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41.
42.
Adaptation of the microscopic properties of redox catalysts to the type of gas-solid reactor 总被引:1,自引:0,他引:1
Catalysts of selective oxidation usually work in a simultaneous redox mode in reactant/air cofed reactors. The solid must provide selective lattice oxygen according to a kinetic mechanism depending on operating conditions that differ from one reactor to another. Better catalytic performance can be obtained in a recirculating solids reactor because it allows separate optimization of the reduction and oxidation steps. Among the microscopic properties of the catalyst, the crystal morphology is to be taken into account because it influences its reactivity on stream. These considerations lead to a new approach of the catalyst-reaction-reactor trio. 相似文献
43.
液相对流对固液界面稳定性的影响 总被引:1,自引:0,他引:1
以模型合金丁二腈-乙醇的强制性晶体生长为基础,利用自行研制的液相对流驱动装置,详细考查了液相自然对流及强迫对流作用下,模型合金平界面失稳的动态生长过程,证实了液相的流动加快了液相温度与浓度分布的均匀化,从而增强了液/固界面的稳定性。并且随流动速度的增加,界面稳定性提高。 相似文献
44.
聚氧乙烯 - 聚氧丙烯 - 聚苯乙烯多嵌段聚合物的力学和导电性能研究 总被引:1,自引:0,他引:1
研究了聚苯乙烯含量对聚氧乙烯-聚氧丙烯-聚苯乙烯多嵌段聚合物的力学性能及其与LiClO4络合物的离子导电性能的影响;并以电导率较高的络合物为电解质,Na1+xV3O8复合物和Li片分别为正、负极组装了薄型锂电池并测定其放电性能。 相似文献
45.
Studies of the complete oxidation of methane on a Pt electrode-catalyst in the cell with a solid proton-conducting electrolyte (CH4 + O2, Pt ¦ SrCe0.92Dy0.08O3 ¦ Pt, H2O + N2) were carried out. The non-Faradaic effect of electrochemical hydrogen pumping on the rate of methane oxidation has been demonstrated. The induced change in the reaction rate at anodic polarization of a Pt electrode-catalyst was over two orders of magnitude higher than the rate of hydrogen pumping from the reaction zone through the electrolyte. 相似文献
46.
Catalytic chlorination of methane was studied over SO
4
2–
/ZrO2, Pt/SO
4
2–
/ZrO2, and Fe/Mn/SO
4
2–
/ZrO2 solid superacid catalysts. The reactions were carried out in a continuous flow reactor under atmospheric pressure, at temperatures below 240°C, with a gaseous hourly space velocity of 1000 ml/g h and a methane to chlorine ratio of 4 to 1. At 200°C with 30% chlorine converted the selectivity in methyl chloride exceeds 90%. At more elevated temperatures, the selectivity decreases but stays above 80% in methyl chloride at 225°C using the sulfated zirconia catalysts. The selectivity can be enhanced by adding platinum to sulfated zirconia catalysts. An iron and manganese-doped catalyst exhibited excellent selectivities at somewhat lower conversions. Methyl chloride is obtained at 235°C in selectivities greater than 85%. No chloroform or carbon tetrachloride is formed. The electrophilic insertion involves electron-deficient metal-coordinated chlorine into the methane C-H bond.Catalysis by solid superacids, 29. For part 28 see ref. [14]. 相似文献
47.
Savitree Jungsakulrujirek & Athapol Noomhorm 《International Journal of Food Science & Technology》1998,33(4):367-374
The effect of fruit size and harvesting of Thai tangerine fruit ( Citrus reticulata , Blanco) at different growth stages, 8–12 months after fruit set, on the distribution of limonin in whole fruit as well as in the individual fruit parts and extracted juice was investigated. The highest limonin concentration was observed in seed, followed by albedo, flavedo, segment membrane and juice sacs in decreasing order. The limonin concentration in juice as well as in whole fruit was decreased when fruit was harvested 8–12 months of fruit set. Increasing harvesting time from 8 to 12 months showed corresponding decreases in the amount of limonin in flavedo, albedo and seed. There was a decrease in titrable acidity and increase in total soluble solid and total soluble solid/titrable acidity ratio of juice with a later than normal harvesting time. However, fruit size showed no effect on limonin content and other properties of juice extracted from tangerine. 相似文献
48.
饮料包装的计算机控制和管理 总被引:1,自引:1,他引:0
着重介绍计算机技术在饮料包装方面应用的发展情况,灌装生产流水线的计算机控制和管理,自动装卸搬运系统和计算机仓库管理系统等。 相似文献
49.
Due to their simplicity and intuitiveness, swept surfaces are widely used in many surface modelling applications. In this paper, we present a versatile swept surface technique called the boundary constrained swept surfaces. The most distinct feature is its ability to satisfy boundary constraints, including the shape and tangent conditions at the boundaries of a swept surface. This permits significantly varying surfaces to be both modelled and smoothly assembled, leading to the construction of complex objects. The representation, similar to an ordinary swept surface, is analytical in nature and thus it is light in storage cost and numerically very stable to compute. We also introduce a number of useful shape manipulation tools, such as sculpting forces, to deform a surface both locally and globally. In addition to being a complementary method to the mainstream surface modelling and deformation techniques, we have found it very effective in automatically rebuilding existing complex models. Model reconstruction is arguably one of the most laborious and expensive tasks in modelling complex animated characters. We demonstrate how our technique can be used to automate this process. 相似文献
50.
CIE TC8‐01 has adopted a new color appearance model: CIECAM021 replaces the CIECAM97s.2 The new model consists of a number of refinements and simplifications of the CIECAM97s color appearance model. This article describes further tests to the robustness of the forward and reverse modes. © 2005 Wiley Periodicals, Inc. Col Res Appl, 30, 99–106, 2005; Published online in Wiley InterScience (www.interscience.wiley.com). DOI 10.1002/col.20087 相似文献