吸附精制提高催化裂化柴油的安定性

用卸出的催化裂化平衡催化剂对催化裂化柴油进行吸附精制，取得了很好的效果。精制油收率99％以上，其安定性达到了优级轻柴油的标准（沉渣＜2．0mg／100mL，色号≤16）。精制后柴油的胶质下降约1个百分点，对吸附物的组成分析表明，其氮含量是柴油的17倍以上。对精制油的分析表明，吸附精制可明显降低柴油的酸度和碱性氮化物的含量。     

磷酸盐激光玻璃中铂颗粒密度与氧化还原平衡关系的研究

用吸收光谱法研究了Ｒ２Ｏ—ＢａＯ—Ｐ２Ｏ５系统磷酸盐激光玻璃中铂颗粒密度与铭的氧化还原平衡的关系。结果表明，玻璃中铂颗粒密度随平衡向右移动而减小；玻璃中平衡随熔炼气氛中氧分压增大、熔炼温度升高而向右移动，当足够大时，铂颗粒不能形成。     

Finances and Well-Being: A Dynamic Equilibrium Model of Resources.

This study of 513 Dutch farmers tested a dynamic equilibrium model of resources (an extension of the conservation of resources theory; S. E. Hobfoll, 1989, 1998, 2001). With structural equation modeling, the advantages of a 3-wave longitudinal design were comprehensively used, such as addressing bidirectional causal effects and within-individual vs. between-individual change. This allowed for a careful analysis of the management function of resources in the stress process. Results showed that well-being had stronger within-person stability than finances. Increased levels of financial problems temporarily increased psychological distress but not self-reported illness. Conversely, farmers with higher stable baselines of psychological distress also had higher baselines of self-reported illness and experienced more negative changes in their financial situation. (PsycINFO Database Record (c) 2010 APA, all rights reserved)     

Estimation of the Equilibrium Constants for Pure Hydrocarbons

Equilibrium constants of pure hydrocarbons in different temperatures and pressures are necessary in most engineering calculations. A general formula has been developed to calculate equilibrium value for a group of hydrocarbons which have the general formula C_n H_2n+2 and C_n H_2n based on three parameters. This formula is a function of reduced temperature, reduced pressure, and an acentric factor. It is applied within a wide range of temperatures and pressures. As a result this technique is considered to be useful for the predication of K values of pure hydrocarbons depending on its reduced temperature, reduced pressure, and acentric factor.     

Phase equilibria in the system Al-Rh

Methods of differential thermal analysis, x-ray diffraction, microstructural analysis and electron probe microanalysis are used to study alloys of the Al-Rh system over the whole concentration range. It is established that the phase of equiatomic composition AlRh melts congruently at 2060°C and it has an extended range of homogeneity (45.1–54.2 at.% Rh). The solubility of aluminum in rhodium reaches 9 at.%, decreasing to 6 at.% at 850°C. Coordinates are determined for the eutectic point l ⇆ AlRh + 〈Rh〉 as 70 at.% Rh and 1715°C. The existence of intermediate phases, their crystal structure, and also the method of forming phases in the field of composition rich in aluminum given in publications are confirmed. __________ Translated from Poroshkovaya Metallurgiya, Nos. 5–6(449), pp. 48–56, May–June, 2006.     

正丁基硫醇-正辛烷体系等压气液相平衡研究

利用双循环气液平衡釜测定了101.3 kPa下正丁基硫醇-正辛烷体系的气液平衡数据,并运用该实验结果,进一步获得组分的液相活度系数。实验数据经Herrington方法检验符合热力学一致性。用UNIQUAC热力学模型对该实验数据进行处理,计算结果与实验值的平均绝对偏差为0.050 5。     

Hydrolysis of Fe(OH)SO4 in the presence of metallic iron

Hydrolysis of Fe(OH)SO₄ was carried out in the presence of metallic iron in order to prevent the formation of iron(III) oxides with strongly bonded sulphate. Under the conditions of the experiment, the products were found to be mixtures of ?-Fe₂O₃ and α-FeOOH. The occluded sulphate, if any, could be easily washed out with water. The hydrolysis reaction passes through an equilibrium state before coming to completion. The entropy with enthalpy of the hydrolysis corresponding to the equilibrium state were found to be 4 e.u. and 0·5 kJ/mol, respectively. The activation energy of the hydrolysis reaction was found to be 21 kJ/mol.     

PVT Measurements on tetrafluoroethane (R134a) along the vapor-liquid equilibrium boundary between 288 and 373 K and in the liquid state from the triple point to 265 K

For the investigations of the gas-liquid phase equilibria, a new apparatus has been developed capable of simultaneously determining the pressure and the liquid and vapor densities using Archimedes' principle. The relative measurement uncertainties of the liquid and vapor densities of R134a (purity, 99.999%) at 313 K are 2×10^–4 and 7×10^–4, respectively (95% confidence level). For the measurements in the liquid region along nine quasi-isochores at pressures up to 5 MPa, an isochoric apparatus was used. The relative measurement uncertainty ofpv/(RT) is less than 1×10^–3. In addition to the investigation of the (p, v, T) properties, the temperature and pressure at the triple point and the vapor pressure between the triple point and 265 K were measured. On the basis of these data, a vapor pressure correlation has been developed that reproduces the measured vapor pressures within the uncertainty of measurement. The results of our measurements are compared with a fundamental equation for R134a, which is based on the measurements of other research groups.Paper presented at the Twelfth Symposium on Thermophysical Properties, June 19–24, 1994, Boulder, Colorado, U.S.A.     

Relationship between CO2 Sensor Voltage Response and Phase Equilibrium of Solid Electrolyte Na, K-β/β"-Al2O3

A type of CO2 sensor based on oxygen concentration cell was designed as following: Cell I: Pt | Au, O2,CO2|Na2CO3(Au)|NKBA(Au)|YSZ|O2, CO2|Pt or Cell Ⅱ: Pt|Au, O2, CO2|K2CO3(Au)|NKBA(Au)|YSZ|O2, CO2|Pt.(Na,K-β/β″-Al2O3 is named by NKBA). The sensor signal is consistent with the Nernstian slope within the region ofphase equilibrium for Na, K-β/β"-Al2O3 material. The relationship between CO2 sensor voltage response and phaseequilibrium of solid electrolyte Na, K-β/β-Al2O3 is discussed in this paper.