Analog and radio-frequency performance analysis of silicon-nanotube MOSFETs

This work presents a comparative study of the influence of various parameters on the analog and RF properties of silicon-nanotube MOSFETs and nanowire-based gate-all-around (GAA) MOSFETs. The important analog and RF performance parameters of SiNT FETs and GAA MOSFETs, namely drain current (I_d), transconductance to drain current ratio (g_m/I_d), I_on/I_off, the cut-off frequency (f_T) and the maximum frequency of oscillation (f_MAX) are evaluated with the help of Y- and H-parameters which are obtained from a 3-D device simulator, ATLAS^TM. It is found that the silicon-nanotube MOSFETs have far more superior analog and RF characteristics (g_m/I_d, f_T and f_MAX) compared to the nanowire-based gate-all-around GAA MOSFETs. The silicon-nanotube MOSFET shows an improvement of~2.5 and 3 times in the case of f_T and f_MAX values respectively compared with the nanowire-based gate-all-around (GAA) MOSFET.     

Oxidative steam reforming of vacuum residue for hydrogen production

A two-step process for production of hydrogen from vacuum residue has been developed. In the first step, which has already been communicated [18], the residue is reacted with ozone to get oxidized and cracked products. Next, the catalytic oxidative steam reforming of the product obtained after ozonation over a Pt catalyst supported on La₂O₃-CeO₂-γ-Al₂O₃ was carried out. Effects of the operating conditions: the temperature, the steam to carbon ratio and the oxygen to carbon ratio on oxidative steam reforming were investigated. The oxidative steam reforming was efficient at the molar ratio of O₂/C = 0.5, S/C = 4 at 1173 K. Pt catalyst deactivated with time due to coke formation. The catalyst could be regeneration by blowing oxygen through the catalytic bed. Catalysts were characterized by XRD, N₂ adsorption–desorption and thermo gravimetrically to understand the microstructures.     

Quality Assessment of Mine Water in the Raniganj Coalfield Area,India

In a qualitative assessment of mine water from the Raniganj coalfield, 77 mine water samples were analyzed to assess water quality and suitability for domestic, industrial, and irrigation uses. The pH of the mine water ranged from 6.5 to 8.8. Total dissolved solids (TDS) ranged from 171 to 1,626 mg L⁻¹; spatial differences between the TDS values reflect variations in lithology, activities, and prevailing hydrological regime. The anion chemistry was dominated by HCO₃ ⁻ and SO₄ ²⁻. On average, Cl⁻ contributes 10 and 19% of the total anionic balance, respectively, in the Barakar and Raniganj Formation mine water. F⁻ and NO₃ ⁻ contribute <2% to the total anions. The cation chemistry is dominated by Mg²⁺ and Ca²⁺ in the mine water of the Barakar Formation and Na⁺ in the Raniganj Formation mines. Much of the mine water, especially of the Barakar Formation area, has high TDS, total hardness, and SO₄ concentrations. Concentrations of some trace metals (i.e. Fe, Cr, Ni) were found to be above the levels recommended for drinking water. However, the mine water can be used for irrigation, except at some sites, especially in the Raniganj Formation area, where high salinity, sodium adsorption ratio, %Na, residual sodium carbonate, and excess Mg restrict its suitability for agricultural uses.     

An ensemble wavelet bootstrap machine learning approach to water demand forecasting: a case study in the city of Calgary,Canada

This paper explores a hybrid wavelet, bootstrap and neural network (WBNN) modeling approach for daily (1, 3 and 5 day) urban water demand forecasting in situations with limited data availability. This method was tested using 3 years of daily water demand and meteorological data for the city of Calgary, Alberta, Canada. The performance of the WBNN method was compared to that of three other methods: traditional neural networks (NN), wavelet NNs (WNN), and bootstrap-based NN (BNN) models. While the hybrid WBNN and WNN models equally provided 1-day lead-time forecasts of greater accuracy than those obtained with other methods, for longer lead-time (3- or 5-day) forecasts the WBNN model alone outperformed the other models. The confidence bands generated using the WBNN model displayed the uncertainty associated with the forecasts.     

Antagonism of microRNA function in zebrafish embryos by using locked nucleic acid enzymes (LNAzymes)

MicroRNAs (miRNAs) have crucial functions in many cellular processes, such as differentiation, proliferation and apoptosis; aberrant expression of miRNAs has been linked to human diseases, including cancer. Tools that allow specific and efficient knockdown of miRNAs would be of immense importance for exploring miRNA function. Zebrafish serves as an excellent vertebrate model system to understand the functions of miRNAs involved in a variety of biological processes. We designed and employed a strategy based on locked nucleic acid enzymes (LNAzymes) for in vivo knockdown of miRNA in zebrafish embryos. We demonstrate that LNAzyme can efficiently knockdown miRNAs with minimal toxicity to the zebrafish embryos.     

V-ATPase upregulation during early pregnancy: a possible link to establishment of an inflammatory response during preimplantation period of pregnancy

Various mechanisms exist to prevent a potentially deleterious maternal immune response that results in compromising survival of semiallogeneic fetus. In pregnancy, there is a necessary early preimplantation inflammatory stage followed by a postimplantation anti-inflammatory stage. Thus, there is a biphasic 'immune response' observed during the course of pregnancy. We provide the evidence that capacitation of sperm induced the expression of a2 isoform of V-ATPase (ATP6V0A2 referred to as a2V), leukemia inhibitory factor (Lif), Il1b, and Tnf in the sperm. Capacitated sperm also released cleaved N-terminal domain of a2V-ATPase (a2NTD), which upregulates the gene expression of Lif, Il1b, Tnf, and monocyte chemotactic protein-1 (Ccl2 (Mcp1)) in the uterus. Unfertilized eggs had low a2V expression, but after fertilization, the expression of a2V increased in zygotes. This increased level of a2V expression was maintained in preimplantation embryos. Seminal plasma was necessary for upregulation of a2V expression in preimplantation embryos, as mating with seminal vesicle-deficient males failed to elicit an increase in a2V expression in preimplantation embryos. The infiltration of macrophages into the uterus was significantly increased after insemination of both sperm and seminal plasma during the preimplantation period of pregnancy. This dynamic infiltration into the uterus corresponded with the uterine a2V expression through the induction of Ccl2 expression. Furthermore, the polarization ratio of M1:M2 (pro-inflammatory/anti-inflammatory) macrophages in the uterus fluctuated from a ratio of 1.60 (day 1) to 1.45 (day 4) when female mice were inseminated with both sperm and seminal plasma. These data provide evidence that exposure to semen may initiate an inflammatory milieu by inducing a2V and cytokine/chemokine expression, which triggers the influx of macrophages into the preimplantation uterus during the onset of pregnancy and ultimately leads to successful pregnancy outcome.     

Heat transfer enhancement and pressure drop analysis in a helically coiled tube using Al2O3 / water nanofluid

In this experimental investigation, the heat transfer and pressure drop analysis of a shell and helically coiled tube heat exchanger by using Al₂O₃ / water nanofluids have been carried out under turbulent flow condition. The Al₂O₃/ water nanofluids of 0.1%, 0.4%, and 0.8% particle volume concentration have been prepared by using two step method. The tube side experimental Nusselt number of 0.1%, 0.4% and 0.8% nanofluids were found to be 28%, 36% and 56%, respectively higher than water. These enhancements are due to higher thermal conductivity of nanofluid, better fluid mixing and strong secondary flow formation in coiled tube. The pressure drop of 0.1%, 0.4% and 0.8% were found to be 4%, 6%, and 9%, respectively higher than water. The increase in pressure drop is due to increase in nanofluid viscosity while adding nanoparticles. The measurement of nanofluid thermal performance factor is found to be greater than unity. It is concluded that the Al₂O₃ nanofluid can be applied as a coolant in helically coiled tube heat exchanger to enhance heat transfer with negligible pressure drop.     

Investigations of Ce3+ co-doped SbPO4:Tb3+ nano-ribbons and nanoparticles by vibrational and photoluminescence spectroscopy

Nano-ribbons and very small nanoparticles (size 2-5 nm) of SbPO4 doped with lanthanide ions (Ce3+ and Tb3+) are prepared at a relatively low temperature of 120 degrees C based on a solution method. Detailed vibrational and luminescence studies on these samples establish that these lanthanide ions are incorporated at Sb3+ site of the SbPO4 lattice. The excitation spectrum corresponding to the Tb3+ emission and the excited state lifetime of the 5D4 level of Tb3+ ions in the sample confirm the energy transfer from Ce3+ to Tb3+ ions in the SbPO4 host. The extent of energy transfer from Ce3+ to Tb3+ in these samples is found to be around 60%. Dispersion of these nanomaterials in silica matrix effectively shields the lanthanide ions at the surface of the nano-ribbons/nanoparticles from the stabilizing ligands resulting in the reduction in the vibronic quenching of the excited state. Our results show significant reduction in the surface contribution in the decay curve corresponding to the 5D4 level of the Tb3+ ions after incorporating the nano-ribbons/nanoparticles in silica. These nanomaterials incorporated in silica matrix can have potential applications in bio-assays and bio-imaging.