锤头用中锰耐磨铸钢的生产与应用

含碳含硅较高的中锰铸钢是一种可用于制造锤头的耐磨铸钢，破碎白云石时，此种钢制作的锤头的单耗为７．１ｇ／ｔ，而高锰钢制作的锤头单耗为１７．４ｇ／ｔ。中锰耐磨铸钢属脆性材料，在非强烈冲击条件下使用，是高锰钢耐磨性的２．４５倍，适用于破碎中低硬度的矿石。文中介绍了中锰铸钢的成分、生产工艺、热处理过程和机械性能。     

Self-emulsifiable soybean oil phosphate ester polyols for low-VOC corrosion resistant coatings

A series of soybean oil phosphate ester polyols (SOPEP) was prepared by reaction of fully epoxidized soybean oil with phosphoric acid and simultanoeous hydrolysis in the presence of a polar solvent. The polyols were characterized by determination of acid value, oxirane number, hydroxyl value, molecular weight (GPC), and FTIR spectra. These polyols with varying amounts of acid phosphate groups could be self-emulsified to form aqueous dispersions after neutralization with organic base. These aqueous dispersion showed varying degrees of stability and their appearance ranged from opaque dispersions to translucent to clear solutions. Waterborne coating compositions were prepared using these aqueous dispersions as principal components and their thermally cured film properties were studied. it was found that by careful selection and formulation, SOPEPs can be successfully used for low-VOC waterborne coating formulations. SOPEPs with 3.5% phosphate ester content showed visibly superior corrosion resistance properties.     

Electrochemical ferrate generation for waste water treatment using cast irons with high silicon contents

This paper deals with the electrochemical preparation of ferrate in 15 M NaOH media, with a view to treatment of waste waters. Grey cast irons with high silicon contents were shown to allow current yields in the range 20–40% depending on the applied current density, up to 34 mA cm^–2. Ferrate solutions with contents up to 0.08 M could be produced in a divided cell of simple design, and provided with flat or packed-bed electrodes. Deactivation of the anode surface was shown to be of moderate significance for hour-long runs. The ferrate produced was tested for treatment of industrial liquid wastes: coagulation efficiency of the suspended matter was comparable with that of an electrocoagulation process with sacrificial Al anodes. The potential of waste water treatment by addition of ferrate is discussed.     

Shear performance analysis of a heavy-duty universal hinged cast steel support

This paper presents the shear performance analysis of a heavy-duty universal hinged cast steel support with the largest bearing capacity. The effect of 9 parameters ( 52 specimens) ,i. e. height of the upper support,depth of the ring of the upper support,depth of the top plate of the bottom support,height of the ribs of the bottom support,depth of the ribs of the bottom support,bolt hole diameter,number of the ribs of the bowl,depth of the ribs of the bowl,and yield strength of the material,were analyzed with a 3-dimensional elastic-plastic finite element model in which the nonlinearities of geometry,material and contact were all considered. Analysis shows that height of the upper support,depth of the ring of the upper support and yield strength of the material have a great effect on the mechanical performance of the support. Height of the upper support has the largest effect on performance price ratio of the support,and the maximum effect can be up to 160% . Depth of the top plate of the bottom support,height of the ribs of the bottom support and depth of the ribs of the bottom support have a medium effect on performance price ratio of the support,and the effect is within the limit of 15% 19% .     

灰口铸铁给水管道内壁腐蚀试验

目的 灰口铸铁给水管道运行过程必然造成内壁发生不同程度的腐蚀,通过实验研究内腐蚀各影响因素,分析灰口铸铁供水管道腐蚀变化规律.方法 在调查分析埋地供水管道腐蚀状况及腐蚀原因的基础上,对灰口铸铁试片进行室内挂片实验,分别考虑不同溶解氧、pH值、余氯和流速的条件下的腐蚀速率.同时对灰口铸铁管的内壁腐蚀产物进行电子扫描电镜分析和X-射线衍射分析,确定内壁腐蚀结构成分.结果 pH＜5和pH＞11时腐蚀速率分别呈线性递增和线性递减趋势,水中溶解氧在初始50 h内消耗速度呈直线增加变化,随后DO消耗速度几乎不变,余氯对腐蚀过程有促进作用,流速与铸铁管道的腐蚀速率成正比例关系.结论 pH值、溶解氧、余氯、流速和侵蚀性CO2是引起灰口铸铁供水管道内腐蚀的主要原因.     

考虑腐蚀的埋地灰口铸铁管失效预测及可靠度分析

针对早期埋设的灰口铸铁管存在的破损频繁、漏失严重等影响输配水安全问题,通过管土相互作用模型得到管道应力,应用腐蚀模型预测管道腐蚀深度,进而评估管道的剩余强度,结合失效准则得到管道失效预测模型,并运用蒙特卡罗方法对管道可靠度进行分析.计算模型充分考虑了管道腐蚀、各种外部荷载以及参数的不确定性对管道失效的影响.计算结果表明,在通常荷载作用下仅考虑管道受力,管道不会失效,腐蚀是导致管道失效的重要因素;管道安全因子的概率密度分布曲线呈对数正态分布;当使用时间为20～50 a时管道失效风险较大,在使用时间超过80 a之后,管道失效风险变小且呈现出略有下降的趋势;由于渗漏或不均匀沉降引起的管道基础局部流失在腐蚀深度超过一定值时对管道失效概率的影响较大.     

固定电话网络瘦身方案的研究与设计

为解决固定电话网络交换设备的冗余和数据提取问题,以华为C＆C08程控交换机为背景,采用华为公司的TABLEBROWSE软件系统,研究和设计了一套固定电话网络的瘦身方案。该方案基于网络数据提取和割接命令脚本实现,解决了固定电话网络割接过程中存在的多种问题。与从97系统中提取数据的一般方法相比,该方案的数据实时性强,数据的准确率达到100%,所耗费的时间也缩短了一半。经过实际工作证明完全可行。     

不同支护结构的实测土压力及其分析

通过对南京某大厦深基坑支护结构侧土压力的实测研究 ,分析和研究了软土地区悬臂支护结构、单层支点混合支护结构、连拱支护结构侧土压力分布的基本规律。     

Effect of electromagnetic and ultrasonic cast rolling on microstructure and properties of 1050 aluminum substrate for presensitized plate

The 1050 aluminum alloy strip was prepared by means of electromagnetic and ultrasonic cast rolling on the modified asymmetric twin roll caster, and then the aluminum substrate for presensitized plate was prepared through cold rolling and annealing.The effects of electromagnetic and ultrasonic cast rolling on microstructure, mechanical properties, surface roughness and electrolytic corrosion properties of 1050 aluminum substrate were studied. The results show that electromagnetic and ultrasonic cast rolling can decrease the average crystallite size of aluminum substrate by 5 μm, increase the crystal boundaries with uniform distribution, and make the second-phase particles with smaller size distributed dispersively in the substrate, meanwhile, it can increase the tensile strength, elongation and micro-hardness by 4.58%, 9.85% and HV 2, respectively, reduce the surface roughness, make the surface appearance more even, electrolytic corrosion polarization curve of aluminum substrate more smooth and the surface corrosion pits with regular shape more dispersive.     

Effect of vanadium and chromium on the microstructural features of V–Cr–Mn–Ni spheroidal carbide cast irons

The objective of this investigation is to study the influence of vanadium（5.0wt%–10.0wt%） and chromium（0–9.0wt%） on the microstructure and hardness of Cr-V-Mn-Ni white cast irons with spheroidal vanadium carbides. The alloys＇ microstructural features are presented and discussed with regard to the distribution of phase elements. The structural constituents of the alloys are spheroidal VC, proeutectoid cementite, ledeburite eutectic, rosette-shaped carbide eutectic（based on M7C3）, pearlite, martensite, and austenite. Their combinations and area fraction（AF） ratios are reported to be influenced by the alloys＇ chemical composition. Spheroidized VC particles are found to be sites for the nucleation of carbide eutectics. Cr and V are shown to substitute each other in the VC and M7C3 carbides, respectively. Chromium alloying leads to the formation of a eutectic（γ-Fe ＋ М7С3）, preventing the appearance of proeutectoid cementite in the structure. Vanadium and chromium are revealed to increase the total carbide fraction and the amount of austenite in the matrix. Cr is observed to play a key role in controlling the metallic matrix microstructure.