内蒙古额济纳地区奥陶纪火山岩地球化学特征及其地质意义

内蒙古额济纳地区广泛出露的奥陶纪火山岩是中亚造山带南缘中段早古生代地质事件的重要响应，对研究及认识古亚洲洋的演化有着重要的启示.对内蒙古额济纳旗呼仍巴斯克地区咸水湖组火山岩与白云山组凝灰岩进行了岩石学、同位素年代学和全岩主、微量元素地球化学研究.结果显示:咸水湖组为一套基性-酸性熔岩及其同质的火山碎屑岩组合，白云山组凝灰岩为酸性凝灰岩；火山岩与凝灰岩皆属于亚碱性系列岩石，主要表现出钙碱性系列的演化趋势，具有富钙，富铝，贫镁，较大的TFeO/MgO比值的特征，稀土元素配分曲线呈右倾斜型，同时富集大离子亲石元素（LILE）和轻稀土元素（LREE），亏损高场强元素（HFSE）；咸水湖组流纹岩样品的SHRIMP锆石U-Pb同位素谐和年龄为462±3 Ma（MSWD=1.6），显示其形成时代为中奥陶世晚期.通过分析比对认为，不同于其西部希热哈达、伊哈托里等地区的岛弧环境，额济纳旗呼仍巴斯克地区奥陶纪火山岩形成于陆缘弧构造背景，揭示了中-晚奥陶世蒙古国境内Zoolen大洋向内蒙古额济纳地区明水-旱山陆块北缘俯冲作用的存在.      

Geochemical and geochronological characteristics of the Um Rus granite intrusion and associated gold deposit,Eastern Desert,Egypt

The Um Rus tonalite-granodiorite intrusion(~6 km2)occurs at the eastern end of the Neoproterozoic,ENE-trending Wadi Muba rak shear belt in the Central Eastern Desert of Egypt.Gold-bearing quartz veins hosted by the Um Rus intrusion were mined intermittently,and initially by the ancient Egyptians and until the early 1900 s.The relationship between the gold mineralization,host intrusion,and regional structures has always been unclear.We present new geochemical and geochronological data that help to define the tectonic environment and age of the Um Rus intrusion.In addition,field studies are integrated with EPMA and LA-ICP-MS data for gold-associated sulfides to better understand the formation and distribution of gold mineralization.The bulk-rock geochemical data of fresh host rocks indicate a calc-alkaline,metaluminous to mildly peraluminous,I-type granite signature.Their trace element composition reflects a tectonic setting intermediate between subduction-related and within-plate environments,presumably transitional between syn-and post-collisional stages.The crystallization age of the Um Rus intrusion was determined by in situ SHRIMP 206 Pb/238 U and 207Pb/235U measurements on accessory monazite grains.The resultant monazite U-Pb weighted mean age(643±9 Ma;MSWD 1.8)roughly overlaps existing geochronological data for similar granitic intrusions that are confined to major shear systems and are locally associated with gold mineralization in the Central Eastrn Desert(e.g.,Fawakhir and Hangaliya).This age is also consistent with magmatism recognized as concomitant to transpressional tectonics(D2:~650 Ma)during the evolution of the Wadi Mubark belt.Formation of the gold-bearing quartz veins in NNE-SSW and N-S striking fault segments was likely linked to the change from transpressional to transtensional tectonics and terrane exhumation(D3:620-580 Ma).The development of N-S throughgoing fault arrays and dike swarms(~595 Ma)led to heterogeneous deformation and recrystallization of the mineralized quartz veins.Ore minerals in the auriferous quartz veins include ubiquitous pyrite and arsenopyrite,with less abundant pyrrhotite,chalcopyrite,sphalerite,and galena.Uncommon pentlandite,gersdorffite,and cobaltite inclusions hosted in quartz veins with meladiorite slivers are interpreted as pre-ore sulfide phases.The gold-sulfide paragenesis encompasses an early pyrite-arsenopyrite±loellingite assemblage,a transitional pyrite-arsenopyrite assemblage,and a late pyrrhotite-chalcopyrite-sphalerite±galena assemblage.Free-milling gold/electrum grains(10 sμm-long)are scattered in extensively deformed vein quartz and in and adjacent to sulfide grains.Marcasite,malachite,and nodular goethite are authigenic alteration phases after pyrrhotite,chalcopyrite,and pyrite and arsenopyrite,respectively.A combined ore petrography,EPMA,and LA-ICP-MS study distinguishes morphological and compositional differences in the early and transitional pyrites(PyⅠ,PyⅡ)and arsenopyrite(ApyⅠ,ApyⅡ).Py I forms uncommon small euhedral inclusions in later PyⅡand Apy II.PyⅡforms large subhedral crystals with porous inner zones and massive outer zones,separated by narrow As-rich irregular mantles.The Fe and As contents in PyⅡare variable,and the LA-ICP-MS analysis shows erratic concentrations of Au(<1 to 177 ppm)and other trace elements(e.g.,Ag,Te,and Sb)in the porous inner zones,most likely related to discrete sub-microscopic sulfide inclusions.The outer massive zones have a rather homogenous composition,with consistently lower abundances of base metals and Au(mean 1.28 ppm).The early arsenopyrite(Apy I)forms fine-grained euhedral crystals enriched in Au(mean 17.7 ppm)and many other trace elements(i.e.,Ni,Co,Se,Ag,Sb,Te,Hg,and Bi).On the other hand,ApyⅡoccurs as coarsegrained subhedral crystals with lower and less variable concentrations of Au(mean 4 ppm).Elevated concentrations of Au(max.327 ppm)and other trace elements are measured in fragmented and aggregated pyrite and arsenopyrite grains,whereas the undeformed intact zones of the same grains are poor in all trace elements.The occurrence of gold/electrum as secondary inclusions in deformed pyrite and arsenopyrite crystals indicates that gold introduction was relatively late in the paragenesis.The LAICP-MS results are consistent with gold redistribution by the N-S though-going faults/dikes overprinted the earlier NNW-SSE quartz veins in the southeastern part of the intrusion,where the underground mining is concentrated.Formation of the Um Rus intrusion and gold-bearing quartz veins can be related to the evolution of the Wadi Mubarak shear belt,where the granitic intrusion formed during or just subsequent to D2 and provided dilatation spaces for gold-quartz vein deposition when deformed by D3 structures.     

赣南狮吼山硫铁多金属矿区花岗岩地球化学、年代学特征及其成因

狮吼山矿区是江西省内规模最大的矽卡岩型硫铁多金属矿床，伴生W、Cu、Au多种成矿元素，成矿作用与矿区出露的茶山迳复式花岗岩体有关。岩体主要包括茶山迳似斑状黑云母二长花岗岩和莲湖细粒二长花岗岩两期，为研究成矿岩体的侵位时代、岩石成因及与成矿的关系，本次工作进行了U-Pb锆石定年、岩相学和岩石地球化学等测试分析。结果表明：岩体具有高硅、高钾、富铝的特征，属高钾钙碱性系列花岗岩；轻重稀土元素分馏明显，均为右倾型，弱Eu负异常，以富集Cs、Rb、Th、U、Pb，亏损Ba、Nb、Sr、和Ti等元素为主要特征，属于低Ba-Sr壳源花岗岩类；锆石具较好晶形，具典型岩浆锆石特征，利用LA-ICP-MS进行U-Pb测年，获得谐和年龄为（162.4±0.6）Ma（MSWD=1.8），加权平均年龄为（162.4±1.4）Ma（MSWD=1.4），谐和年龄与加权平均年龄在误差范围内高度一致，表明茶山迳复式岩体侵位于燕山早期中侏罗世；综合考虑岩体矿物组合、主微量元素及高分异特征，认为其成因分类应属于S型花岗岩；对比中国花岗岩成矿元素平均含量，茶山迳两期花岗岩均具有较高的W、Mo、Bi、Pb等成矿元素含量，可同时为成矿作用提供热源、流体及物质。     

华北板块北缘勃隆克A型花岗岩锆石U-Pb定年及其地质意义

内蒙古翁牛特旗勃隆克岩体位于华北板块北缘,侵位于上侏罗系火山岩地层中。详细的岩相学研究显示,勃隆克花岗岩具有粒状结构、蠕虫结构和文像结构,块状构造,部分斜长石已绢云母化、泥化。对勃隆克花岗岩进行了LA-ICP-MS锆石U-Pb定年,获得134.0±1.8Ma和134.9±4.1Ma的侵位年龄,表明其形成于早白垩世。地球化学特征显示,花岗岩属于高钾钙碱性系列,有较高的SO2(74.1%~75.6%)、Na2O+K2O(8.98%~9.2%)、Rb(210×10-6~225×10-6)含量和10000×Ga/Al(2.69~2.80)、Rb/Sr(5.8~18.9)值,具有较低的CaO、MgO、Ba和Sr含量。铝饱和指数A/CNK=0.99~1.03,属于偏铝质或过铝质A型花岗岩。稀土元素球粒陨石标准化图解显示,轻稀土元素相对富集,负Eu异常明显;在原始地幔标准化图解上,Ba、Sr、Nb、Ta、P、T强烈亏损,富集Rb、Th、K、Hf等元素,与华北板块北缘早白垩世A型花岗岩类似。结合区域构造演化,认为勃隆克花岗岩形成于伸展构造背景。晚中生代,华北板块北缘构造体制经历了重大的转变,地壳从挤压体制转为岩石圈减薄和地壳伸展体制,软流圈物质上涌导致上覆地壳长英质物质的部分熔融形成勃隆克A型花岗岩。     

天津蓟州东水厂中元古代高于庄组凝灰岩锆石SHRIMP U-Pb年龄 ——对中元古代生物-环境事件的制约

对华北克拉通北缘中-新元古界标准剖面的高于庄组第三亚组(张家峪亚组)下部凝灰岩样品进行了锆石SHRIMP U-Pb定年,获得~(207)Pb/~(206)Pb加权平均年龄1 582±12 Ma。该凝灰岩层厚度约15 cm,层位介于高于庄组第三亚组下部"瘤状灰岩"层与含宏观藻类化石(Parachuaria glabra.)层之间,紧邻藻类化石层。该地层时代为高于庄组属于国际中元古界盖层系(Calymmian System)下部层位提供了新依据,为中元古代高于庄组全球生物-环境事件及全球对比提供了重要约束。     

福建北部近岸东台山岛火山岩形成时代、地球化学与古太平洋板块俯冲的响应

福建北部沿岸岛屿岩石组合以晚中生代火成岩为主，研究认为是古太平洋俯冲消减的产物，对反演洋盆构造演化具有重要的指示意义。本次对其中的福建北部海域东台山岛上广泛发育的酸性火山岩进行了锆石U-Pb定年以及全岩主微量地球化学分析工作。2件年代学样品分别获得了92 Ma和86 Ma的锆石U-Pb年龄，确定东台山岛火山岩形成于晚白垩世。全岩地球化学特征指示火山岩样品以酸性钙碱性岩石为主，整体富集Rb、Ba等元素，亏损Nb、Ta、Sr、Eu等元素，显示弧型岩浆岩的地球化学组成。研究认为东台山岛火山岩起源于古老下地壳变沉积岩熔融，并在浅层岩浆房内经历了不同程度的结晶分异过程。结合区域上晚中生代岩浆作用由陆向海的时空迁移特征，福建北部沿岸岛屿火山岩形成的深部动力学机制应该与古太平洋俯冲过程中的板片回转过程相关。     

湘东北新元古代冷家溪群沉积岩的地球化学特征和碎屑锆石U-Pb年代学

江南造山带已被普遍接受为是由扬子陆块与华夏陆块在新元古代碰撞拼合而形成，正确理解江南造山带形成机制是探索华南前寒武纪地质演化的前提，也是深入剖析华南显生宙构造演化的重要因素，但是人们对其拼贴时限及构造属性仍存在争议.沉积岩的矿物组成及地球化学特征可以对其沉积物源及形成的构造背景起到很好的指示作用.然而，前人多聚焦于岩浆岩的地球化学－年代学研究或地层中碎屑锆石的年代学研究，江南造山带新元古代沉积物的物源示踪研究相对薄弱.针对江南造山带中段平江地区冷家溪群中段小木坪组及黄浒洞组沉积岩开展了详细的岩石学、地球化学和锆石U-Pb年代学研究，结果表明，这些样品具有较高的SiO₂（58.82%~70.62%，平均为64.68%）和Al₂O₃（13.35%~20.99%，平均为16.78%），高的Al₂O₃/（CaO+Na₂O）（3.8~12.4，平均6.6）、K₂O/Na₂O（0.95~3.20，平均1.8）、La/Sc（2.0~2.7）、Th/Sc（0.84~0.86）比值，与此同时，具有较低的CaO、MgO和Na₂O含量（分别为0.19%~2.85%、1.43%~2.13%、和1.44%~2.27%）和Co/Th（0.83~5.30）比值.同时，这些沉积岩富集轻稀土元素（LREE），具有明显的铕负异常（Eu/Eu*=0.62~0.69），与澳大利亚后太古代页岩（PAAS）的稀土元素配分模式相似.其中两件定年样品的碎屑锆石最小年龄峰值分别为856 Ma和860 Ma.综合前人研究成果，江南造山带冷家溪群沉积岩来自于中酸性火成物源区，并经历了快速剥蚀和较弱的风化过程，在860~830 Ma时处于活动大陆边缘的构造环境中.      

大兴安岭南部二叠系—三叠系界线及沉积环境演化

北方陆相二叠系—三叠系界线研究是界线地层研究的重要问题之一,对采自内蒙古巴林右旗幸福之路组二段建组剖面的安山质岩屑晶屑凝灰岩开展锆石LA-ICP-MS U-Pb测年,结果为(255.5±1.1)Ma,火山岩上部多个层位粉砂质泥岩中发现孢粉化石,计17属20种,时代为晚二叠世—早三叠世,推断幸福之路组的时代为晚二叠世—早三叠世,大兴安岭地区二叠系—三叠系界线在幸福之路组内部,二者为整合接触。幸福之路组以红层做为划分标志,岩性为正常沉积碎屑岩夹火山岩,见大量泥灰岩夹层、钙质结核及干裂现象,反映了炎热、干燥及强氧化条件的气候环境,大兴安岭地区晚二叠世晚期(幸福之路组二段下部)就已出现反映干旱气候的红层沉积,与相邻的华北及新疆准噶尔盆地相似。     

北淮阳东段山七岩体地球化学特征、LA-ICP-MS 锆石U-Pb年龄及地质意义

北淮阳东段山七岩体岩性为石英闪长岩,SiO₂、Al₂O₃含量中等,富碱质,Mg^#低,具偏铝质碱性系列岩石特征。稀土元素含量中等,La_N/Yb_N值和LREE/HREE值均较大,HREE相对于LREE明显亏损,具较弱的Ce负异常,轻稀土相对富集,分馏较明显,重稀土分馏不明显。岩石富集大离子亲石元素(LILE)Rb、Ba、K和高场强元素(HFSE)Zr、Hf、Y,明显亏损Nb、Ta、Ti、P、U。通过LA-ICP-MS锆石U-Pb定年,获得山七岩体²⁰⁶Pb/²³⁸U年龄为128.2±3.3Ma,属早白垩世早期。主量元素及微量元素地球化学特征均表明山七岩体岩浆来源于地壳,受地幔物质混染。     

徐州贾汪地区暗色岩锆石U-Pb年龄及金刚石成因探讨

对徐州贾汪地区暗色岩进行锆石U-Pb年龄测定,结合该区地质构造背景和华北板块金伯利岩岩浆活动期次特征,探讨暗色岩中的金刚石成因及成矿前景。研究表明:该区暗色岩分布时代跨度较大,从新元古代至中生代甚至新生代,几乎每个重要的岩浆活动期均有暗色岩。北许阳辉绿岩中的金刚石应来源于幔源岩浆结晶,但不具备金刚石找矿前景; 西村金伯利岩具有一定的金刚石找矿前景,但其含矿性比山东金伯利岩差; 从物质成分上看,燕山晚期—喜山期玄武玢岩具有一定的金刚石找矿前景。结合该区深部地质条件,认为该区具有基性岩上升过程中携带金刚石矿层的条件及新生代金伯利岩产出的可能性,但较高的大地热流值对金刚石保存不利。