Preparation of CaO granules using the granulation method

ABSTRACT

Improving the hydration resistance of CaO particle in manufacturing and application of free CaO-containing materials has practical significance. In this study, CaO granules was made from Ca(OH)₂ particles, which were fabricated by the granulation method. The results showed that the hydration resistance of the CaO granules which was prepared under 1700?r?min^?1 was the best, the CaO granules was sintered well in calcination process, the shell of CaO granules was relatively dense, which improves the hydration resistance of CaO granules, and the rate of hydration weight increment was 0.58% after placed in the air for 20 days under a temperature of 10–14°C and a relative humidity of 57–81%.     

Studying the effect of organo-modified nanoclay loading on the thermal stability,flame retardant,anti-corrosive and mechanical properties of polyurethane nanocomposite for surface coating

Clay polyurethane nanocomposite (CPN) coating films were fabricated by uniformly dispersing nanoclay, organically modified with 25–30 wt.% octadecylamine in varying concentrations up to 5 wt.%, in a commercial two component, glossy, acrylic aliphatic polyurethane using ultrasonication. Organo-modified nanoclay was characterized by X-ray diffraction (XRD). The dispersion of the nanoclay into the matrix was investigated by scanning electron microscopy (SEM). CPN coating films were characterized by thermogravimetric analysis (TGA), and flame retardant, corrosion resistance and mechanical properties were also investigated. The XRD measurement indicated that, the organo-modified nanoclay particles were mainly constituted of montmorillonite with traces of quartz and calcite also found to be present. The SEM analysis showed that the nanoclay layers were dispersed and intercalated into the polyurethane coating. Thermogravimetric analysis showed that incorporating 5 wt.% organo-nanoclay into polyurethane considerably enhanced the thermal stability and increased the char residue to 14.11 wt.% relative to 4.58 for the sample without organo-nanoclay (blank polyurethane). The limiting oxygen index (LOI) test revealed that incorporation of organo-nanoclay led to a further increase in LOI values, which indicate an improvement in flame retardancy properties. The corrosion resistance also improved and this improvement increases with increase nanoclay wt.%. The mechanical resistance measurements demonstrated that the gloss of the CPN coating films slightly decreased, although hardness, adhesion and impact resistance of the CPN coating films improved with the incorporation of the organo-nanoclay.     

Q690钢焊接接头微观组织对冷裂纹的影响研究

分析了Q690钢手工电弧焊与气体保护焊焊接冷裂纹产生与微观组织的联系。结果表明: 焊接冷裂纹起源于斜Y坡口根部, 沿熔合区、焊缝扩展至焊缝表面;2种工艺焊接的接头组织硬度均较母材高, 而塑性较差。热影响区为马氏体、贝氏体与铁素体混合组织, 焊缝组织由先共析铁素体、侧板条铁素体、贝氏体和针状铁素体等组成, 针状铁素体抗裂纹扩展能力较其他组织强。在2种焊接方法对应断口中观察到了冷裂纹起裂、扩展与断裂区的不同形貌, 起裂与扩展区存在塑性变形, 而断裂区为解理断裂。     

转速对2524铝合金搅拌摩擦点焊组织与性能的影响

对2524铝合金薄板进行搭接搅拌摩擦点焊试验, 研究了搅拌头转速对其组织与性能的影响。结果表明, 随转速增加, 焊点外侧飞边越加严重, 组织畸变程度增加, 焊核区宽度增大, 有效连接宽度先增大后减小。母材区硬度最大, 热影响区硬度最低;在焊核区内, 显微硬度随转速增加而增大, 当转速为1 100 r/min时达到最大133.9HV, 而热影响区在300 r/min时硬度最大。在单向拉伸试验中, 接头剪切强度随转速增加先增大后减小, 在700 r/min时达到最大值3 510 N;接头呈现出两种断裂模式: 即低转速下平行于两板面断裂和高转速下沿倾斜方向断裂;断口呈现明显的剪切韧窝形态, 韧窝小而浅, 焊接接头为韧性断裂。     

机制砂混凝土耐磨性的主要影响因素分析及多因素计算模型

本文研究了砂类型、砂率、石粉含量和抗压强度对机制砂混凝土耐磨性的影响,建立了磨损量的多因素计算模型。结果表明:由于含石粉及具有更高的粗糙度和坚固性,石灰岩与辉绿岩机制砂制备的C30、C40混凝土耐磨性比河砂混凝土提高20%以上;在0.40~0.44范围内选取较低的砂率可获得较优的耐磨性;利用石粉含量为5%~11%(质量分数)的机制砂制备混凝土,石粉含量为9%时可获得最佳的混凝土耐磨性,微观分析表明此时混凝土密实度最佳;通过灰色系统理论确定了耐磨性影响因素的影响程度排序为:砂率R₃>压碎值R₂>粗糙度R₁>抗压强度R₅>石粉含量R₄>0.6;对比验证表明提出的混凝土磨损量多因素计算模型具有较高的预测精度和良好的适用性。     

Linear friction welding of Ti6Al4V: experiments and modelling

Linear friction welding of the Ti6Al4V alloy is studied. A new definition of the energy input rate is proposed, based on an integration over time of the in-plane force and velocity; a strong correlation with the upset rate is then found. The effective friction coefficient is estimated to be 0·5±0·1 for varying frequencies and amplitudes, with only a weak dependence on the processing conditions displayed. A model is proposed that accounts for both the conditioning and equilibrium stages of the process, which is shown to be in good agreement with the experimental data. The model is used to study the mechanism by which the flash is formed. A criterion is proposed by which the rippled nature of its morphology can be predicted.     

硼氢化钠对滑轮用铸钢板化学镀Ni-B合金薄膜性能的影响

在滑轮用铸钢板上化学镀Ni-B合金薄膜,并研究了硼氢化钠的质量浓度对化学镀Ni-B合金薄膜性能的影响。结果表明:适当增加硼氢化钠的质量浓度,有利于增大化学镀Ni-B合金薄膜的厚度及硼的质量分数,从而提高化学镀Ni-B合金薄膜的硬度。当硼氢化钠的质量浓度大于1.2 g/L时,硼氢化钠的水解速率加快及剧烈的析氢反应,导致化学镀Ni-B合金薄膜的厚度及硬度有所降低。当硼氢化钠的质量浓度为1.2 g/L时,化学镀Ni-B合金薄膜表面"胞状"颗粒均匀、致密,摩擦因数和磨损率最低,具有最佳的耐磨性。     

Process and joint quality of ultrasonic vibration enhanced friction stir lap welding

In order to improve the process effectiveness and joint quality, ultrasonic vibrations were integrated with friction stir lap welding. Effect of ultrasonic exertion on the process and joint quality of AA 6061-T6 were investigated. Upon ultrasonic exertion, joints owned larger effective lap width, shorter hooks and improved strength. Weld fracture mode changed from a ductile–brittle mixed mode to a more ductile mode while the fracture path shifted from lap interface to beyond the stir zone. Material flow and interface defects were characterised using lap welded dissimilar aluminium alloy joints. Ultrasonic vibration improved the material flow and reduced the interfacial defects. Variations in failure load of joints were found in accordance with the variations in material flow and interfacial defects.     

Effect of in-situ formation of columnar mullite and pore structure refinement on high temperature properties of corundum casatbles

The effects of in-situ synthesis columnar mullite and pore structure on the hot modulus of rupture (HMOR), thermal shock resistance and corrosion resistance of corundum castables have been investigated in this paper. When 2% nano silica was added, the pore diameters of castables could be decreased to 15 nm (at 110 °C), 1 μm (1100 °C) and 6 μm (1500 °C), respectively. The corresponding reducing magnitude of pore size is 98.5%, 83.3% and 33.3%. The HMOR of castables fired at 1500 °C increased by 110% to 3.64 MPa. Furthermore, after three thermal shock cycles, the residual strength ratio of castables increased from 5.2% to 15.3%. A large amount of cross-distributed columnar mullite was formed between nano silica and α-Al₂O₃ by the two-dimensional nucleation mechanism, which remarkably enhanced the high temperature properties. The penetration index reduced from 30.86% to 19.88%, suggesting that smaller pore size and higher viscosity had a great influence to the penetration process.