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71.
72.
阿尔泰地区存在 5条与深大断裂有关的基性、超基性岩带 ,是铜镍硫化物矿床产出的有利地段 ,其中喀拉通克铜镍矿是我国大型铜镍矿之一。通过对成矿必要条件的深入研究 ,得出深大断裂及其次级断裂控制了岩体的产出 ,北北西向断裂叠加北西向断裂控制了矿体的产出 ;成矿充分条件是基性、超基性岩体 ,总结了岩体含矿性的评价指标。结合重磁及地化资料 ,在喀拉通克铜镍矿的成矿模式基础上 ,建立了区域综合信息找矿模型 ,进行成矿预测 ,圈定靶区 9处。 相似文献
73.
青海驼路沟钴(金)矿床成矿物质来源的黄铁矿氦氩硫铅同位素示踪 总被引:2,自引:0,他引:2
为查明青海驼路沟新型独立钴(金)矿床的成因和成矿物质来源,文章对矿区发育的块状、条带状和浸染状黄铁矿矿石进行了黄铁矿流体包裹体氦氩同位素和黄铁矿硫、铅同位素测试。结果表明,不同类型矿石的成矿流体氦、氩同位素组成基本一致,3He/4He介于0.10~0.31Ra(平均0.21Ra),40Ar/36Ar比值为302~569(平均373),反映钴矿化流体主要来源于在赋矿岩系中深循环的大气降水;矿石黄铁矿硫同位素值分布集中且接近于零,δ34S变化于-4.5‰~+1.5‰,集中在-1.8‰~-0.2‰,显示深部来源;矿石铅以高放射性成因为特征(206Pb/204Pb>19.279、207Pb/204Pb>15.691、208Pb/204Pb>39.627),且自地层围岩→区域早古生代火山岩→矿石依次明显增大,可能指示高放射性成因矿石铅主要是由以深循环大气降水来源为主的热液不断从围岩地层中淋取而来。 相似文献
74.
75.
胶东金矿集区矿石中普遍含金属硫化物和碳酸盐矿物,某些矿床中还见有富含炭质的断裂破碎带.成矿溶液中含有大量的SO4^2-、HCO3^-、CO2和有机质等的含硫和含碳组分.矿石硫同位素组成明显富集重硫,结合胶东金矿主要成矿时期(早白垩世)特殊的地质背景、同期海水硫酸盐δ^34S平均值(约+16‰)及现代海水沿NE-NNE向断裂倒灌情况,笔者认为,硫的主要来源与海水硫的大量补给有关.而根据碳、氧同位素组成特征分析,形成金矿床中方解石的物源有很大一部分来自前寒武系碳酸盐岩.浅表环境下成矿金属元素及硫、碳等物质在热液对流系统中的大规模循环是成矿的关键,SO4^2-与S2^-之间的临界转化是制约成矿金属元素活化-迁移-聚集的重要因素,而含碳组分(CO3^2-、HCO3^-、CO2和有机质)则有利于Au、Cu、Pb、Zn等元素的活化和迁移,含硫和含碳组分的循环及有关的物理化学反应之间有明显的关联性. 相似文献
76.
大宝山多金属矿床是粤北地区典型的巨厚型及细脉带型矿化的多金属硫化物矿床.层状和脉状黄铁矿的氦氩同位素表明:3He/4He的R/Ra值为0.60~4.13,40Ar/86Ar=327~411,反映该成矿流体是大气饱和水(海水)与地幔流体混合作用的结果.铅和硫同位素都揭示了层状(块状)和脉状矿体可能来自不同时期的成矿流体.其中层状矿体为泥盆纪海底火山喷发沉积作用所致,脉状矿体可能来自燕山期岩浆热液充填叠加形成,古大陆碎屑物质和部分有机质的还原对后期成矿流体具有较大的影响作用. 相似文献
77.
Stella M. Resende 《Journal of Atmospheric Chemistry》2007,56(1):21-32
The atmospheric reaction between HS and NO2 was theoretically investigated at 298 K and 1 atm of pressure. Our results show that the first reaction step will lead to the formation of HSNO2 or HSONO, spontaneously and exothermically. HSONO easily decomposes into HSO + NO. On the other hand, HSNO2 can hardly dissociate in the reactants, and its isomerization to other adducts is much hindered. Production of HNO + SO and SNO + OH was found to be unfavorable. Thus, the main products would be HSO + NO and HSNO2, and new investigations focusing on the atmospheric fate of HSNO2 are suggested. A general discussion of the fate of HS under atmospheric conditions is presented. Recent investigations indicate that NO2, O2 and N2O should be the most important oxidants of HS, while the O3 influence will not be significant. 相似文献
78.
热解硫酸钡制备硫同位素分析试样二氧化硫 总被引:1,自引:1,他引:0
改进了硫同位素分析中由BaSO4制备SO2的方法:BaSO4和V2O5及SiO2混合后覆盖铜丝,在真空状态980℃加热20min,用液氮捕集SO2。与火焰直接加热分解法相比,用高温炉方便,改善了制样环境,避免污染。经国际标样和国家标准物质分析验证,结果与标准值相符,标准偏差(1σ)在±009‰~±020‰,符合分析要求。 相似文献
79.
A Three-Dimensional Global Model Study of Carbonyl Sulfide in the Troposphere and the Lower Stratosphere 总被引:4,自引:0,他引:4
Erik Kjellström 《Journal of Atmospheric Chemistry》1998,29(2):151-177
Global distributions of carbonyl sulfide and carbon disulfide have been calculated with a three-dimensional global model of the atmospheric general circulation (ECHAM). The model calculates a global sink strength for carbonyl sulfide of 0.3 Tg S yr-1, with vegetation uptake being the largest sink. With this sink strength, the sources have to be close to the lower limit of the present estimate in the literature. The calculated mixing ratios are higher in the Southern Hemisphere than in the Northern Hemisphere. This interhemispheric gradient is the opposite of what is observed demonstrating that the present knowledge of the distribution of sinks and sources is not fully adequate. The model calculations support the idea that the open oceans could act as a net sink of carbonyl sulfide. The calculated stratospheric photolysis of carbonyl sulfide constitutes about 4% of the total sink of carbonyl sulfide. A stratospheric production of sulfate from carbonyl sulfide of 0.013 Tg S yr-1 is obtained, which is 3 to 12 times less than what is needed to maintain the stratospheric sulfate aerosol layer. Although these results are associated with uncertainties, due to the low upper boundary and coarse vertical resolution of the model, they support recent findings of a low stratospheric production of sulfate from carbonyl sulfide. Instead, sulfur dioxide transported from the troposphere is calculated to be the most important precursor for the stratospheric sulfate aerosol layer. 相似文献
80.
Veli-Matti Kerminen Risto E. Hillamo Anthony S. Wexler 《Journal of Atmospheric Chemistry》1998,30(3):345-370
A box model was constructed to investigate connections between the particulate MSA to non-sea-salt sulfate ratio, R, and DMS chemistry in a clean marine boundary layer. The simulations demonstrated that R varies widely with particle size, which must be taken into account when interpreting field measurements or comparing them with each other. In addition to DMS gas-phase chemistry, R in the submicron size range was shown to be sensitive to the factors dictating sulfate production via cloud processing, to the removal of SO2 from the boundary layer by dry deposition and sea-salt oxidation, to the entrainment of SO2 from the free troposphere, to the relative concentration of sub- and supermicron particles, and to meteorology. Three potential explanations for the increase of R toward high-latitudes during the summer were found: larger MSA yields from DMS oxidation at high latitudes, larger DMSO yields from DMS oxidation followed by the conversion of DMSO to MSA at high latitudes, or lower ambient H2O2 concentrations at high latitudes leading to less efficient sulfate production in clouds. Possible reasons for the large seasonal amplitude of R at mid and high latitudes include seasonal changes in the partitioning of DMS oxidation to the OH and NO3 initiated pathways, seasonal changes in the concentration of species participating the DMS-OH reaction pathway, or the existence of a SO2 source other than DMS oxidation in the marine boundary layer. Even small anthropogenic perturbations were shown to have a potential to alter the MSA to non-sea-salt sulfate ratio. 相似文献