A facile method for preparation of PGS@ZB‐N and gas‐sol alternating synergistic effect for fire resistance of EVA

Through the simple precipitation of palygorskite (PGS) by zinc borate (ZB) (to make PGS@ZB) and the decoration of PGS@ZB by dodecylamine (N), a novel organic‐inorganic@inorganic hybrid flame retardant of PGS@ZB‐N was prepared and was incorporated with ethylene vinyl acetate copolymer (EVA) to improve its flame retardance. The structure and morphology of PGS@ZB‐N were characterized by Fourier transform infrared (FTIR) spectroscopy, X‐ray diffraction (XRD), and scanning electron microscopy (SEM), and it was confirmed that the PGS@ZB‐N hybrid had been successfully prepared. The flame retardancy and burning behavior of EVA/PGS@ZB‐N/EG (EG = expandable graphite) composite were studied through thermogravimetric analysis (TGA), limiting oxygen index (LOI), UL‐94 (by the vertical burning test), and cone calorimeter test (CCT) characterizations. The prepared EVA/PGS@ZB‐N/EG composite obtained an LOI value of 41.2% with the addition of 30 wt% PGS@ZB‐N/EG. It was found that EVA/PGS@ZB‐N/EG was protected through a gas phase and condensed phase alternating synergistic effect mechanism.     

Single-Crystalline TiO2(B) Nanobelts with Unusual Large Exposed {100} Facets and Enhanced Li-Storage Capacity

The {100} facet of single-crystalline TiO₂(B) is an ideal platform for inserting Li ions, but it is hard to be obtained due to its high surface energy. Here, the single-crystalline TiO₂(B) nanobelts from H₂Ti₃O₇ with nearly 70% {100} facets exposed are synthesized, which significantly enhances Li-storage capacity. The first-principle calculations demonstrate an ab in-plane 2D diffusion through the exposed {100} facets. As a consequence, the nanobelts can significantly accommodate Li ions in LiTiO₂ formula with specific capacity up to 335 mAh g⁻¹, which is in good agreement with the electrochemical characterizations. Coating with conductive and protective poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate), the cut-off discharge voltage is as low as 0.5 V, leading to a capacity of 160.7 mAh g⁻¹ after 1500 cycles with a retention rate of 66% at 1C. This work provides a practical strategy to increase the Li-ion capacity and cycle stability by tailoring the crystal orientation and nanostructures.     

Skidding analysis of angular contact ball bearing subjected to radial load and angular misalignment

Journal of Mechanical Science and Technology - Skidding is a phenomenon that frequently occurs in ball–raceway contact areas of bearings and often leads to their early failure. This paper...     

Influences of gap pressure on machining performance in radial ultrasonic rolling electrochemical micromachining

Microdimples as a typical surface texture has been widely used for improving the properties in tribology and heat transfer fields. Ultrasonically assisted     

Synthesis of highly efficient,structurally improved Li4SiO4 sorbents for high-temperature CO2 capture

Li₄SiO₄ sorbents for high-temperature CO₂ removal have drawn extensive attention owing to their potential application in carbon capture and storage (CCS). The major challenge in the application lies in the poor CO₂ capture performance under realistic conditions of low CO₂ concentrations, owing to the dense structure and poor porosity. In this work, Li₄SiO₄ sorbents were prepared with porous micromorphologies and large contact areas using a variety of organometallic Li-precursors, achieving fast CO₂ sorption kinetics, high capacity and excellent cyclic stability at a low CO₂ concentration (15?vol%). It was found that a high conversion of ~?74% was maintained for pure Li₄SiO₄ even after 100 sorption/desorption cycles. Moreover, by doping with Na₂CO₃ to reduce the CO₂ diffusion resistance, the conversion of the sorbent was further enhanced to 93.2%. The enhancement mechanism of alkali carbonate have been proven here to be ascribed to the formation of the eutectic melt of Li/Na carbonates, the existence and function of which has been confirmed in this study.     

浅析HPT250轧机中滑移系数对轧制过程的影响

通过HPT250轧机在技术改造中遇到的一个问题，即滑移系数对冷轧元缝钢管在轧制过程中所起的作用。在实际生产中经过不断的技术研究和改进。使闲置多年的HPT250轧机为钢管公司的生产迭拉起到很大的作用。     

炼油达标污水回用处理试验研究

采用曝气生物滤池、多介质过滤、超滤、反渗透工艺,对炼油达标外排污水进行回用处理中试试验。结果表明,曝气生物滤池对油、COD和浊度去除效果良好,超滤、反渗透膜化学清洗周期达到 2个月以上,脱盐率稳定在98％以上,产水品质达到回用要求。     

新型高相对分子质量阳离子聚丙烯酰胺的合成

研究了采用复合引发体系,以丙烯酰胺为单体,丙烯酰氧乙基三甲基氯化铵(DAC)为阳离子功能单体,共聚合制备高相对分子质量的阳离子聚丙烯酰胺的方法。考察了单体含量、阳离子单体类型、聚合体系pH、助溶剂用量、复合引发体系中氧化剂、还原剂和偶氮化合物配比及用量、烘干温度对共聚物产品性能的影响。结果表明,在单体含量30％、DAC为阳离子单体、聚合体系pH 3．0、助溶剂用量占单体用量4％-5％、复合引发体系氧化剂、还原剂和偶氮化合物体积配比为1:1:1,烘干温度90℃以下条件下,可合成相对分子质量为(1000-1200)×104、阳离子度为 30％的阳离子聚丙烯酰胺产品。     

基于多线程技术的监控系统的设计

详细介绍在32位操作系统Windows95／98下，用C Builder3．0开发基于多线程技术的监控系统的有关方法。