographic areas. Therefore, our biomonitoring results did not show that the Mediterranean Sea had any particularly alarming pollution by PFCs, although it is located in a semi-closed basin with scarce water change. Nonetheless, a worrying element is that a few fish showed extremely high contamination by PFOA and PFOS. This finding needs further clarification in order to assess whether such unusual contamination is linked to “dot-like” pollutant release, which could explain the anomaly. 相似文献
94.
O'Connell JE Saracino P Huppertz T Uniake T de Kruif CG Kelly AL Fox PF 《The Journal of dairy research》2006,73(3):312-317
The influence of ethanol on the rennet-induced coagulation of milk was studied to investigate potential synergistic effects of these two mechanisms of destabilisation on the casein micelles. Addition of 5% (v/v) ethanol reduced the rennet coagulation time (RCT) of milk, whereas higher levels of ethanol (10-20%, v/v) progressively increased RCT. The temperature at which milk was coagulable by rennet decreased with increasing ethanol content of the milk. The primary stage of rennet coagulation, i.e., the enzymatic hydrolysis of kappa-casein, was progressively slowed with increasing ethanol content (5-20%, v/v), possibly due to ethanol-induced conformational changes in the enzyme molecule. The secondary stage of rennet coagulation, i.e., the aggregation of kappa-casein-depleted micelles, was enhanced in the presence of 5-15% ethanol, the effect being largest at 5% ethanol. Enhanced aggregation of micelles is probably due to an ethanol-induced decrease in inter-micellar steric repulsion. These results indicate an interrelationship between the effects of ethanol and chymosin on the casein micelles in milk, which may have interesting implications for properties of dairy products. 相似文献
95.
Occurrence of variable levels of health‐promoting fruit compounds in horn‐shaped Italian sweet pepper varieties assessed by a comprehensive approach 下载免费PDF全文
96.
Assessing the Potential Content of Ethyl Carbamate in White,Red, and Rosé Wines as a Key Factor for Pursuing Urea Degradation by Purified Acid Urease 下载免费PDF全文
Martina Cerreti Marcello Fidaleo Ilaria Benucci Katia Liburdi Pasquale Tamborra Mauro Moresi 《Journal of food science》2016,81(7):C1603-C1612
The ethyl carbamate (EC) content of a wine after a given temperature‐time storage was theoretically predicted from the potential concentration of ethyl carbamate (PEC), as determined via an accelerated EC formation test. Such information was used to decide whether an enzymatic treatment was needed to reduce the wine urea level before bottling/aging. To this end, 6 white, red, and rosé wines, manufactured in Italy as such or enriched with urea, were tested for their PEC content either before or after enzymatic treatment using a purified acid urease preparation derived from Lactobacillus fermentum. The treatment was severely affected by the total phenolic content (TP) of the wine, the estimated pseudo‐first‐order kinetic rate constant for NH3 formation reducing by a factor of approximately 2000 as the TP increased from 0 to 1.64 g L‐1. Such a sensitivity to TP was by far greater than that pertaining to a killed cell‐based enzyme preparation used previously. Urea hydrolysis was successful at reducing EC concentration in wines with low levels of TP and other EC precursors. 相似文献
97.
98.
Alberto D’Amore Luigi Grassia Pasquale Verde 《Mechanics of Time-Dependent Materials》2013,17(1):15-23
A two-parameter model explicitly accounting for the cyclic as well as the mean stress was proposed and tested on the basis of static and fatigue data obtained in four-point bending on a random continuous glass-fiber-reinforced polypropylene. The model is based on residual strength degradation and captures the effect of stress ratio (i.e. the ratio between the minimal and the maximal stress). The experimental data were in excellent agreement with the theoretical predictions, indicating that a fatigue characterization can be achieved with a minimum of experimental tests. Further, the reasonable agreement between the static strength data and the theoretical predictions highlighted the potential and reliability of the model in view of its statistical implementation 相似文献
99.
In this study, a novel and simple diffractive spectrographic method for real-time measurements of circular dichroism (CD) is considered from a theoretical and experimental approach. A demonstrator prototype of the CD spectrograph has been developed and its performance has been compared with a commercial phase-modulation CD spectrometer. The main element of the device is a polarization holographic grating, recorded in a thin photosensitive organic film, by two interfering opposite circularly polarized beams. A peculiarity of this grating is that the amplitude of the +1 (-1) order of diffraction is proportional to the right (left) circular polarization component of the incoming beam. Here we demonstrate that the CD spectrum of a specimen can be easily evaluated from the intensities of the diffracted beams. A white light beam passing through the specimen is diffracted from the grating and the intensities of the +/-1 orders of diffraction are measured. Due to the spectral selectivity of the grating, the CD at each wavelength can be evaluated at the same time using two linear array detectors. 相似文献
100.
Vincenzo Leone Silvana Canzano Pasquale Iovino Sante Capasso 《Journal of Porous Materials》2012,19(4):449-453
The sorption of humic acids (HA) on zeolite-feldspar-bearing Phlegraean Yellow Tuff enriched with calcium ions has been investigated at neutral pH both on fixed-bed columns and in batch. A two-step sorption kinetics and a relatively long time to reach the equilibrium were observed in batch. In line with this behaviour, the breakthrough curves and shipping curves from exhaust columns showed distinctive properties that cannot be easily modelled by the common mass balance equations; noteworthy, the breakthrough curves were dependent on the space velocity also for very slow processes and the bed sorption capacity decreased linearly with the space velocity. Moreover, after an initial high-rate burst, HA desorption from exhausted columns proceeded at a very slow rate, particularly so for columns loaded with higher amounts of HA. 相似文献