Raman spectral study of poly(p-phenylene) and related oligomers

Raman spectroscopy was used to study the structure of two samples of poly(p-phenylene) (PP) and related oligomers. The ratio of the intensities of the bands at 1600 and 1280 cm^–1 increases linearly with extension of the chain and may be used for characterization of these macromolecules. Quinoid forms were found for heat-treated samples of PP and dodecaphenyl. These forms are apparently related to the effect of catalyst residues and subsequent heating.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2167–2170, September, 1990.     

Identification of absorption bands corresponding to C-C1 stretching vibrations in the IR spectra of organic compounds

Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 55, No. 3, pp. 392–396, September, 1991.     

Measurement of the ϕ → π0 e + e − decay probability

The measurement of the ? → π⁰ e ⁺ e ^? conversion decay probability on the SND detector at the VEPP-2M e ⁺ e ^? collider gave the value Br(? → π ⁰ e ⁺ e ^?) = (1.01 ± 0.28 ± 0.29) × 10^?5.     

Experimental study of the decay φ→ηγ in multiphoton final state

The φ(1020)→ηγ→3π ⁰ γ decay is studied in the SND experiment at the VEPP-2M e ⁺ e ⁻ collider. The measurements give a branching ratio Bφ→ ηγ)=(1.246±0.025±0.057)%. Pis’ma Zh. éksp. Teor. Fiz. 68, No. 7, 549–551 (10 October 1998) Published in English in the original Russian journal. Edited by Steve Torstveit.     

Analysis of e + e −→π+π−π+π− and e + e −→π+π−π0π0 processes in the energy range of \sqrt 2 = 0.98 - 1.38 GeV in experiments with a spherical neutral detector

The cross sections of the e ⁺ e ^?→π⁺π^?π ⁺π^?, e ⁺ e ^?→π⁺π^?π⁰π ⁰, and e ⁺ e ^?→ωπ→ π⁺π^?π ⁰π⁰ processes, as well as the e ⁺ e ^?→π⁺π^?π⁰π⁰ process with subtracted contribution of the ωπ intermediate state, are measured in experiments with a spherical neutral detector on the VEPP-2M collider in the energy range 0.98–1.38 GeV. About 41 000 events of the e ⁺ e ^?→π⁺π^?π⁺π ^? process and more than 54 000 events of the e ⁺ e ^?→π⁺π ^?π⁰π⁰ process have been selected in experiment. The statistical error in determining the cross section is 2–20%, while the systematic error is 7 and 8%.     

Search for e + e − → f 0(600)γ, f 0(980)γ, f 0(1350)γ, and f 2(1270)γ processes in the energy range from 1.05 to 1.38 GeV

In the energy range from 1.05 to 1.38 GeV, the upper limits for the cross sections of e ⁺ e ^? → f ₀(600)γ, f ₀(980)γ, f ₀(1350)γ, and f ₂(1270)γ → π⁰π⁰γ processes have been established. Measurements are performed in accordance with the statistics gathered in experiment with a spherical neutral detector (SND) on the VEPP-2M e ⁺ e ^? collider. The resultant upper limits vary from 6 to 42 pb depending on the energy and the model.     

Donor-acceptor interaction and intramolecular proton transfer in aminopolyenes

The influence of donor and acceptor substituents at chain termini on the geometry of the chain and charge distribution on atoms was studied for the ground and lower triplet electronically excited state of model ω-dimethylaminopolyene molecules (CH₃)₂N(CH=CH) _n CH=C(CN)₂, n = 1–3. Calculations were performed by the B3LYP/6-31+G** method. The influence of substituents on bond lengths and the amplitude of deviations from the equilibrium carbon-carbon bond length in unsubstituted polyenes increased as the conjugation chain grew longer. The deviations of the effects of both donor and acceptor groups from additivity, however, decreased. In the lower triplet electronically excited state of the molecule, the effect of substituents on changes in C-C bond lengths along the chain was not damped. The section of the potential energy surface for intramolecular proton shift from the donor amino to the acceptor nitrile group in “cyclic” (cis) conformers of the H₂N-CH=CH-CN and H₂N-CH=CH-CH=CH-CN molecules was analyzed. The structure of the reaction transition state and the height of the barrier to proton transfer were calculated.     

Measurement of the ω, ρ → π0 e + e − branching fractions

The e ⁺ e ^? → ω, ρ → π⁰ e ⁺ e ^? processes have been investigated in the experiments with Spherical Neutral Detector at the VEPP-2M e ⁺ e ^? collider. The measurements provide the probability ?(ω → π⁰ e ⁺ e ^?) = (0.761 ± 0.053 ± 0.064) × 10^?3 of the ω → π⁰ e ⁺ e ^g- conversion decay and the upper limit ?(ρ → π⁰ e ⁺ e ^?) < 1.2 × 10^?5 (at 90% CL) for the ρ → π⁰ e ⁺ e ^? decay. The transition form factor was measured at three values of the 4-momentum transfer squared.     

The e + e −→π0π0γ process below 1.0 GeV

The e ⁺ e ^?→π⁰π⁰ γreaction was studied in the energy range 0.36–0.97 GeV on a VEPP-2M e ⁺ e ^? collider with an SND detector. The decay probabilities were found to be B(ω→ π⁰π⁰γ)= (7.8 ±2.7±2.0)×10^?5 and B(π→ π⁰π⁰γ)= (4.8 _?1.8 ^+3.4 ±0.2)×10^?5.