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51.
In order to perform business modelling as apart of information systems development, there is a need for frameworks and methods. The paper proposes a framework for business interaction based on a language/action perspective. The framework is an architecture of five generic layers. The first layer concept is ‘business act’, which functions as the basic unit of analysis. The following four layer concepts are ‘action pair’, ‘exchange’, ‘business transaction’, and ‘transaction group’. The framework is inspired by a similar framework constructed by Weigand et al. The paper makes a critical examination of this framework as a basis for the proposed framework. 相似文献
52.
Kwannapat Sorachoti Bhuckchanya Pangkumhang Visanu Tanboonchuy Sarttrawut Tulaphol Nurak Grisdanurak 《中国化学工程学报》2017,25(6):768-774
Metalworking fluids(MWFs) are classified as hazardous substances. Due to the characteristics of the stable oil–water emulsions, it requires more costly and complicate treatment techniques to remove oil from spent MWFs. Metal organic frameworks(MOFs) are a porous network material used to remove contaminants from environment. One of the most prominent of MOFs is HKUST-1 or Cu-BTC. In this study, the Cu-BTCs were prepared by solvothermal method in various conditions and used as absorbent for removing oil micelles in MWF emulsion. The particle size of all synthesized Cu-BTCs ranged from ≈80 to 400 nm. The ability of all synthesized Cu-BTCs to remove oil micelle was greater than 95% in 60 min, while the capacity of GAC was obtained the result for only 6.8%. The maximum adsorption capacity(q _(max)) of oil micelles on Cu-BTCs was 1666.7 mg·g~(-1). The highest removal capacity of oil micelles in MWF emulsion is greater than 99% in 24 h by using Cu-BTCs washed with either butanol or ethanol. 相似文献
53.
《International Journal of Hydrogen Energy》2021,46(73):36023-36036
Transition metal catalysts were supposed to be the most likely substitute for commercial noble metal catalysts, and the development of highly active and long-term catalyst for water splitting are the future trend. Herein, Ni rectangular nitrogen doped carbon nanorods@Fe–Co nanocubes (Ni-CNRs@Fe–Co cubes) were fabricated via a facile template-free method. This simple strategy not only realizes the structure tailoring, but also achieves high-quality nitrogen-doping. Specifically, nickel dimethylglyoxime [Ni(dmg)2] with rectangular rodlike structure was firstly synthesized by solution method, then metal-organic frameworks Fe–Co nanocube with different contents were loaded on rectangular carbon nanorods with polydopamine as the locating and the connecting agent, and finally Ni-CNRs@xFe-Co cubes were obtained by a one-step calcination. A series of electrochemical tests were researched on materials with different metal contents in the 1 M KOH solution. The Ni-CNRs@Fe–Co cubes show excellent electrocatalytic activity in the hydrogen evolution reaction (HER) and the oxygen evolution reaction (OER). For HER and OER, the Tafel slopes were 83.3 mV dec−1 and 71 mV dec−1, the onset potential were −167 mV and 1.62 V, and reached the current densities of 10 mA cm−2, the overpotential just needed 196 mV and 433 mV, respectively. This novel synthetic strategy will provide a template-free way for cheap electrocatalysts of non-precious metal for OER and HER. 相似文献
54.
Adsorption Behavior of Halogenated Anesthetic and Water Vapor on Cr‐Based MOF (MIL‐101) Adsorbent. Part I. Equilibrium and Breakthrough Characterizations 下载免费PDF全文
Ye Hua Nicola Gargiulo Antonio Peluso Paolo Aprea Mladen Eić Domenico Caputo 《化学,工程师,技术》2016,88(11):1730-1738
A synthesized chromium‐based metal organic framework (Cr‐MOF) was used for the adsorption of halogenated anesthetics, i.e., sevoflurane (SF). Adsorption isotherm and breakthrough experiments involving SF (reference sorbate) and water vapor were measured at 298 K and atmospheric pressure on both Cr‐MOF and a commercially used reference adsorbent. The Cr‐MOF MIL‐101 showed a significantly higher SF adsorption capacity and much higher selectivity relative to water vapor compared to the reference adsorbent. Binary‐mixture breakthrough tests demonstrated a “roll‐up effect” for SF on the reference adsorbent while no such effect was observed on MIL‐101. 相似文献
55.
《International Journal of Hydrogen Energy》2021,46(76):37977-37985
The poor kinetics is the main issue hindering MgH2 for practical hydrogen storage application. In this work, the tricarboxybenzene was used to construct the stable Ni MOF (Ni-BTC300) as the catalyst for MgH2. The prepared MOFs maintained their chemical structure after 300 °C calcining and doped to MgH2 by ball milling. The dispersed, uniformly bonded Ni atoms can improve the kinetics of the composites, which could desorb 5.14 wt% H2 within 3 min at 300 °C. And the stable MOF structure leading to good cycle stability in both kinetics and capacity, with retention of 98.2% after 10 cycles. 相似文献
56.
《International Journal of Hydrogen Energy》2021,46(57):29323-29331
In order to identify the best porous materials for the cryogenic physisorption of hydrogen, high-throughput calculations are performed starting, i.e., from the collected information in crystallographic databases. However, these calculations, like molecular simulations, require specific training and significant computational cost. Herein, a relatively simple procedure is proposed to estimate and compare hydrogen uptakes at 77 K and pressure values from 40 bar starting from the porous properties of MOF materials, without involving simulation tools. This procedure uses definitions for adsorption and considers the adsorbed phase as an incompressible fluid whose pressure-density change is that for the liquid phase at 19 K. For the 7000 structures from the CoRE MOF database, the average error of the predictions is only of 1% from reference values at 100 bar, with an SD of ±8%. This accuracy is lower than that from simulation tools, but involving lower computational cost and training. 相似文献
57.
《International Journal of Hydrogen Energy》2022,47(26):12927-12936
Hydrogen is considered as a viable alternative to traditional fossil fuels. Hydrogen evolution reaction (HER) by electrochemical water splitting is the most reliable and effective way for the sustainable production of pure hydrogen. The design and synthesis of highly active and stable non-noble-metal-based electrocatalysts is the core of the large-scale application of this technology. Herein, peony petal-like CoMnP/NF nanomaterials growing on nickel foam (NF) are prepared via facile hydrothermal and phosphorization methods. The results showed that CoMnP/NF had excellent HER activity in acidic and alkaline media. In 0.5 M H2SO4, CoMnP/NF only needed 66.6 mV overpotential to drive the current density of 10 mA cm?2, with a Tafel slope of 38.8 mV dec?1. In addition, a particularly low overpotential of 53.9 mV and Tafel slope of 63 mV dec?1 are required to achieve the same current density in the 1 M KOH electrolyte. Meanwhile, the electrocatalyst showed good stability after 1000 cyclic voltammetry tests and 12 h I-T tests. In the 1 M KOH electrolyte, the current density of 10 mA cm?2 achieved with only 1.70 V battery voltage, and the electrocatalyst showed excellent stability. The performance of CoMnP/NF can be attributed to the synergistic effect between Co and Mn atoms and the high electrochemical surface area (ECSA). This study provides a valuable strategy for the synthesis of non-precious metals and high-performance catalytic materials. 相似文献
58.
59.
Marta Martínez-Abadía Aurelio Mateo-Alonso 《Advanced materials (Deerfield Beach, Fla.)》2020,32(40):2002366
The ability to design and synthesize monomers can affect fundamental aspects in 2D covalent organic frameworks, such as dimensionality, topology, and pore size. Besides this, the structure of the monomers can also affect interlayer interactions, which provide an additional means to influence crystallinity, layer arrangement, interlayer distances, and exfoliability. Herein, some of the effects that the structure of monomers can have on the interlayer interactions in 2D covalent organic frameworks and related materials are illustrated. 相似文献
60.
Weixuan Dong Hongbo Zhou Baodong Mao Zhengyuan Zhang Yashu Liu Yanhong Liu Fenghua Li Dongqi Zhang Dongxu Zhang Weidong Shi 《International Journal of Hydrogen Energy》2021,46(18):10773-10782
The synergistic achievement of low-cost earth-abundant electrocatalysts and high efficiency to meet renewable energy need is highly desirable yet challenging. Here, we developed a simple Ni foam self -templating route for V-doped Ni3S2 nanosheet arrays through in situ formation of metal-organic frameworks (MOFs) combined with subsequent conversion. The as-prepared MOF-V-Ni3S2/NF catalyst delivers outstanding electrocatalytic performance in the alkaline solution, which requires low overpotentials of 118.1 mV @10 mA cm?2 and 268 mV @10 mA cm?2 for hydrogen evolution reaction and oxygen evolution reaction, respectively. The V-doping and MOF-derived 3D hieratical nanostructure play a vital role in the catalytic process, which provides efficient active sites and large surface areas. Furthermore, an alkaline electrolyzer was assembled with two pieces of MOF-V-Ni3S2/NF, which achieves efficient water splitting at 1.58 V @10 mA cm?2. This strategy opens up new channels to synthesize MOF-based bifunctional electrocatalysts toward overall water spitting. 相似文献