Influence of third monomer on the crystal phase transition behavior of ethylene-tetrafluoroethylene copolymer

Crystal phase transition between the low- and high-temperature phases has been investigated for ethylene (E)-tetrafluoroethylene (TFE) alternating copolymer (ETFE) containing the third monomeric species by the temperature dependent measurements of wide-angle X-ray diffraction (WAXD) and small-angle X-ray scattering (SAXS) and differential scanning calorimetry. Nonafluoro-1-hexene (NFH) and hexafluoropropylene (HFP) were chosen as the third monomers, where they are different in the side-branch length, -(CF₂)₃CF₃ and -CF₃, respectively. In the case of E/TFE/NFH copolymer (ET-C4F9), the crystal phase transition temperature of the original ETFE two-components copolymer was not very much affected by the existence of NFH in the range of NFH content from 0.7 to 3 mol%. Contrarily, the crystal phase transition temperature of E/TFE/HFP copolymer (ET-CF3) was found to decrease drastically with increasing HFP content. The melting temperature and the higher-order structure were also affected sensitively depending on the HFP content. This difference in phase transition behavior between ET-C4F9 and ET-CF3 copolymers is reasonably interpreted as follows: the short side groups (-CF₃) of HFP monomeric unit are included in the crystal lattice of E/TFE chains and the unit cell is expanded gradually with an increment of the HFP content, resulting in the decrease in phase transition point because of easier thermal motion of the chains. On the other hand, the long side groups [-(CF₂)₃CF₃] of NFH monomeric units are excluded out of the crystal lattice and located on the lamellar surfaces or in the amorphous region and do not affect very much the phase transition temperature even when the NFH content is increased. In association with such a change in crystal structure, the long period of stacked lamellar structure was found to decrease remarkably in the case of NFH, whereas it does not change very much for HFP, consistent with the interpretation of the above-mentioned WAXD data.     

白庙气田储层伤害因素分析及配套保护措施

外来固相、滤液及生产或作业压差、生产时间等工程因素可造成或加重气层的伤害程度，而储层孔隙结构、润湿性、粘土矿物类型和含量等是造成气层伤害的潜在因素。通过对白庙气田储层敏感性分析及工作液对储层的伤害评价，在气田开发过程中有针对性地制定出气层保护配套措施，减少了储层伤害，提高了气田开发效果。     

以乌海地区为例透视矿业环境问题

以乌海地区为例，全面剖析了采矿对地质环境的破坏及其对生态、经济、社会带来的影响，旨在有助于社会对此问题严重性的认识，以便为区域可持续发展制定良策。     

新型高温永磁体的研制

通过分析影响磁体高温性能的因素,设计了新磁体的成分为:Cu含量高,Fe含量低,Zr适量,Sm含量高;采用粉末冶金工艺制备了高温Sm_2(CoFeCuZr)_(17)永磁体。制得的磁体室温磁性能为:B_r1.075 T,H_(ei)2 098.2 kA/m,H_(eb) 776.1 kA/m,H_k843.8 kA/m,(BH)_(max)210.0 kj/m~3;在200℃时的磁性能为:B_r0.991 T,H_(ci)1 175.7 kA/m,H_(cb)531.7 kA/m,H_k577.9 kA/m,(BH)_(max)172.5 kJ/m~3;矫顽力温度系数β(20～200℃)为-0.24％/℃。经理论分析和实验验证,磁体的使用温度均超过400℃,为高温环境(高于400℃)提供了一种实用性永磁材料。     

聚酯装置熔体过滤器的国产化改造

熔体过滤器为聚酯装置关键设备,其国产化问题一直未能解决。该文通过对天津分公司200kt/a聚酯装置熔体过滤器改造方案的介绍,探讨了其国产化条件,分析了国产熔体过滤器的结构特点,并与进口过滤器进行了对比,提出了一些看法。     

阿曼Daleel油田分支井钻井液技术研究

对Daleel油田作业5区三分支水平井DL-59井井下复杂情况分析,室内测定了引起复杂情况的Nahr Umr泥页岩地层的矿物组分和粘土矿物含量,优选了适应在该泥页岩地层215.9 mm造斜井段的钻井液配方中的各种处理剂,最后研制出钻井液配方,通过DL-73井应用后,取得了良好的防塌效果.     

结构安全性综合评估方法的研究

已有结构的安全性的评估是关系到社会经济、安全的重大问题。本文作者从临界结构入手，以构件失效影响面积为参考，得到了计算构件重要性系数的简便方法，结合构件的可靠度提出了定性与定量结合的结构安全性综合评估方法。从工程实例来看，本文提出的方法简单实用，与现行的鉴定标准符合得比较好。     

Reconstruction of reflectance spectra using weighted principal component analysis

The weighted principal component analysis technique is employed for reconstruction of reflectance spectra of surface colors from the related tristimulus values. A dynamic eigenvector subspace based on applying certain weights to reflectance data of Munsell color chips has been formed for each particular sample and the color difference value between the target, and Munsell dataset is chosen as a criterion for determination of weighting factors. Implementation of this method enables one to increase the influence of samples which are closer to target on extracted principal eigenvectors and subsequently diminish the effect of those samples which benefit from higher amount of color difference. The performance of the suggested method is evaluated in spectral reflectance reconstruction of three different collections of colored samples by the use of the first three Munsell bases. The resulting spectra show considerable improvements in terms of root mean square error between the actual and reconstructed reflectance curves as well as CIELAB color difference under illuminant A in comparison to those obtained from the standard PCA method. © 2008 Wiley Periodicals, Inc. Col Res Appl, 33, 360–371, 2008     

高水头弧形闸门伸缩式水封的黏弹性仿真计算方法

认为止水材料的蠕变和应力松弛是由于材料参数的变化而引起的，把描述橡胶类材料应变能密度函数中的物理参数假设成与时间有关的黏弹性函数。在此基础上改进材料应力张量与应变张量的关系式，得到了改进的Mooney-Rivlin公式，给出了一种考虑止水材料黏弹性性质的伸缩式水封仿真计算方法。分析得出，止水材料由于受周边结构的限制，材料黏弹性阶段除顶点垂直位移不变，关键结点的其它位移并没有因材料的蠕变而显著变化，材料的蠕变有提高封头顶点接触应力的趋势，不会降低水封的水密性。通过工程实例，给出了140m水头下、封头与面板间隙控制在30mm内的可行并较优的伸缩式水封的断面。     

P2井特殊烃组分气测异常显示层探讨

正常的油气显示层气测组分分布遵循一定的规律，而准噶尔盆地西北部的P2井在钻探过程中发现了不符合正常气测分布规律的气测异常显示层，由此引起多方关注与争议。在简述该井气测异常特点及特殊性基础上，对其产生原因进行了探讨，认为第一气测异常层无C1、C2值是由于该层原油为未成熟原油，裂解、降解不彻底所致，第二、第三显示层只有C1则是由于该层为稠油层，C1是微生物降解的结果。通过对相邻区块资料分析，进一步提出了以气测全烃曲线形态为主结合垒烃相对幅度与全烃饱满程度图板的气测异常显示解释评价方法，对于指导其他区块类似情况的研究具有参照作用。