加权EIV模型的经典最小二乘算法

采用GHM方法将EIV模型在最优解处线性化，得到解的近似方差。然后，将EIV模型表达成与Gauss-Markov模型相似的形式，利用标准最小二乘理论推导EIV模型的解及近似方差矩阵，得到与已有算法等价的结论。最后，推导观测值估值和残差的统计性质，建立起一整套EIV模型参数估计和精度评定的体系。     

太平洋深海沉积物来源的菌株Tenacibaculum sp.HMG1对孔雀石绿降解特性的研究

本文在太平洋深海沉积物中分离得到一株孔雀石绿降解菌株，鉴定命名为Tenacibaculum sp.HMG1。通过菌株生长实验和高效液相色谱的研究表明， HMG1菌株可以在20 mg/L的孔雀石绿中维持较快的生长速率，并且在12 h内可降解98.8%的孔雀石绿，这证明该菌株具有很高的孔雀石绿耐受能力和降解活性。通过基因组测序在HMG1菌株发现一条过氧化物酶基因可能参与了孔雀石绿的降解，随后利用原核表达获得了相应的重组蛋白。实验表明，该重组过氧化物酶具有极强的活性，可在1000 mg/L的孔雀石绿中发挥降解功能。本文利用液相色谱-质谱联用（LC-MS）技术对孔雀石绿的菌株降解产物和重组酶降解产物进行鉴定，并基于鉴定结果推测了两种降解途径。结果发现两种降解方式存在共同的降解途径。此外，孔雀石绿降解条件的实验结果证明重组过氧化物酶可以在低温（20℃）、复杂的pH值（6.0–9.0）、高盐度（100 mmol/L）、金属离子和EDTA等反应条件下依旧维持很高的孔雀石绿降解活性。以上实验结果表明，HMG1菌株和重组过氧化物酶均在孔雀石绿污染生物修复方面具有很大潜力。     

基态位涡径向分布对浅水涡旋系统演变的影响分析Part Ⅱ:扰动发展和结构变化

本文在基态位涡（Potential Vorticity，PV）径向分布和基态涡旋强度对热带气旋（Tropical Cyclone，TC）类涡旋系统稳定性特征影响的研究基础上，结合理想试验和数值模拟诊断分析基态PV径向分布对扰动增长和系统结构变化的影响.基于线性正压浅水模型，设计三种典型基态PV中空结构下基态涡旋强度对系统稳定性影响的敏感性试验.结果表明：基态涡旋的强度主要影响稳定性的强弱，强度越强，不稳定增长率越大，而基态PV径向分布对系统最不稳定波动性质起着决定作用.分析不同波数下扰动的发展及不同波数间扰动的相互作用可知，对于宽且实的PV环，系统稳定性主要取决于低波数不稳定，且最不稳定波数扰动的发展具有明显的优势地位；对于窄且空的PV环，系统稳定性主要取决于高波数不稳定，且多个高波数下增长最快模态的不稳定增长率值十分接近.利用模态线性叠加法讨论扰动增长对系统结构变化的影响表明：最不稳定波数的扰动发展对系统结构变化有关键影响，而多个波数的扰动不稳定增长相当时，不同波数的扰动发生相互作用从而影响系统结构变化.最后，利用实际个例模拟资料分析基态PV径向分布及其变化对TC结构和强度的影响表明：TC内核区出现的多边形眼墙结构与当前时刻基态PV径向分布所决定的最不稳定波数有很好的对应关系，同时基态PV径向分布变化所反映出的系统动力稳定性强弱与TC强度发展阶段具有很好的相关性.     

Analytical and empirical models for predicting the drift capacity of modern unreinforced masonry walls

Displacement‐based seismic assessment of buildings containing unreinforced masonry (URM) walls requires as input, among others, estimates of the in‐plane drift capacity at the considered limit states. Current codes assess the drift capacity of URM walls by means of empirical models with most codes relating the drift capacity to the failure mode and wall slenderness. Comparisons with experimental results show that such relationships result in large scatter and usually do not provide satisfactory predictions. The objective of this paper is to determine trends in drift capacities of modern URM walls from 61 experimental tests and to investigate whether analytical models could lead to more reliable estimates of the displacement capacity than the currently used empirical models. A recently developed analytical model for the prediction of the ultimate drift capacity for both shear and flexure controlled URM walls is introduced and simplified into an equation that is suitable for code implementation. The approach follows the idea of plastic hinge models for reinforced concrete or steel structures. It explicitly considers the influence of crushing due to flexural or shear failure in URM walls and takes into account the effect of kinematic and static boundary conditions on the drift capacity. Finally, the performance of the analytical model is benchmarked against the test data and other empirical formulations. It shows that it yields significantly better estimates than empirical models in current codes. The paper concludes with an investigation of the sensitivity of the ultimate drift capacity to the wall geometry, static, and kinematic boundary conditions.     

C-RESPONSE OF GEOMAGNETIC DEPTH SOUNDING ON A 1D THIN SHELL MODEL

This paper tries to formulate the C-response of geomagnetic depth sounding(GDS)on an Earth model with finite electrical conductivity. The computation is performed in a spherical coordinate system. The Earth is divided into a series of thin spherical shells. The source is approximated by a single spherical harmonic P₁⁰ due to the spatial structure of electrical currents in the magnetosphere. The whole solution space is separated into inner and external parts by the Earth surface. Omitting displacement current, the magnetic field in the external space obeys Laplacian equation, while in the inner part, due to the finite conductivity, the electromagnetic fields obey Helmholtz equation. To connect the magnetic fields in the inner and external space, the continuity condition of magnetic fields is used on the Earth surface. The external magnetic fields are expressed by the inner and external source coefficients, from which a new parameter called C-response is computed from the inner coefficient divided by the external coefficient, thus normalizing the actual source strength. The inner magnetic fields in each layer can be recursively derived by the continuity boundary condition of both normal and tangential components of the magnetic field from the initial boundary condition at core-mantle-boundary. The consistency of our C-responses with that from a typical 1-D global model validates the accuracy of the proposed algorithm. Numerical results also show that the C-response estimated from the geomagnetic transfer function method will deviate exceeding 5%from the actual response at longer periods than about 10⁶s, which means that ignoring the curvature of the Earth at extreme long periods will make inversion result unreliable. Therefore, an accurate C-response should be computed in order to lay a solid foundation for reliable inversion.     

The role of fog,orography, and seasonality on precipitation in a semiarid,tropical island

Isotopes of water (²H/¹H and ¹⁸O/¹⁶O) are commonly used to trace hydrological processes such as moisture recycling, evaporation loss, and moisture source region and often vary temporally in a given region. This study provides a first‐ever characterization of temporally variable precipitation mechanisms of San Cristóbal Island, Galápagos. We collected fog, rain, and throughfall samples over three field seasons to understand the mechanisms driving seasonal‐ and event‐based variability in the isotopic composition of precipitation in Galápagos. We establish that fog is a common phenomenon in San Cristóbal, especially during the dry season, and we found that fog, compared with cocollected rainfall, is consistently enriched. We further suggest that the relative contribution of fog formed via different mechanisms (orographic, advective, radiation) varied seasonally. We found that the source region is the most dominant control of the isotopic composition of rainfall in the Galápagos at both the seasonal and event scales, but subcloud evaporative processes (the nontraditional manifestation of the amount effect) became a dominant control on the isotopic composition of rainfall during the dry season. Overall, our findings suggest that understanding seasonally variable water‐generating mechanisms is required for effective water resource management in San Cristóbal Island and other semiarid island ecosystems under current and future regimes of climate change.     

填充墙刚度影响的实测高层建筑增量动力分析

高层结构中的填充墙在地震作用下与周围结构构件之间的相互作用十分复杂,对建筑结构的整体抗震性能具有较大影响。然而我国规范在设计阶段通常不考虑填充墙对结构抗震性能的影响,统一采用周期折减系数来考虑其刚度变化引起的内力变化,因此准确评估填充墙对结构抗震性能的影响具有重要意义。本文在对一栋框-剪结构和一栋剪力墙高层建筑进行随机振动测试的基础上,利用Perform-3D对每栋高层分别建立了3种分析模型。其中对未考虑填充墙作用的结构模型,分别采取规范建议值和实测结果值两种方式进行周期折减。对通过添加斜撑单元来考虑填充墙作用的结构模型,利用环境激励测试识别获得的结构模态信息进行模型修正。对该3种模型进行了增量动力分析,探讨潜在危险性水平地震作用下填充墙对高层建筑抗震性能的影响。结果表明,填充墙增加了结构在弹性阶段的整体初始刚度,但随着地震动强度的增加逐渐丧失对结构刚度的贡献作用。相比考虑了填充墙作用的模型计算结果,规范建议的周期折减系数较为保守。同时研究发现,填充墙对高层框-剪结构的影响程度要比剪力墙结构大。     

Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.     

新冠肺炎疫情扩散与人口流动的空间关系及对中国城市公共卫生分类治理启示

人口流动影响新冠肺炎疫情传播与风险扩散。基于百度迁徙大数据和各省市区卫生健康委员会数据，结合地理信息技术，研究了2020年1月1日至3月5日136个城市新冠肺炎疫情扩散与武汉市人口流出的空间关系及其对我国城市公共卫生治理启示。研究表明：1）中国新冠肺炎疫情扩散过程具有阶段性特征，经历了疫情发生与隐性扩散、快速扩散与暴发、扩散遏制和扩散衰减4个阶段。2）研究时间段武汉市人口主要流向湖北省境内以及周边省市和北京、上海、广州、深圳等一线城市，具有地理邻近性和倾向区域中心城市的人口流入特征。受地理距离、时间成本、社会经济联系、境外输入等因素的影响，新冠肺炎疫情空间分布的不平衡性明显，长江中游城市群、京津冀城市群、长三角城市群、粤港澳大湾区和成渝城市群成为新冠肺炎疫情集中分布的重点区域，一些重点出入境口岸城市的新冠疫情扩散风险较大。3）新冠肺炎疫情扩散与人口流出之间具有较强的正向等级相关性。两者之间的空间关系可以分为8种调控类型，近90%的城市具有人口流入多、确诊病例数高或人口流入少、确诊病例数低的特征。其中，人口流入多、确诊病例数高的城市主要集中分布在湖北省境内以及中国重点城市群的中心城市，其防控压力来自人口流入多、确诊病例数高带来的疫情扩散风险；而人口流入少、确诊病例数低的城市分布较为分散，其防控的难点在于提高防控对策的精准性。我国疫情防控取得了显著成效，但随着时间的演进全球疫情形势反弹的不确定性仍然存在，外防输入、内防反弹的压力依然很重，现阶段乃至未来一段时期，疫情防控将伴随中国经济社会发展成为新常态。建议针对8种调控类型，从人口流动、交通和资源等引导与管控方面分类提出精细化的疫情防控策略，提升城市公共卫生治理能力。