Oligo(ethylene oxide) side‐chain steric screening effects on conductimetric properties of grafted poly(4‐vinylpyridinium) salts in aqueous solutions

A set of poly[N‐oligo(ethylene oxide)yl 4‐vinylpyridinium tosylate] (P4VOEOOTs) has been prepared by spontaneous polymerization of 4‐vinylpyridine. This method gives a grafted polyelectrolyte having a positive charge on every backbone pyridinic moiety. The P4VP15Ts, P4VP164Ts, P4VP350Ts and P4VP750Ts aqueous solution conductivities were determined in the concentration range from 6 × 10^?4 to 10^?2 M at 25 °C. The variation of the conductivity versus concentration of the investigated system exhibits typical polyelectrolyte behaviour. The polyelectrolyte mobility was found to be dependent on the oligo(ethylene oxide) (OEO) side‐chain length. Manning's rod‐like model fails to describe these results. A simple steric effect is proposed to explain the influence of the OEO length. Copyright © 2003 Society of Chemical Industry     

半导体传感器在生物分析科学中的应用(英文)

回顾了半导体生化传感器 (ISFET 和 LA PS)在医学监测、免疫检测、免疫分析、D N A 杂交以及细胞培养等方面应用的进展。为使半导体器件适用于生化检测,对其中所采用的检测手段和取得的研究结果进行了分析。展望了通过与微流体网络相结合,基于半导体传感器的实验室芯片化的可行性。     

川东北飞仙关组碳酸盐岩气藏产能影响因素及压裂酸化新技术探讨

川东北地区飞仙关组碳酸盐岩气藏的储集层条件起好，不论直井还是水平井均可获高产工业气流，投产前的解堵酸化均可实现大幅度增产。在分析介绍该地区气藏地质特征的基础上，全面剖析了影响产能的主要因素，并对多功能深部酸化技术方案和稠化酸加砂压裂技术方案进行了具体探讨。     

农业灌溉的负效应

农业灌溉在提高农业抗灾能力、促进农业发展、改善人民生活中都发挥了十分重要的作用。但同时,灌溉打破了原有水量平衡、水土平衡、水沙平衡和水盐平衡。造成的负面效应有:水污染加剧对物理系统、生物系统(动植物和人类健康等)产生负面影响;水资源短缺降低了历史文化景观价值,对社会系统产生负面影响。应加强流域和区域灌溉水源统一调度,协调灌溉用水和生态环境用水的关系,大力发展节水灌溉,加强灌溉工程运行管理,减小农业灌溉负效应。     

新型槽栅nMOSFET热载流子效应的模拟研究

应用二维器件仿真程序 PISCES- ,对槽栅结构和平面结构器件的特性进行了模拟比较 ,讨论了槽栅结构 MOSFET的沟道电场特征及其对热载流子效应的影响。槽栅结构对抑制短沟道效应和抗热载流子效应是十分有利的 ,而此种结构对热载流子的敏感 ,使器件的亚阈值特性、输出特性变化较大     

DEA评价方法在超稠油生产经营中的应用探讨

超稠油的生产工艺非常复杂，影响油井效益的因素相对较多，因此对油井的评价就要评价各类有限资源投入的利用效果，查明积极因素和消极因素及其对经济指标的影响程度，促进经营管理的改善，寻求有效利用有限人力、物力、财力等资源的途径，实现资源的优化配置。本文通过使用DEA模型可对单井效益进行评价，对单井效益进行排队，对规模效益进行分类，对生产各投入因素进行投影分析，研究弱DEA、非DEA有效的原因，寻求对油井优化成本、提高效益的改进方案。     

数字电路中电源电压瞬间下降的成因及改进

通过分析数字集成芯片多输出中电源电压瞬间下降的原因,对常规驱动电路结构进行改进。改进后单输出电路的峰值电流降为原来的2/3,再通过优化版图的电源布线,能有效防止电源电压下降,使芯片正常稳定地工作。     

浅谈东深供水改造工程的设计监理工作

施工图阶段设计监理工作的内容归纳起来主要是对设计质量进行控制.依据<水利建设工程招标、施工图阶段设计监理试行规定>,其具体工作内容仅限于设计成果的合法性和安全性,没有充分发挥设计监理作用,对施工图阶段设计质量的理解是不全面的.施工图阶段的设计质量不仅仅是提交合法和安全的图纸,而且图纸的提交时限性、可实施性及经济性也应是考核设计质量的重要组成部分,为此东深供水改造工程的设计监理工作内容确定为"五项控制"和"两项权利",全面地对施工图阶段的设计质量进行控制.     

Science in High Magnetic Fields: What Could Be Learned?

High magnetic fields are one of the most powerful tools available to scientists for the study, modification and control of matter. This includes the knowledge on correlations effects, interaction mechanisms, structural information and understanding of mesoscopic effects. In this context, a review of recent scientific achievements at the Grenoble High Magnetic Laboratory is given to illustrate, on specific examples, the power of the Magnetic Field probe.     

The Precedence Effect in Three Species of Birds (Melopsittacus undulatus, Serinus canaria, and Taeniopygia guttata).

The perceived locations of paired auditory images, simulating direct sounds and their echoes, have been recently studied in budgerigars (Melopsittacus undulatus; M. L. Dent & R. J. Dooling, 2003a, 2003b). In this article, the authors extend those experiments to include measurements of the precedence effect using a discrimination paradigm in two additional bird species: canaries (Serinus canaria) and zebra finches (Taeniopygia guttata). Although time courses of summing localization, localization dominance, and echo thresholds were similar across all species, budgerigars had slightly higher overall levels of discrimination. The results from these experiments add further support that the precedence effect in birds is similar to that found in other animals and that the ability to suppress echoes that might degrade localization and auditory object perception may be a general property of the vertebrate auditory system. (PsycINFO Database Record (c) 2010 APA, all rights reserved)