Effect of fiber orientation on the structural behavior of FRP wrapped concrete cylinders

In this study, 27 concrete cylinders with a diameter of 152.4 and a height of 304.8 mm were prepared. Among them, 18 cylinders were wrapped using two layers of fiber reinforced polymer (FRP) with six fiber orientations; six cylinders were wrapped using four layers of FRP with fibers in axial or hoop direction only; the remaining three cylinders were used as control. The FRP used was E-glass fiber reinforced ultraviolet (UV) curing vinyl ester. Fifteen coupon specimens were prepared to experimentally determine the tensile strength of the FRP with fibers oriented at 0°, 45°, and 90° from the loading direction. Co-axial compression tests were conducted on the wrapped cylinders and control cylinders. The test results were compared with existing confinement models. It is found that the strength, ductility, and failure mode of FRP wrapped concrete cylinders depend on the fiber orientation and wall thickness. Fibers oriented at a certain angle in between the hoop direction and axial direction may result in strength lower than fibers along hoop or axial direction. A larger database is desired in order to refine the existing design-oriented confinement models.     

Interpretation of Temperature-Dependent Resistivity of La–Pb–MnO3: Role of Electron–Phonon Interaction

The present paper deals with the theoretical investigation of temperature-dependent resistivity of the perovskite manganites La_0.78Pb_0.22MnO_3-δ within the framework of the classical electron–phonon model of resistivity, i.e., the Bloch–Gruneisen model. Due to inherent acoustic (low-frequency) phonons (ω_ac) as well as high-frequency optical phonons (ω_op), the contributions to the electron–phonon resistivity have first been estimated. At low temperatures the acoustic phonons of the oxygen-breathing mode yield a relatively larger contribution to the resistivity as compared to the contribution of optical phonons. Furthermore, the nature of phonons changes around T = 215 K exhibiting a crossover from an acoustic to optical phonon regime with elevated temperature. The contribution to resistivity estimated by considering both phonons, i.e., ω_ac and ω_op, when subtracted from experimental data, infers a T^4.5 temperature dependence over most of the temperature range. Deduced T^4.5 temperature dependence of ρ_diff = [ρ_exp − {ρ₀ + ρ_e-ph( = ρ_ac + ρ_op)}] is justified in terms of electron–magnon scattering within the double exchange (DE) process. Within the proposed scheme, the present numerical analysis of temperature dependent resistivity shows similar results as those revealed by experiments     

Robust Algorithms for Object Localization

Model-based localization, the task of estimating an object's pose from sensed and corresponding model features, is a fundamental task in machine vision. Exact constant time localization algorithms have been developed for the case where the sensed features and the model features are the same type. Still, it is not uncommon for the sensed features and the model features to be of different types, i.e., sensed data points may correspond to model faces or edges. Previous localization approaches have handled different model and sensed features of different types via sampling and synthesizing virtual features to reduce the problem of matching features of dissimilar types to the problem of matching features of similar types. Unfortunately, these approaches may be suboptimal because they introduce artificial errors. Other localization approaches have reformulated object localization as a nonlinear least squares problem where the error is between the sensed data and model features in image coordinates (the Euclidean image error metric). Unfortunately, all of the previous approaches which minimized the Euclidean image error metric relied on gradient descent methods to find the global minima, and gradient descent methods may suffer from problems of local minima. In this paper, we describe an exact, efficient solution to the nonlinear least squares minimization problem based upon resultants, linear algebra, and numerical techniques. On a SPARC 20, our localization algorithm runs in a few microseconds for rectilinear polygonal models, a few milliseconds for generic polygonal models, and one second for generalized polygonal models (models composed of linear edges and circular arcs).     

Perspective model-based visual tracking scheme for robust tracking of objects in complex environs

Multimedia Tools and Applications - Robust tracking of moving objects is still an open problem in computer vision. The problem and its difficulty depend on many factors, which includes the...     

Development of Phospholipids Vesicular Nanocarrier for Topical Delivery of Tea Tree Oil in Management of Atopic Dermatitis Using BALB/c Mice Model

This work aims to develop and evaluate the efficacy of tea tree oil (TTO) ethosomal cream with improved deposition in skin layers for treatment of atopic dermatitis (AD). Ethosomes of TTO are developed using phosphatidylcholine (2% and 3% w/v) and ethanol (20%, 30%, and 40% w/v). Ethosomes are evaluated for percent entrapment efficiency (%EE), vesicle size, zeta potential, and in vitro drug diffusion. Ethosomal creams with optimized ethosomal dispersion are developed and evaluated for physicochemical parameters, thermal stability, ex vivo permeation, skin retention, and in vitro cytotoxicity using HaCat skin cell lines in comparison to conventional creams of TTO. In vivo investigations of optimized creams are performed using BALB/c mice model. The %EE, vesicle size, and zeta potential for optimized ethosomes are found to be 76.19 ± 3.26%, 333.6 nm, and –35.3 mV, respectively. Ethosomal creams showed higher deposition in the epidermis and dermis. The optimized creams are non-cytotoxic to HaCat cell lines. The creams significantly reduce the inflammatory response by decreasing the clinical score and infiltration of white blood cells, eosinophils, and IgE antibodies. Overall efficacy of ethosomal cream is higher than conventional cream. In conclusion, optimized ethosomal cream of TTO shows good efficacy for treatment of AD. Practical applications : The method used for the formulation of ethosomes is simple and can be easily scaled up on the industrial level. The loading of TTO within ethosomes can increase the efficiency by enhanced drug deposition in the epidermis and might also improve its stability against oxidative degradation. Topical ethosomal cream of TTO can improve patient compliance by avoidance of adverse effects linked with corticosteroids and could be a possible complementary or alternative therapy in management of AD.     

ACMICS: an agent communication model for interacting crowd simulation

Behavioral plausibility is one of the major aims of crowd simulation research. We present a novel approach that simulates communication between the agents and assess its influence on overall crowd behavior. Our formulation uses a communication model that tends to simulate human-like communication capability. The underlying formulation is based on a message structure that corresponds to a simplified version of Foundation for Intelligent Physical Agents Agent Communication Language Message Structure Specification. Our algorithm distinguishes between low- and high-level communication tasks so that ACMICS can be easily extended and employed in new simulation scenarios. We highlight the performance of our communication model on different crowd simulation scenarios. We also extend our approach to model evacuation behavior in unknown environments. Overall, our communication model has a small runtime overhead and can be used for interactive simulation with tens or hundreds of agents.     

Oxime-Modified Aluminum(III) Isopropoxide: A Promising Sol–Gel Precursor for Corrosion Resistive Nano-Alumina Coating on an Aluminum Alloy

Protection of Metals and Physical Chemistry of Surfaces - Dense alumina coatings were fabricated over aluminum alloy via dip coating method using oxime-modified aluminum(III) isopropoxide as a...     

Graphene-based electrocatalysts: Hydrogen evolution reactions and overall water splitting

Recently, carbon-based materials (e.g., graphene, carbon nanotubes, carbon quantum dots) have been used as electrocatalysts to catalyze the reactions such as hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and oxygen reduction reaction (ORR). Among them, graphene has attracted attention as an electrocatalyst, and its electrocatalytic performances have been improved by doping with metals and non-metals, surface and defect engineering, and hybrid development. In this perspective, the present paper reviewed the recent advances (2018 onwards) on the progress of graphene-based electrocatalysts for HER and overall water splitting (OWS). It is emphasizing strategies for optimizing electrocatalytic properties followed by challenges and future outlook. This review will provide the essential ideas and strategies that can help design graphene-based electrocatalysts of high performance that can be implemented for sustainable energy application.     

Metal organic frameworks as electrocatalysts: Hydrogen evolution reactions and overall water splitting

The development of clean energy technologies to protect the environment is an important demand of the times. Electrocatalysis is emerging as a promising method for evolution of hydrogen and overall water splitting. Nowadays, metal organic frameworks (MOFs) have emerged as electrocatalysts having uniformly distributed active sites and high electrical conductivity. This review summarizes the latest advances in heterogeneous catalysis by MOFs and their composite/derivatives for efficient hydrogen evolution reaction (HER) and water splitting. Pristine MOFs with their recent development are summarized first followed by composites of MOFs with their enhanced electrocatalytic performances. Overall water splitting by using bifunctional electrocatalysts derived from MOFs with different synthetic approaches is provided and this review gives the metal-based categorisation of precursor MOFs. Different strategies to improve chemical stability, conductivity, and overall electrocatalytic properties have been discussed. In the last, perspectives on the synthesis of efficient MOF-based electrocatalyst materials are provided.