基于C8051F020的以太网远程监控系统的设计

以C8051F020单片机为核心,以太网模块作为接口,液位控制系统作为被控对象,实现了基于以太网的远程液位监控.讨论了C8051F020单片机的特点,并详细讨论了模拟量输入输出电路的设计和以太网接口电路的设计.给出了单片机的部分初始化代码和程序流程图,并讨论了单片机与上位机通信协议的设计.经实验验证,数据通信正常,检测数据正确.     

硅氟变化对湿法磷酸生产的影响及应对措施

磷矿中SiO2与氟的组分往往是不匹配的。分析了n(SiO2)／n(F)偏高或偏低时对湿法磷酸生产的影响，着重讨论了对尾气洗涤系统正常生产的影响，通过对卧式错流洗涤器洗涤液配置等的改进，用硅氟摩尔比偏高的磷矿生产湿法磷酸时，取得了较好的效果。     

Determination of the vapor pressures of select polychlorinated dibenzo-p-dioxins and dibenzofurans at 75-275 °C

Vapor pressures were determined for several polychlorinated dibenzo-p-dioxins (PCDDs) and polychlorinated dibenzofurans (PCDFs) at 75-275 °C, extending the available literature data to more relevant temperature regions and providing the first experimental data for 2,3,7-trichlorodibenzo-p-dioxin (2,3,7-TriCD). A modification of the effusion technique, based upon controlling the diffusion of the target compound and subsequent high resolution gas chromatography/low resolution mass spectrometry (HRGC/LRMS) analysis, was proven comparable to other accepted methods for determining the vapor pressures of semi-volatile organic compounds (SVOCs). Vapor pressures for octachlorodibenzo-p-dioxin (OCDD) and octachlorodibenzofuran (OCDF) were in excellent agreement with those reported in literature. The application of the current method for the vapor pressure determinations of eight polychlorinated dibenzo-p-dioxins/dibenzofurans (PCDDs/PCDFs) in the extended temperature range (up to 275 °C) is reported. The extension of the vapor pressures to such temperatures, unprecedented for the PCDDs/Fs, is important for vapor-particle partitioning modeling in regions relevant to PCDD/F formation and control. Estimates for the melting temperatures and enthalpies of sublimation and vaporization are also reported, the latter for which no experimentally determined values have been found in the literature. The use of the method to deliver reproducible, trace concentrations (ppt-ppb) of targets was applied to the calibration of the jet-REMPI/TOFMS as an online detector for low chlorinated PCDDs/Fs.     

基于PCI和LVDS的高速数据存储系统的设计

针对某系统图像数据量大、传输速率快的特点,提出了采用PCI总线协议完成PC与高速数据存储系统之间的通信,利用LVDS总线协议传输数据并进行混合编帧的解决方案。为提高数据存储速率,使用Flash交叉双平面页编程技术,将写入速度提高到30 MB/s,有效地满足了图像高速存储的要求。针对数据的码率匹配,通过构建片内FIFO缓存来实现。测试结果表明,所设计的数据存储系统能够稳定地接收并存储图像数据,而且具有很高的可靠性。     

二环己基并-18-冠-6合成工艺的改进

报道了改进的二环己基并-18-冠-6(DCH-18-C-6)合成方法,并用该法实现了DCH-18-C-6的工业规模合成。对由二苯并-18-冠-6加氢合成DCH-18-C-6的反应中使用的Picher-钌催化剂进行了改性,用pH 3~5条件下新制备的Picher-钌催化剂,将反应温度提高并控制在130~140℃之间,可使氢化产率由文献报道的最高65%提高到85%以上,还显著提高了产物中DCH-18-C-6的立体异构体A(cis-syn-cis)含量。建立了用气相色谱法测定DCH-18-C-6异构体含量的方法,并用正庚烷进行结晶以实现A(cis-syn-cis)的提纯。     

Experimental and theoretical study on H2/CO2 separation by a five-step one-column psa process

An experimental and theoretical study is performed for bulk separation of H₂/CO₂ mixture (70/30 volume %) by PSA process with zeolite 5A, a process widely used commercially in conjunction with the catalytic steam reforming of natural gas or naphtha. For the optimized adsorption conditions of PSA, the characteristics of adsorption/desorption characteristics have been studied through breakthrough and desorption experiments under various conditions. The purge-to-feed ratio is important to the H₂ product purity only at a long adsorption step time. H₂ could be concentrated from 70% in the feed to 99.99% at H₂ recovery of 67.5%. The results of all five steps in PSA are successfully predicted by the LDF model considering an energy balance and nonlinear isotherm. For the model, the effective diffusivities (D,) are obtained separately from the uptake curves of H₂ and CO₂. The Langmuir-Freundlich isotherm is used to correlate the experimental equilibrium data and is very well fitted to the results.     

Parameter Estimation for Periodically Stationary Time Series

Abstract. The innovations algorithm can be used to obtain parameter estimates for periodically stationary time series models. In this paper, we compute the asymptotic distribution for these estimates in the case, where the innovations have a finite fourth moment. These asymptotic results are useful to determine which model parameters are significant. In the process, we also develop asymptotics for the Yule–Walker estimates.     

PVC芯层发泡管的研制

PVC芯层发泡管除具备实壁管的性能外,还具有抗冲强度高、适用温度变化大、建筑下水隔音等优点,并且节省原材料25％～30％。通过试验确定了生产工艺要点。产品质量达到或超过了等效采用美国ASTM F891同类产品标准的企业标准。     

基于MFC和MCU的任意波形发生器的设计

为了获得测试测量中特殊信号的波形,在上位机波形编辑软件和信号发生器基础上,提出了任意信号发生器的设计方法。在MFC平台上,实现任意波形编辑软件。该软件支持手绘任意波形、高阶曲线拟合以及常用波形编辑,并可将波形数据下载至基于C8051F340单片机的信号发生器中。实验表明,本设计方案可以获得任意手绘波形、高阶拟合曲线波形、正弦波、可调占空比的三角波和方波、高斯噪声等,还实现了多通道输出和通道间有幅度或者相位关联输出,具有实际应用价值。     

基于MSP430F449的掺杂煤炭快速检测系统设计

介绍了一种基于MSP430F449的掺杂煤炭快速检测仪的设计,阐述了该系统的工作原理和系统设计方案。该系统以DDS芯片AD9833为核心设计激励源,采用24位高精度A/D转换器CS5532实现数据采集,通过RS—232实现上位机和下位机的通信。在煤炭阻抗数据预处理中,采用剔除疏失误差技术,并设计了基于LabVIEW的上位机数据库管理系统。实验证明:该仪器便于携带,低功耗,能够准确识别煤炭的掺杂情况,同时具有操作简单、稳定可靠、方便管理等特点。