Curing of epoxy systems at sub‐glass transition temperature

Three epoxy‐amine thermoset systems were cured at a low ambient temperature. Evolution of the reaction kinetics and molecular structure during cure at the sub‐glass transition temperature was followed by DSC and chemorheology experiments. The effect of vitrification and the reaction exotherm on curing and final mechanical properties of the epoxy thermosets was determined. Thermomechanical properties of the low‐temperature cured systems depend on the reaction kinetics and volume of the reaction mixture. Curing of the fast‐reacting system in a large volume (12‐mm thick layer) resulted in the material with T_g exceeding the cure temperature by 70–80°C because of an exothermal temperature rise. However, the reaction in a too large volume (50‐mm layer) led to thermal degradation of the network. In contrast, thin layers (1.5 mm) were severely undercured. Well‐cured epoxy thermosets could be prepared at sub‐T_g temperatures by optimizing reaction conditions. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 99: 3669–3676, 2006     

改进的可信网络连接机制

针对传统可信网络中存在会话密钥协商过程易受中间人攻击的不足,提出改进的可信网络连接机制。该机制基于椭圆曲线Diffie-Hellman（ ECDH）算法实现会话密钥的安全协商,用户与节点使用私钥和随机数完成会话密钥的计算。分析表明改进的密钥协商协议具有抗中间人攻击、高效性等特点,会话密钥具有前向安全性及较强的新鲜性和保密性。     

近红外分析网络共享平台中复杂工作流实现算法

近红外分析共享平台中的采集工作流是一个以数据为中心的工作流。对系统中复杂采集工作流的跳转执行过程进行了详细分析,针对自由工作流跳转造成的数据和状态不一致性的问题,提出了一个任务执行优先关系算法,计算采集工作流中各个活动任务执行次序关系值,并构造一个执行次序关系树,记录各任务活动的状态信息;在流程回退、撤销、跳转时保证了数据和状态的一致性,较好地实现了跨任务活动的跳转。应用结果表明,此算法能够正确高效地实现复杂流程的跳转。     

流程加工CAN测控网络的应用层协议研究

为提高CAN测控网络的适应性和通信效率,以CAN2.0A技术规范为基础,针对流程加工测控网络的特点,设计面向流程加工领域的CAN总线应用层协议ProCAN。在明确流程加工概念及范围的基础上,分析流程加工测控系统结构模型的特征,提出通信报文的类型,定义标准数据帧仲裁域与数据域的编码格式,并讨论ProCAN协议的通信模式、通信状态、通信异常及长报文误帧重传控制。利用OPNET网络仿真软件进行实验,结果表明,ProCAN协议能实现报文通信,并且具有延时短、实时性强、可靠性高的特点,尤其当网络负载较大时,效果更为明显。     

Biomimetic strain hardening in interpenetrating polymer network hydrogels

In this paper, we present the systematic development of mechanically enhanced interpenetrating polymer network (IPN) hydrogels with Young's moduli rivaling those of natural load-bearing tissues. The IPNs were formed by synthesis of a crosslinked poly(acrylic acid) (PAA) network within an end-linked poly(ethylene glycol) (PEG) macromonomer network. The strain-hardening behavior of these PEG/PAA IPNs was studied through uniaxial tensile testing and swelling measurements. The interaction between the independently crosslinked networks within the IPN was varied by (1) changing the molecular weight of the PEG macromonomer, (2) controlling the degree of PAA ionization by changing pH, and (3) increasing the polymer content in the PAA network. Young's moduli and the maximum stress-at-break of the swollen hydrogels were normalized on the basis of their polymer content. Strain hardening in the IPNs exhibited a strong dependence on the molecular weight of the first network macromonomer, the pH of the swelling buffer, as well as the polymer content of the second network. The results indicate that the mechanical enhancement of these IPNs is mediated by the strain-induced intensity of physical entanglements between the two networks. The strain can be applied either by mechanical deformation or by changing the pH to modulate the swelling of the PAA network. At pHs below the pK_a of PAA (4.7), entanglements between PEG and PAA are reinforced by interpolymer hydrogen bonds, yielding IPNs with high fracture strength. At pHs above 4.7, a “pre-stressed” IPN with dramatically enhanced modulus is formed due to ionization-induced swelling of the PAA network within a static PEG network. The modulus enhancement ranged from two-fold to over 10-fold depending on the synthesis conditions used. Variation of the network parameters and swelling conditions enabled “tuning” of the hydrogels' physical properties, yielding materials with water content between 58% and 90% water, tensile strength between 2.0 MPa and 12.0 MPa, and initial Young's modulus between 1.0 MPa and 19.0 MPa. Under physiologic pH and salt concentration, these materials attain “biomimetic” values for initial Young's modulus in addition to high tensile strength and water content. As such, they are promising new candidates for artificial replacement of natural tissues such as the cornea, cartilage, and other load-bearing structures.     

基于视频数据和传递熵的鱼群信息传递网络构建

鱼群中的个体如何通过信息传递从而达到一致的群体运动状态,至今还没有刻画这一现象的统一数学模型.本文阐述了一种利用视频数据和传递熵构建鱼群中个体间信息传递网络的方法.首先用实验获取斑马鱼集群的视频数据,并采用计算机视觉跟踪的方法获取鱼群中每个个体的位置和运动速度,然后利用传递熵计算个体两两之间的信息传递关系,在此基础上构建了鱼群信息传递网络.通过网络分析,揭示了鱼群中个体间的信息交互个数与信息传播速度之间的关系,进一步发现了鱼群信息传递网络中的频繁子结构.本文提供了一种利用探测时间序列间因果关系建立鱼群信息传递网络的方法,为鱼群信息传递研究提供了一种新的思路.     

基于无线传感网的智能环境监控系统设计

针对传统环境监控系统存在的缺点,设计了一种新型无线传感器网络的环境监控系统。系统采用分布式融合结构,通过终端节点的多种传感器采集环境信息,终端对信息预处理后实时将信息传输到协调器。协调器融合各终端传感器信息,提取精确信息上传至融合中心,融合中心通过分析数据发布命令给控制中心,控制中心利用单片机驱动电机可以自动或手动控制风机和水泵对环境进行调节和控制。同时,系统还具有自动预警功能。通过验证,该系统稳定、可靠,能广泛应用于不同领域的分布式多点环境监控。     

RGA-D：一种无线传感器网络覆盖优化方法

研究了无线传感器网络覆盖优化问题,针对传感器节点随机部署、分布不均,传统覆盖优化算法一般只考虑网络部署后单次优化的问题,提出基于节点冗余和覆盖集冗余的计算方法,用网络的局部特征表征全局特征,改进了网络覆盖模型。并在此基础上提出RGA-D算法,利用遗传算法计算覆盖集,同时考虑节点和覆盖集冗余度,对网络整个生存期进行全局优化。仿真实验表明,RGA-D算法能在活跃节点数和网络覆盖率之间达到平衡,解决了网络生存期后期容易出现覆盖盲区的问题。     

HiSLIP协议的研究与应用

为解决无LAN口仪器仪表网络接入问题,仪器的网络代理应运而生。当前网络代理的仪器控制机制主要基于TCP/UDP协议,仪器控制及网络传输数据效率较低,为此,IVI联盟制定了标准的仪器控制协议HiSLIP。通过对该协议的功能和交互过程的详细分析,根据协议规范实现协议的运行代码,并基于此协议设计出仪器网络代理,可以实现对支持VXI仪器的便捷网络接入和高效控制,降低通信时延和网络带宽对仪器测量的影响,满足网络化测控系统中对仪器实时性的要求。     

汽车胎压监测系统的设计及其通信抗干扰研究

针对大多数直接式汽车胎压监测系统组件集成度低、体积和功耗较大等问题,提出了一种基于短距离无线通信ZigBee技术的新型胎压无线监测系统的设计。主要采用TI的CC2530芯片和英飞凌SP12集成式数字传感器,实现对汽车轮胎内部状态的实时监测。采用软硬件协同设计以降低系统功耗,并通过多点轮询通信方式和ZigBee高级加密设置保障了其无线通信的抗干扰能力。