Design and synthesis study of the thermo-sensitive poly (N-vinylpyrrolidone-b- N,N-diethylacrylamide)

The reversible addition fragmentation chain transfer (RAFT) polymerization method was adopted here to prepare a series of thermo-sensitive copolymers, poly (N,N-diethyl- acrylamide-b-N-vinylpyrrolidone). Their structures, molecular weight distribution and temperature sensitivity performances were characterized by the nuclear magnetic resonance (¹HNMR), the gel permeation chromatography (GPC) and the fluorescence spectrophotometer, respectively. It has been identified that the synthesis reaction of the block copolymer was living polymerization. The thermo-sensitivity study suggested that N-vinylpyrrolidone (NVP), played a key role on the lower critical solution temperature (LCST) performance.     

温度敏感高分子水凝胶的合成及性能研究

从分子设计的角度出发,选用具有优良温敏性的N-异丙基丙烯酰胺(NIPA)为基本原料,制备了温度敏感水凝胶,系统研究了水凝胶的基本物理性能(密度、平均分子量、交联密度、平衡态水含量、固定电荷密度等),测试了水凝胶在不同离子强度下的溶胀、退溶胀性能,并对其响应机理进行了探讨,同时对水凝胶的机械性能进行了测试.结果表明:温度敏感水凝胶的溶胀受离子强度和温度的影响很大,离子强度越高,溶胀率越低;其机械强度随温度变化显著.