The influence of subzero temperatures on fatigue behavior of composite sandwich structures

The fatigue lives and failure modes of foam core carbon/epoxy and glass/epoxy composite sandwich beams in 4-point bending were characterized from room temperature (22 °C) down to −60 °C. Similar previous investigations had focused on elevated temperatures only, but the low temperature fatigue behavior must be understood so that these materials may be evaluated for possible use in the hull structures of ships, which operate in cold regions. Core shear was found to be the dominant fatigue failure mode for the test specimens over the entire temperature range from 22 °C down to −60 °C. Significant increases in the useful fatigue life with brittle type core shear failure were observed at low temperatures by comparison with the corresponding room temperature behavior. Fatigue failure at the low temperatures was catastrophic and without any significant early warning, but the corresponding failures at room temperature were preceded by relatively slow but steadily increasing losses of stiffness. Two different approaches were used to investigate stiffness reductions during fatigue tests, and both approaches led to the same conclusions. Experimental observations regarding the location of fatigue crack initiation were confirmed by static finite element analyses for both materials.     

Local Dynamics of Adhesives in Aggressive Environment in the Pre-Damage Stage

Molecular aspects of chemical and physical changes in adhesive joints caused by absorbed moisture were investigated. The focus was on the pre-damage stage that precedes the formation of voids and microcracks. A model and a commercial epoxy-amine formulation were studied. Local dynamics were monitored by broad-band dielectric relaxation spectroscopy (DRS). One portion of the absorbed water does not form hydrogen bonds with the network and gives rise to a fast relaxation process (termed γ) with activation energy of 28 kJ/mol. The local β dynamics are slowed down by the interactions between water and various sites on the network that include the ether oxygen, the hydroxyl group and the tertiary amine nitrogen. One particularly significant finding is that the average relaxation time for the β process above 20°C is of the order of nanoseconds or less and, hence, the detection and monitoring of this process hinges upon the ability to perform high-precision DRS at frequencies above 1 MHz. This is an important consideration in the ongoing efforts aimed at the implementation of DRS as nondestructive inspection (NDI) tool for adhesive joints.     

Survivable Network Design: The State of the Art

In the past few years the telecommunications industry has undergone significant changes. We are rapidly evolving to a state where audio/visual and data traffic is all provided on the same networks. Telecommunication companies are investing billions of dollars in the design and maintenance of telecommunication networks to provide the users with the better quality of service that they have begun to expect. Due to their high capacity, fiber optic cables have become the medium of choice in the deployment of such new networks worldwide. Such high capacities encourage telecommunication providers to create networks that are substantially more sparse than previous copper based networks. Unfortunately, with sparsity comes vulnerability to failure. Given the dependence on the varied services offered by the modern networks, the magnitudes of the investments involved and the costs of disasters it is only logical that researchers look at problems in survivable network design as an interesting research question. There have been a number of papers that have addressed these and other related issues. In this paper we try to classify the area of survivable network design and provide a classification scheme for the same.     

The fine structure of bicomponent polyester fibers

The application of alkaline hydrolysis to study the change in the fine structure of bicomponent polyester fibers as their surface is removed progressively was explored. The samples were prepared with a poly(butylene terephthalate) (PBT) sheath and a poly(ethylene terephthalate) (PET) core. The reagent used to hydrolyze the PBT was 1M NaOH in 75/25 methanol to water since it appeared to react topochemically with the fiber. The solution reacted more rapidly with PET than with PBT. Thus, when necessary to retard the weight loss of the bicomponent fibers, after a 2‐h hydrolysis with this reagent to remove PBT, it was replaced with aqueous 1M NaOH solution containing 0.1% cetrimmonium bromide. Unlike homofil PET or PBT fibers, where alkaline attack appeared to be confined to the surface and left the residue relatively smooth, the bicomponent fiber was attacked unevenly, and penetration to the PET core occurred before all the PBT at the surface was removed. Nevertheless, most of the reaction was confined initially to the PBT sheath. The tenacity and extension at break of the PBT–PET fiber passed through a maximum as hydrolysis progressed. The fall in tenacity at high weight losses is ascribed to increasing surface defects in the fiber surface. After removal of the PBT by the hydrolysis, the birefringence of the residue became progressively higher. The synergistic effect of the PBT sheath on the properties of the PET core and the possible causes of the nonuniform hydrolysis at the PBT surface are discussed. An equation is proposed that includes an interaction parameter, which can be utilized to determine which property is affected most by the hydrolysis of a bicomponent fiber. In this instance, it appears from the parameters that the order is strength > extension at break ≈ birefringence. © 1999 John Wiley & Sons, Inc. J Appl Polym Sci 71: 1163–1173, 1999     

Peptides Containing meso-Oxa-Diaminopimelic Acid as Substrates for the Cell-Shape-Determining Proteases Csd6 and Pgp2

The enzymes Csd6 and Pgp2 are peptidoglycan (PG) proteases found in the pathogenic bacteria Helicobacter pylori and Campylobacter jejuni, respectively. These enzymes are involved in the trimming of non-crosslinked PG sidechains and catalyze the cleavage of the bond between meso-diaminopimelic acid (meso-Dap) and d -alanine, thus converting a PG tetrapeptide into a PG tripeptide. They are known to be cell-shape-determining enzymes, because deletion of the corresponding genes results in mutant strains that have lost the normal helical phenotype and instead possess a straight-rod morphology. In this work, we report two approaches directed towards the synthesis of the tripeptide substrate Ac-iso-d -Glu-meso-oxa-Dap-d -Ala, which serves as a mimic of the terminus of an non-crosslinked PG tetrapeptide substrate. The isosteric analogue meso-oxa-Dap was utilized in place of meso-Dap to simplify the synthetic procedure. The more efficient synthesis involved ring opening of a peptide-embedded aziridine by a serine-based nucleophile. A branched tetrapeptide was also prepared as a mimic of the terminus of a crosslinked PG tetrapeptide. We used MS analysis to demonstrate that the tripeptide serves as a substrate for both Csd6 and Pgp2 and that the branched tetrapeptide serves as a substrate for Pgp2, albeit at a significantly slower rate.     

Graft copolymerization of acrylonitrile onto Cassia tora gum with ceric ammonium nitrate–nitric acid as a redox initiator

The graft copolymerization of acrylonitrile (AN) onto Cassia tora gum (CTG) was carried out in an aqueous medium with a ceric ammonium nitrate (CAN)–nitric acid initiation system. The percentage grafting and percentage grafting efficiency were determined as functions of the concentrations of CAN, nitric acid, AN, and CTG and the polymerization temperature and time. The results are discussed, and a reaction mechanism is proposed. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 90: 129–136, 2003     

Tracking model of an adaptive lattice filter for a linear chirp FMsignal in noise

The paper studies the behavior of the partial correlation (PARCOR) coefficients and the output misadjustment of the stochastic gradient adaptive lattice filter in response to a complex linear chirp FM signal in white Gaussian noise. Analytic expressions for the optimal PARCOR coefficients of the filter are derived. Analytic as well as iterative models for a three-stage filter are also derived. The analytic expressions show that the tracking and convergence properties of the filter are separate phenomena. Simulation results also show that the spectral contents of the PARCOR coefficients for the stochastic gradient update algorithm consist of a stationary and a linearly swept component. A single-stage model is developed to explain this behavior. Finally, output misadjustment plots for the filter show that an optimum value for the forgetting factor can be obtained to minimize the misadjustment, but the value required to achieve local minimum misadjustment varies with each stage of the filter. It is shown that in applications where the input has a high signal-to-noise ratio (SNR), the misadjustment decreases rapidly at each successive stage, thus implying that relatively short filter lengths are sufficient to provide effective tracking     

An Approximation To The Stationary Distribution Of A Multidimensional Markov Process

In this paper we present an approximate, non-iterative method for calculating the stationary distribution of a multidimensional Markov process. Although the method has more general applications, we illustrate it for a particular example of a repairable item inventory model with returns. We analyze two versions of this model. In the first version we assume that all failed items are repairable, whereas in the second version we assume that some of the failed items are irreparable and hence are scrapped. Each version gives rise to multidimensional state spaces that are extremely large even for problems with a relatively small number of items. Because of the large state spaces, the emphasis of this paper is on developing an approximation for the stationary distribution. We show that this approximation is not only easy to calculate but is also quite accurate across a broad range of problem parameters.