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61.
脉冲激光沉积法制备氧化铋薄膜及其电化学性质研究 总被引:4,自引:0,他引:4
首次采用355nm脉冲激光沉积在不锈钢基片上制备了氧化铋薄膜,X—射线衍射(XRD)测试表明在基片温度为300℃,沉积时间为0.5h制备得到的Bi2O3薄膜具有四方结构,SEM和Raman光谱测定对该Bi2O3薄膜的表面形貌和锂化前后的结构进行了表征,结果表明薄膜由小于100nm针状晶粒组成,锂化后的产物可能是LixBi2O3。此外,由电位阶跃法测定了上述Bi2O3薄膜电极的锂离子扩散系数。电化学测定表明,上述Bi2O3薄膜具有充放电循环性能,在电压范围为0.70~3.5V,该氧化铋薄膜在充放电速率为2C时的比容量大约为100mAh/g,并且保持经100次以上充放电循环而没有明显的衰减。 相似文献
62.
LU Anhuai GAO Xiang QIN Shan & WANG ChangqiuDepartment of Geology Peking University Beijing . China Correspondence should be addressed to Lu Anhuai 《科学通报(英文版)》2003,48(9):920-923
The Xiangtan manganese deposit (XTM) used to be considered a supergene oxide manganese ore in South China. We reported a new identification of the naturally outcropping cryptomelane by examining the physical, chemical and structural features of the XTM supergene oxide manganese ore. The MnO2 content was over 90%, K2O more than 3%, and water from 2.2%-3.1% which is similar to one in zeolite. The cell parameters of the cryptomelane were given as a0 = 0.9974 nm, b0 = 0.2863 nm, c0 = 0.9693 nm and β= 91.47°. There was a larger pseduotetragonal tunnel in the natural cryptomelane that was formed by [MnO6] octahedral double chains with aperture of 0.462×0.466 nm2, filled with K cations resulting in some Mn3+ substituting for Mn4+ to balance the negative charges of structure. The finding is important not only for prospecting manganese resources in South China, but also in application of octahedral molecular sieve of natural cryptomelane as that developed in the tetragonal molecular sieve of natural zeolite o 相似文献
63.
利用斑点试验、点蚀试验、电化学测试及扫描电镜等方法 ,研究了熔敷温度、保温时间和稀土添加量等工艺参数对热熔敷法制备的玻璃涂层耐蚀性的影响 ,探讨了添加稀土提高玻璃涂层耐蚀性的机理。试验结果表明 ,采用热熔敷法制备的玻璃涂层有较好的耐蚀性。随着熔敷温度的提高和保温时间的延长 ,形成了一定量的晶相后会降低涂层的耐蚀性。试验结果表明 ,熔敷温度为 70 0℃、保温 5min后能够得到耐蚀性良好的玻璃涂层。添加稀土提高了釉料的软化温度和熔融釉料的粘度 ,阻止了结晶形核和晶核长大 ,减少了晶相 ,同时提高了涂层的电极电位 ,使涂层耐蚀性显著提高。当稀土含量为 2 %时 ,涂层的耐蚀性较好。 相似文献
64.
WANG Tieguan WANG Chunjiang ZHANG Weibiao SHI Quan ZHU Lei CHEN Junyuan 《自然科学进展(英文版)》2003,13(12):936-941
Totally 19 samples of typical Upper Proterozoic-Lower Cambrian sedimentary rocks were collected and analyzed for an organic geochemical investigation. Almost all these rocks have high TOCs, super-maturities and similar biomarker distribution. As an exception, however, the Sinian Nantuo Tillite shows much lower TOCs and little phytane and pristane in comparison with those in other strata, which implies a very faint photosynthetic process, and a restricted euphotic zone and quite limited sunlight within the sedimentary water column during the Sinian glaciation age in the western Yangtze region providing an evidence for palaeo-oceanic environment of the Neoproterozoic Snowball Earth age. 相似文献
65.
从黄土Sr同位素探讨海水87Sr/86Sr变化的原因 总被引:3,自引:1,他引:3
目前多数认为河流输入是引起海水^87Sr/^86Sr变化的最主要因素,对此推论并没有提供确实的定量分析和依据.通过对黄土高原洛川剖面黄土—古土壤Sr同位素组成和沉积速率等的定量计算说明,在过去2.5Ma期间,海水^87Sr/^86Sr上升总量仅是河流输人海洋总量的大约1/10,而其9/10被海底玄武岩的热液蚀变输入所抵消.海底玄武岩的热液蚀变输入对海水^87Sr/^86Sr变化的总影响量应近似等于河水输入对海水^87Sr/^86Sr变化的总影响量.海水^87Sr/^86Sr变化的原因是河水输入与海底玄武岩的热液烛变输入联合作用的结果. 相似文献
66.
HV/CVD Grown Relaxed SiGe Buffer Layers for SiGe HMOSFETs 总被引:2,自引:0,他引:2
High-vacuum/chemical-vapor deposition (HV/CVD) system was used to grow relaxed SiGe buffer layers on Si substrates. Several methods were then used to analyze the quality of the SiGe films. X-ray diffraction and Raman spectroscopy showed that the upper layer was almost fully relaxed. Second ion mass spectroscopy showed that the Ge compositions were step-graded. Transmission electron microscopy showed that the misfit dislocations were restrained to the graded SiGe layers. Tests of the electrical properties of tensile-strained Si on relaxed SiGe buffer layers showed that their transconductances were higher than that of Si devices. These results verify the high quality of the relaxed SiGe buffer layer. The calculated critical layer thicknesses of the graded Si1-xGex layer on Si substrate and a Si layer on the relaxed SiGe buffer layer agree well with experimental results. 相似文献
67.
Design and application of 60mer oligonucleotide microarray in SARS coronavirus detection 总被引:6,自引:0,他引:6
SHI Rong MA Wenli WU Qinghua ZHANG Bao SONG Yanbin GUO Qiuye XIAO Weiwei WANG Yan & ZHENG Wenling . Institute of Molecular Biology First Military Medical University Guangzhou China . Department of Medical Research Guangzhou Liu Hua Qiao Hospital Guangzhou China Correspondence should be addressed to Ma Wenli 《科学通报(英文版)》2003,48(12):1165-1169
In April 2003, a novel coronavirus[1,2] which was associated with cases of Severe Acute Respiratory Syn-drome (SARS) was first isolated and sequenced in Canada. The genome of SARS coronavirus (SARS-CoV) is 29727[3] nucleotides in length and has 11 known open reading frames (ORFs). Although the genome organiza-tion of this virus is similar to that of other coronaviruses, phylogenetic analyses and sequence alignment show that SARS-CoV is not closely related to any of the previously ch… 相似文献
68.
WANGPinxian JIANZhimin ZHAOQuanhong LIQianyu WANGRujian LIUZhifei WUGuoxuan SHAOLei WANGJiliang HUANGBaoqi FANGDianyong TIANJun LIJianru LIXianhua WEIGangjian SUNXiangjun LUOYunli SUXin MAOShaozhi CHENMuhong 《科学通报(英文版)》2003,48(23):2549-2561
As the third summary report of ODP Leg 184 to the South China Sea (SCS), this paper discusses the evolution of the East Asian monsoon and the SCS basin. A multi-proxy approach, involving geochemistry, micropale-ontology, pollen and other analyses, was adopted for reconstructing the evolutionary history of the East Asian monsoon, which was characterized by a series of paleo-climate events especially at 8, 3.2, 2.2 and 0.4 Ma. The new record indicates similar stages in the development of the East and South Asian monsoons, with an enhanced winter monsoon over East Asia being the major difference. The rich spectrums of monsoon variability from the southern SCS also reveal other characteristic features of the low latitude ocean. Evidence for the evolution of the SCS includes the hemipelagic Oligocene sediments, implying the existence of deep water environments during the early seafloor spreading stage of the SCS basin. The four major unconformities and some remarkabl ediagenetic features in upper Oligocene deposits indicate the strongest tectonic events in the region. From a careful comparison of lithologies and sedimentation rates, we conclude that the prominent differences in sedimentary environments between the southern and northern SCS were established only by ~3 Ma. 相似文献
69.
鄂尔多斯盆地低渗透油田注水开发的调整与优化 总被引:4,自引:0,他引:4
根据鄂尔多斯盆地成功开发的主要特低渗油田——安塞、靖安、华池油田长6、长3油层的储层特征及开发实践,提出了改善特低渗油田注水开发效果的注采参数、注水方式优化及调整技术,从而达到提高单井产量及最终采收率,降低开发投资和生产成本,以提高整体开发效益的目的. 相似文献
70.
DNA分子标记在果树上的应用 总被引:4,自引:0,他引:4
介绍了在果树上常用的DNA分子标记的原理和特点,并对其在果树的分子遗传图谱和指纹图谱的构建,品种鉴别、系谱分析和分类,基因定位与分子标记辅助选择等方面的应用进行了综述。 相似文献