贵州作为全国磷复肥建设基地磷化工产业发展前景广阔

分析国际、国内高浓度磷复肥的需求与产能形势,贵州发展磷化工产业的优势条件;提出对贵州省磷化工产业发展的若干建议,认为我国磷复肥产能虽然过剩,但作为全国磷复肥建设基地的贵州省磷化工产业仍具有广阔的发展前景.     

Long-term residual value of North Carolina and Queensland rock phosphates compared with triple superphosphate

The effectiveness of large single applications of North Carolina reactive rock phosphate, Queensland non-reactive rock phosphate, and Calciphos, were compared to the effectiveness of superphosphate in field experiments in south-western Australia for up to 11 years after application. As measured using plant yield, superphosphate was the most effective fertilizer in the year of application, and relative to freshly-applied superphosphate, the effectiveness of the superphosphate residues declined to be about 15 to 65% as effective in the year after application, and 5 to 20% as effective 9 to 10 years after application. Relative to freshly-applied superphosphate, all the rock phosphates were 10 to 30% as effective in the year of application, and the residues remained 2 to 20% as effective in the 10 years after application. The bicarbonate soil test reagent predicted a more gradual decrease in effectiveness of superphosphate of up to 70% 10 years after application. For rock phosphate, the reagent predicted effectiveness to be always lower than for superphosphate, being initially 2 to 11% as effective in the year after application, and from 10% to equally as effective 10 years later. Therefore rock phosphates are unlikely to be economic alternatives to superphosphate in the short or long term on most lateritic soils in south-western Australia.     

基于短时能量和最小相对均方误差准则的神经网络语音水印方法

针对传统最小均方误差（LMS）和最小二乘准则（RLS）的神经网络语音水印的局限性,提出了基于短时能量和最小相对均方误差（LRMS）准则的神经网络语音水印算法。首先在首帧语音中嵌入同步序列,然后求出每帧的短时能量并对大于设定阈值的语音帧进行小波变换,最后利用以LRMS准则构建的神经网络实现水印的嵌入和提取。通过合理设定短时能量阈值,实现了水印容量和鲁棒性的平衡,而采用Levenberg-Marguardt（LM）算法地让网络迅速收敛。理论分析和实验结果表明,与文献[8]相比,本文提出的神经网络方案收敛速度更快,对于噪声,低通滤波,重采样,重量化等攻击有更强的鲁棒性,性能平均提高了5%。     

Comparison of single and coastal superphosphate for subterranean clover on phosphorus leaching soils

Coastal superphosphate, a partially acidulated rock phosphate (PARP), is being considered as an alternative fertilizer to single superphosphate for pastures in high rainfall (> 800 mm annual average) areas of south-western Australia. The effectiveness of single and coastal superphosphate, as P fertilizers, was measured in two field experiments using dry herbage yield of subterranean clover (Trifolium subterraneum). The experiments were started in April 1990 and were terminated at the end of 1993. In the years after P applications, soil samples were collected each January to measure Colwell soil-test P, which was related to plant yields measured later on that year, to provide soil P test calibrations.Relative to freshly-applied single superphosphate, the effectiveness of freshly-applied coastal superphosphate and the residues of previously-applied single and coastal superphosphate were less effective in some years (from 3% as effective to equally effective), and up to 100% more effective in other years. This large range in effectiveness values in different years is attributed to different climatic conditions. Soil P test calibrations were different for soils treated with single or coastal superphosphate. The calibrations were also different for different yield assessments (harvests) in the same year, and in different years. Consequently soil P testing can only provide a very crude estimate of the current P status of the soils.     

A discussion of the methods for comparing the relative effectiveness of phosphate fertilizers varying in solubility

Because various phosphate (P) fertilizers differ widely in their solubility, it is commonly observed that crop response to P fertilizers varies under the same soil and crop conditions. Furthermore, a major problem encountered in the methods for determining the relative effectiveness (RE) of water-insoluble P fertilizer (e.g., phosphate rock) with respect to water-soluble P fertilizers, e.g., single superphosphate (SSP) and triple superphosphate (TSP), is that their growth response curves are usually nonlinear and often do not share a common maximum yield. In this paper, we review and discuss the advantages and disadvantages of the three most commonly used methods for calculating the RE of phosphate rock with respect to TSP (or SSP). The three methods are vertical comparison, horizontal (substitution rate) comparison, and linear-response comparison.     

Gas Hold‐Up in Stirred Tank Reactors in the Presence of Inorganic Electrolytes

Gas hold‐up (?_G) in air‐aqueous electrolyte solutions in stirred tank reactors (STR) is correlated using a relative gas dispersion parameter, N/N_cd and a surface tension factor (STF), (c/z)(dδ/dc)². For electrolyte concentration below transition concentration (c_t) a single correlation in the form of ?_G = f(N/N_cd, vvm, STF) shows good agreement with gas hold‐up data over a wide range of system and operating conditions. Above ct no effect of STF on gas hold‐up is observed and the correlation obtained is of the form ?_G = f(N/N_cd, vvm). Data available in the literature on large STR show good fit with the proposed correlation.     

反式 -1,4-聚异戊二烯相对分子质量的调节

采用负载钛本体沉淀聚合法,以氢气作链转移剂,制备了不同相对分子质量的反式-1,4-聚异戊二烯(TPI),讨论了老化、氢气调节及塑炼对其相对分子质量的影响,以及不同相对分子质量TPI的结构与性能。结果表明,本体系合成TPI的数均相对分子质量为(5～15)×104,相对分子质量分布为2.00～3.00;门尼粘度为20～120时,随着TPI相对分子质量的降低,其结晶速度提高,结晶度无明显变化,拉伸强度明显降低,扯断伸长率、屈服强度和邵尔A型硬度无明显变化。     

悬浮法合成固体粒状丙烯酸树脂

研究了悬浮法合成固体丙烯酸树脂颗粒。讨论了不同软硬单体配比对丙烯酸树脂颗粒的玻璃化转变温度、相对分子质量及其分布的影响以及不同的引发剂及悬浮剂对其聚合过程、最终产物形态及上述性能的影响。制得的丙烯酸树脂的数均相对分子质量用凝胶渗透色谱(GPC)测定为3.9×104～6.2×104,相对分子质量分布为2.04～2.32;用红外光谱图表征了制得的丙烯酸树脂结构。差示扫描量热法(DSC)测定了聚合物的玻璃化转变温度(Tg)。     

侧向水流作用下均匀沙休止角变化的试验研究

散体沙动水休止角是表征沙丘、沙洲等散体沙堆积体稳定形态的重要特征参数,在岸坡稳定分析、坝前冲刷漏斗形态研究中有着广泛的应用。采用室内试验的方法研究了侧向水流作用下不同粒径天然均匀散体沙水下休止角的变化规律。结果表明:在水流流速超过泥沙颗粒起动流速后,天然散体沙水下休止角随流速增大而减小,且减小的速度随着流速的进一步增加而更加迅速;相同流速条件下,粗颗粒泥沙的水下休止角大于细颗粒,其对流速变化的敏感度也低于细颗粒。基于侧向水流边坡上泥沙颗粒的受力分析,引入相对流速概念,初步建立了侧向水流作用下均匀散体沙动水休止角计算公式及其简化形式。     

梅州大埔陶瓷与佛山石湾陶艺的比较

对梅州大埔陶瓷和佛山石湾陶艺在地理环境、造型和装饰方面进行分析比较,阐述了两地陶瓷艺术在充分利用地方资源的优势下,形成的独自鲜明的艺术效果,使人们领悟到两地不同陶瓷的艺术之美。