Some kinetic aspects of unsteady-state partial oxidation reactions. Dynamic processes on metal oxide surfaces

It is shown that steady-state kinetic data do not allow the discrimination between the redox and associated mechanisms of the partial oxidation reactions. A discrimination between these mechanisms was performed using transient experiments. The obtained rate expressions are in agreement with experimental kinetic data for catalytic partial oxidation of o-xylene.

An influence of the conjugate oxidation of a catalyst surface on dynamics and kinetics of the heterogeneous catalytic oxidative reactions is considered. Computing simulation of methane oxidative coupling of methane reaction at lowered temperature and elevated pressure has been performed. It showed that the reaction order with respect to oxygen exceeding unity is consistent with the chain branching mechanism of the reaction in the presence of TiSi₂ and TiB₂ and showed the important role of the branching chain cycles in the low-temperature OCM reaction at elevated pressure.     

汽油辛烷值智能调合系统

采取一种能够在线学习、不断提高、建立一系列模型的策略，提出了一种具有学习功能的汽油辛烷值智能调合系统。该系统可以根据成品汽油辛烷值指标、生产成本和市场价格等因素提供一个较好的油品调合调度方案。实际应用结果表明，利用参数学习的方法计算调合汽油辛烷值是可行的。     

多掺炼新疆渣油的催化裂化工业生产技术

兰州石化公司以加工新疆原油为主，重油收率高，平均在37％左右，所生产的重油主要靠催化裂化装置来加工，多余部分以低附加值重油出厂。随着涩宁兰天然气工程的逐渐建成，低附加值重油出厂将受到严重威胁，因此，催化裂化装置加工重油显得尤为重要。兰州石化公司炼油厂1.2Mt/a重催装置通过采用先进技术进行改造，使重油掺炼比由41.52%提高到52.20%，提高了10.68个百分点，年多加工重油14.95万t，产品收率达到79.20%以上，能够灵活调节产品结构，创造了良好的经济效益。     

车用乙醇汽油调合及储运问题的探讨

简要介绍了车用乙醇汽油的组成、性质 ,阐述了车用乙醇汽油调合及储运设施的工艺设计思想 ,以及车用乙醇汽油储运设施设计中应注意的问题。     

土壤固化剂无侧限抗压强度试验研究

针对山西省长治市石子河河道处理问题 ,采用固化剂粘土进行了无侧限抗压强度试验 ,并与水泥土进行了比较。发现固化剂 2的无侧限抗压试验强度最佳 ,为工地现场试验及河道综合治理提供了更为有力的理论依据     

Ecological aspects of the manufacture and application of highly pure liquid substances

The action mechanism for aggressive and highly pure media on fluoropolymer constructional elements is assumed to consist of two basic microeffects: destructive changes in the fluoropolymer and contamination of the environment. Our approach to a quantitative estimation of the physicochemical stability is based on logic similar to that of a thermodynamic model of a two‐component system. A fluoropolymer and changes in its microstructure are considered the first component of the system. The second component is composed of liquid media contaminated with fluoroorganic compounds extracted from the fluoropolymer. The proposed methods for delivering aggressive and highly pure fluids to consumers allow the exclusion of pollution from working areas with gaseous products through an exception to a number of intermediate stages of product transport. The discussed principles allow the creation of a modern, highly effective, and safe (with respect to the ecology and raw materials) production of aggressive liquid chemicals for consumers. © 2002 Wiley Periodicals, Inc. J Appl Polym Sci 85: 906–910, 2002     

Effects of fluoropolymer addition to an epoxy on scratch depth and recovery

Samples were prepared by addition of a fluorinated poly(aryl ether ketone) (12F-PEK) to a commercial epoxy resin and curing at either 24 °C or 70 °C. The concentrations of fluoropolymer in the samples were 0, 5, 10, 20, 30, 40, and 50%. Phase inversion facilitates the formation of more and more smooth surfaces for scratch testing with increasing fluoropolymer concentration. A progressively increasing load from 0.03 N to 12 N was administered with a diamond tip to the surfaces of the samples; depths were determined within ±7.5 nm. The original scratch depth is a function of the fluoropolymer concentration. Scratch recovery (healing) reaches values up to 95%. Plots of the residual depth versus concentration of the fluoropolymer at 4, 6, 8, and 10 N reveal minima for all forces and both temperatures. Addition of only 5% or 10% 12F-PEK improves the scratch recovery significantly. The results are explained by changes of material morphology with the fluoropolymer concentration. Electronic Publication     

在线近红外光谱分析仪在汽油自动调合系统中的应用

在线近红外光谱分析仪可以实时测定汽油调合组分及成品油的多种物化性质指标如烯烃、芳烃、苯及氧化物含量、辛烷值（RON、MON）、馏程、蒸气压等。文章介绍了用于汽油自动调舍工艺中的在线近红外光谱分析仪的原理、系统组成和特点，以及在国内外的汽油调合优化控制中的实际应用情况。典型的应用实例表明，将该分析仪用于汽油自动调合工艺中，可为炼油厂带来可观的经济效益和社会效益。     

精密深孔表面环状硬挤条纹的产生机理与控制

本文建立了不同条件下环状硬挤条纹的生成模型,详细分析了其产生机理.用理论解析和试验验证了所建模型的可靠性,最后提出了控制其产生的方法.     

Influence of wood extractives on the photo‐discoloration of wood surfaces exposed to artificial weathering

Extracted and unextracted black cherry (Prunus serotina), red oak (Quercus rubra), and red pine (Pinus resinosa) wood specimens were exposed to artificial weathering, and their discoloration process was investigated to obtain basic understanding on the role of wood extractives in the weathering of hardwoods and softwoods. Color measurements were made with a spectrometer according to ISO 2470 standards, using the CIELAB system. Results obtained showed that the rate of whiteness was not significantly affected by extractives removed with organic solvents, but were significantly affected when organic solvent extraction was followed by water extraction. The total discoloration rate had the same pattern, and chromaticity coordinates were less affected by wood extractives. These results confirm the hypothesis that some extractives contained in wood act as antioxidants and are able to provide some protection to wood surfaces against weathering degradation. However, more work is needed to understand the chemistry and mechanism of action of these extractives so as to develop any practical use for this property. © 2006 Wiley Periodicals, Inc. Col Res Appl, 31, 425–434, 2006; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/col.20248