全文获取类型
收费全文 | 16144篇 |
免费 | 1556篇 |
国内免费 | 1094篇 |
学科分类
工业技术 | 18794篇 |
出版年
2024年 | 51篇 |
2023年 | 361篇 |
2022年 | 594篇 |
2021年 | 968篇 |
2020年 | 713篇 |
2019年 | 472篇 |
2018年 | 379篇 |
2017年 | 491篇 |
2016年 | 566篇 |
2015年 | 556篇 |
2014年 | 749篇 |
2013年 | 914篇 |
2012年 | 929篇 |
2011年 | 1300篇 |
2010年 | 871篇 |
2009年 | 1005篇 |
2008年 | 906篇 |
2007年 | 982篇 |
2006年 | 931篇 |
2005年 | 746篇 |
2004年 | 577篇 |
2003年 | 529篇 |
2002年 | 478篇 |
2001年 | 464篇 |
2000年 | 397篇 |
1999年 | 355篇 |
1998年 | 267篇 |
1997年 | 222篇 |
1996年 | 176篇 |
1995年 | 163篇 |
1994年 | 134篇 |
1993年 | 120篇 |
1992年 | 107篇 |
1991年 | 73篇 |
1990年 | 67篇 |
1989年 | 25篇 |
1988年 | 24篇 |
1987年 | 29篇 |
1986年 | 13篇 |
1985年 | 20篇 |
1984年 | 17篇 |
1983年 | 5篇 |
1982年 | 6篇 |
1981年 | 7篇 |
1980年 | 8篇 |
1979年 | 5篇 |
1978年 | 3篇 |
1974年 | 4篇 |
1959年 | 3篇 |
1951年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 468 毫秒
41.
文章通过对五口井的现场应用介绍,阐述了快速色谱分析技术在油气层识别和解释方面的准确性,探讨了该技术在薄油气层的发现和评价、快速钻进条件下油气层的发现、对油气层全烃组份变化的统一、水平井的地质导向以及排除钻井液添加荆对油气显示的影响五个方面的优势,从而论证了快速色谱分析技术在油气勘探中的应用价值。 相似文献
42.
郯庐断裂带是中国东部一条巨型断裂构造带,该文从其基本构造特征入手,分析了它的几何学、运动学和动力学特征,并进一步研究其含油气特点,认为:a)郯庐断裂带对中国东部诸多中新生代含油气盆地的形成及演化有重要的控制作用,不同演化阶段产生并控制了不同的沉积盆地(如松辽盆地和渤海湾盆地);b)郯庐断裂带对油气藏的形成及演化有重要的控制作用,不仅控制盆地烃源岩的发育、基本的储集层和盖层条件,以及圈闭的形成等等,而且对油气的生成、运移及聚集成藏、大中型油气田的形成及分布等有重要的控制作用. 相似文献
43.
Heidi Bernas Arie J. Plomp Johannes H. Bitter Dmitry Yu. Murzin 《Catalysis Letters》2008,120(1-2):8-13
The density functional theory (DFT/B3LYP) calculations were applied to investigate the interaction of a Pt6 particle with the ZSM-5 zeolite framework. The electronic structure of the metal particle is strongly affected by the interaction with basic framework oxygens and acid sites of the zeolite support. Adsorption on basic sites (Eads = 6 kcal/mol) favors the formation of the electron enriched metal cluster. Interaction of the platinum cluster with the acid site characterized by stabilization energy of 47 kcal/mol results in oxidation of the metal particle and suppression of Brønsted acidity of the support. The hypothesis is put forward that the oxidized platinum particle can function as an active site for the alkane isomerisation on platinum supported high silica zeolites. 相似文献
44.
M. Jayasankar 《Materials Letters》2007,61(3):790-793
Formation of aluminium titanate (AT) has been achieved at low temperature through sol-gel process using boehmite and titanium hydroxide as precursors by controlling the particle size at nanoscale followed by in-situ peptisation. The formations of AT phase, particle size distributions, sintering and thermal expansion characteristics, and microstructural features have been reported. DTA and XRD analysis have been performed to confirm the formation of AT. A 94% relative density was obtained for aluminium titanate sintered at 1550 °C with controlled grain size in the range of 2-3 μm. 相似文献
45.
研究了显色剂 4 ( 2 噻唑偶氮 ) 5 二甲氨基苯胺 (简称TADMA)与铑 的显色反应。结果表明 ,在 pH3 2~ 4 8范围内 ,铑 与TADMA反应形成 1∶2红色络合物 ,加入无机酸后色泽加深 ,络合物的表观摩尔吸光系数为 1 2 1× 10 5,铑质量浓度在 0~ 0 92 μg/mL范围内服从比尔定律。本方法操作简便 ,灵敏度高 ,选择性好 ,常见金属离子在一定范围内无干扰 ,用于催化剂中微量铑的测定 ,结果满意 相似文献
46.
根据高频旋回层序在长周期旋回层序内的有序叠加方式可在研究区石炭系中划分出3个Ⅲ级旋回层序和2个Ⅱ级旋回层序.其中Ⅲ3和Ⅲ3旋回层序为海侵体系域,Ⅲ2为高水位体系域,它们共同构成了研究区的层序地层格架并且控制着沉积相和生储盖组合的时空展布特征.由于受成岩历史差异性和不同成岩环境的影响,石炭系碎屑岩和碳酸盐岩储集岩成岩特征和储集性能在巴楚隆起区和麦盖提斜坡区均存在明显差异,且分布在斜坡区的储层物性明显优于隆起区同层位的储层,是近期有利的的勘探区域. 相似文献
47.
Yuanjing Zheng Anker Degn Jensen Jan Erik Johnsson 《Applied catalysis. B, Environmental》2005,60(3-4):253-264
The deactivation of a commercial type V2O5-WO3-TiO2 monolith catalyst under biomass combustion was studied at a full-scale grate-fired power plant burning straw/wood using a slip stream pilot scale reactor. The aerosols in the flue gas consisted of a mixture of potassium chloride and sulphate. Three catalyst elements were exposed at 350 °C, and one element was exposed at 250 °C for comparison. The catalyst activity was measured in the reactor at the exposure temperature by addition of NH3 and extra NO. The activity, in terms of a first-order rate constant, dropped by 52% after about 1140 h indicating a very fast deactivation compared to coal firing. It was also found that the reactor temperature was not of importance for the deactivation rate. SEM-EDX analysis showed that particle deposition and pore blocking contributed to the deactivation by decreasing the diffusion rate of NO and NH3 into the catalyst. However, potassium also penetrated into the catalyst wall and the resulting average K/V ratio in the catalyst structure was high enough (about 0.3–0.5) for a significant chemical deactivation. Chemisorption studies carried out in situ showed that the amount of chemisorbed NH3 on the catalyst decreased as a function of exposure time, which reveals that Brøndsted acid sites had reacted with potassium compounds and thereby rendered inactive. When washed by 0.5 M H2SO4 the regenerated catalyst regains a higher activity than that of the fresh catalyst at temperatures higher than 300 °C, but even though reactivation is possible, the deactivation rate appears too high for practical use of the SCR process in straw combustion. 相似文献
48.
Yi‐Hung Chen Ching‐Yuan Chang Wei‐Ling Su Chun‐Yu Chiu Yue‐Hwa Yu Pen‐Chi Chiang Chiung‐Fen Chang Je‐Lueng Shie Chyow‐San Chiou Sally IM Chiang 《Journal of chemical technology and biotechnology (Oxford, Oxfordshire : 1986)》2005,80(1):68-75
This study investigates the ozonation of CI Reactive Black 5 (RB5) by using the rotating packed bed (RPB) and completely stirred tank reactor (CSTR) as ozone contactors. The RPB, which provides high gravitational force by adjusting the rotational speed, was employed as a novel ozone contactor. The same ozone dosage was separately introduced into either the RPB or the CSTR for the investigation, while the experimental solution was continuously circulated within the apparatus consisting of the RPB and CSTR. The decolorization and mineralization efficiencies of RB5 in the course of ozonation are compared for these two methods. Moreover, the dissolved and off‐gas ozone concentrations were simultaneously monitored for the further analysis. As a result, the ozone mass transfer rate per unit volume of the RPB was significantly higher because of its higher mass transfer coefficient and gas–liquid concentration driving force. Furthermore, ozonation kinetics was found to be independent of the gravitational magnitude of an ozone gas–liquid contactor. Therefore, the results suggest employing RPBs as ozone‐contacting devices with the advantage of volume reduction. The experimental results, which can be used for further modeling of the ozonation process in the RPB, also show the requirement of correct design for the RPB. Consequently, the present study is useful for the understanding of practical application of RPBs. Copyright © 2004 Society of Chemical Industry 相似文献
49.
高速钢W6Mo5Cr4V2的脱磷试验 总被引:1,自引:0,他引:1
在30kg感应炉上用CaO-Na2CO3-CaF2-FexO(MoO3)渣、MoCl6粉剂和Al-Ca合金作脱磷剂对高速钢W6Mo5Cr4V2进行脱磷试验。结果表明,CaO-Na2CO3-CaF2-FexO渣的脱磷效果最好,一般脱磷率可达26% ̄56%。 相似文献
50.