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101.
102.
城市生活垃圾能源利用探讨 总被引:7,自引:0,他引:7
报道了城市有机废弃物转化为能源的几种途径。在管式反应器内甘蔗渣裂解气化制煤气以及在高压釜内湿式裂解气化制煤气液体产品,可得到中值煤气。也研究了甘蔗渣二步法糖化和糖发酵,当PH为3.6,酵母浓度为1.33%,乙醇产率可达理论值的64.86%。 相似文献
103.
笔者较为详细地阐述了利用含钨废催化剂生产钨酸的工艺流程、各工序反应原理及其操作工艺实践、产品质量情况、原辅材料单耗等。实践证明 ,该工艺实用性强 ,具有显著的经济效益、社会和环保效益。 相似文献
104.
对焦化干气一步法预处理工艺催化剂进行了工业侧线试验。考察了温度和体积空速对催化剂的活性及催化剂稳定性和加氢选择性的影响。催化剂为以复合型ZnO和过渡金属氧化物为活性组分的多功能催化剂,用于低温下焦化干气中烯烃加氢和硫化物脱除。试验结果表明,在压力1.6MPa、温度285~350℃、空速100~500h-1的条件下,多功能催化剂能将焦化干气中烯烃的体积分数由8%~14%降至0,总硫含量从10~70μg/g脱除至5μg/g以下;经28d考核,多功能催化剂仍保持良好的烯烃加氢和硫化物脱除性能,可用于精制焦化干气。 相似文献
105.
聚丙烯催化剂的研发进展 总被引:5,自引:4,他引:1
综述了用于丙烯聚合的Ziegler-Natta催化剂在给电子体技术及催化剂制备工艺等方面,茂金属催化剂在制备丙烯均聚物、丙烯共聚物及特殊聚丙烯等方面,非茂单活性中心催化剂在丙烯活性聚合、丙烯与极性单体共聚及水介质聚合等方面的研发进展;讨论了聚丙烯催化剂的前景。 相似文献
106.
The deactivation characteristics of Pd/SiO2 in the selective hydrogenation of acetylene were correlated with changes in the amount of the C4 species produced. The amounts of butenes produced changed in parallel with the catalyst activity, indicating that the rate limiting step for butene production was the same as that for acetylene hydrogenation. On the other hand, the amount of 1,3-butadiene produced changed, showing a maximum with catalyst deactivation because 1,3-butadiene is an intermediate in the sequential reaction process which involves both the production and consumption of 1,3-butadiene. This was verified by a simultaneous TG/reaction experiment showing that 1,3-butadiene was a precursor of green oil. The catalyst showed a self-regenerative behavior in its activity and the amounts of C4 species produced during the early stage of deactivation because two opposite factors, which contributed to either the lowering or the promotion of activity, were involved in the process. A specific type of polymer species, produced during the initial period of deactivation, is proposed to be responsible for the promotion of catalyst activity. 相似文献
107.
A newly developed catalyst type DVR-1 for catalytic cracking of Daqing vacuum resid was put into use in a commercial VRFCC unit,This catalyst features uniquely active matrix and modified ultra-stable zeolite.The commercial application results show that the DVR-1 type catalyst has the advantage of high heavy oil conversion,good metal tolerance nd gooed stability for catalyst regeneration,The FCC tests have shown Favorable product distribution,acceptable product quality and enormaous economic benefits whe processing the feedstock containin 75%-100% Daqing VR. 相似文献
108.
乙炔在磁稳定床中的选择性加氢研究 总被引:1,自引:0,他引:1
制备了一种磁性Pd/Al2O3催化剂,采用磁稳定床考察了活性组分负载量、反应条件及CO浓度对乙炔加氢反应性能的影响。结果表明,当反应温度80℃、反应压力1.5MPa、空速9000h-1、磁场强度(H)25kA/m时,乙炔转化率为100%,乙烯选择性可达81%,具有优良的乙炔加氢活性和乙烯选择性,优于相同反应条件下的进口催化剂;250h稳定性实验结果表明,磁性Pd/Al2O3催化剂具有良好的初活性和乙烯选择性,催化剂性能稳定。 相似文献
109.
Development of a poly-functional catalyst that has higher hydrodealkylation activity based on 15% Cr/γ- Al2 O3 was researched for benzene production from an alkyl-aromatic mixture via hydrodealkylation. For this goal, the effects of the promoters like Fe, Co, or Ni and their concentrations on the activity of a Cr/Al2 O3 catalyst were investigated. Toluene + n-heptane + tetrahydrotiophene (89:10:1 w%) model mixture, which has the same content as industrial aromatics, was used as feedstock. The activities of catalysis in reactions of hydrodealkylation, hydrocracking, and hydrogenolize with respect to conversions of toluene, heptane, and tetrahydrotiophene were tested, respectively. As to the obtained results, the catalyst including 5% Fe has a higher hydrodealkylation activity, compared to the catalyst including Co, and especially to the alumocrom catalyst not including a promoter, while it has a lower coke formation and reduced activity to the catalyst including Ni. 相似文献
110.