Membrane degumming of crude rice bran oil: Pilot plant study

The procedure for the classical chemical refining of vegetable oils consists of degumming, alkali neutralization, bleaching, and deodorization. Conventional refining of rice bran oil using alkali gives oil of acceptable quality, but the refining losses are very high. A critical work has been carried out to study the application of membrane technology in the pretreatment of crude rice bran oil. Oils intended for physical refining should have a low phosphorus content, and this is not readily achievable by the conventional acid/water degumming process. The application of membrane technology for the pretreatment of rice bran oil has been investigated. The process has already been successfully applied to other vegetable oils. Ceramic membranes, which are important from the commercial point of view, were examined for this purpose. The results showed that the membrane‐filtered oils met the requirements of physical refining, with a substantial reduction in color. It was observed that most of the waxy material was also rejected. Experiments were carried out to establish the relationship between permeate flux and rejection with membrane pore size, trans‐membrane pressure and micellar solute concentration.     

复杂运动目标ISAR成像技术进展与展望

逆合成孔径雷达成像是宽带雷达实现目标信 息获取和精细描述的重要途径,但在成像过程中存在复杂运动导致散焦和成像分辨率不高两 个难题。针对目标复杂运动导致成像散焦问题,本文总结了微动对雷达波调制、进动目标成 像、 三维运动成像、分离部件成像等技术现状;针对成像分辨率不高问题,分析了多频段宽带回 波相参配准、融合成像等技术进展。本文介绍了雷达成像新技术,为解决上述两个难题带来 新的思路和途径,其中,雷达关联成像不依赖于雷达与目标的相对运动,可避免成像的复杂 运动补偿;太赫兹雷达成像容易实现大带宽和窄波束,获得目标精细雷达像。最后对新兴技 术的难点和发展趋势进行了展望。     

数字皮影动画脚本的研究与应用

为简化数字皮影动画的制作流程,提高数字皮影作品的交互性,降低数字皮影实时表演的难度,对皮影常见角色及动作进行了抽象、分类,提出一种针对特定类型的通用的骨骼模型。基于反向动力学,设计了一套描述皮影骨骼动画的脚本。该脚本通过对骨骼位置与旋转属性的控制定义皮影角色的基本动作,并通过对基本动作的叠加实现复杂动作。脚本对动作的定义基于骨骼模型而非具体角色,具有通用性。最后通过实验证明了脚本的有效性。     

Grafting poly(t‐butyl acrylate) to poly(allylamine) by inverse microemulsion radical polymerization: From comb‐polymer to amphiphilic shell crosslinked polymer nanocapsule

An interfacial grafting radical polymerization method for amphiphilic comb copolymer and shell crosslinked polymer nanocapsules was reported. Macropolyradicals on a water soluble long chain polyamine were generated with hydrogen peroxide in the water phase and subsequent grafting radical polymerization of a vinylic monomer at the water/oil interface proceeded at 65°C. In the presence of a crosslinker, the resulting graft copolymer formed a defined core‐shell structure with hydrophilic aqueous core functionalized by the polyamine and a hydrophobic crosslinked polymer shell. The structure of the core‐shell material was characterized by NMR, FTIR, DSC, TGA, SEM, TEM, and the mechanism of the graft polymerization is proposed. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci 104: 1905–1911, 2007     

Designing amino acid sequences to fold with good hydrophobic cores

We present two methods for designing amino acid sequences ofproteins that will fold to have good hydrophobic cores. Giventhe coordinates of the desired target protein or polymer structure,the methods generate sequences of hydrophobic (H) and polar(P) monomers that are intended to fold to these structures.One method designs hydrophobic inside, polar outside; the otherminimizes an energy function in a sequence evolution process.The sequences generated by these methods agree at the levelof 60–80% of the sequence positions in 20 proteins inthe Protein Data Bank. A major challenge in protein design isto create sequences that can fold uniquely, i.e. to a singleconformation rather than to many. While an earlier lattice-basedsequence evolution method was shown not to design unique folders,our method generates unique folders in lattice model tests.These methods may also be useful in designing other types offoldable polymer not based on amino acids     

Surface functionalized colloidal silica particles from an inverse microemulsion sol gel process

Colloidal silica particles are prepared via a sol gel technique carried out in an inverse microemulsion of water in a toluene solution of tetraethoxysilane (TEOS), stabilized by either an anionic surfactant AOT or isopropanol. Functionalized material was obtained using a functional coupling agent (RO)₃Si(CH₂)₃ X, X being a functional group such as methacryloyl, thiol, vinyl, amino group, or a chlorine atom. Functionalization can be carried out either directly via the direct copolycondensation of TEOS and the coupling agent, or in a two-step process involving a core-shell polycondensation of the coupling agent onto preformed silica particles. Kinetic studies of the copolycondensation are carried out using either²⁹Si NMR analysis or liquid chromatography. They show that the consumption of TEOS is more rapid than that of the coupling agent. The materials are characterized both chemically (elemental analysis, FTIR,¹³C and²⁹Si NMR CPMAS analysis), and by their particle size. The silica functionalized with a polymerizable methacryloyl group is encapsulated by a polymer layer in an inverse emulsion polymerization of acrylic acid. After inversion of the emulsion in water, the resulting material is covered with a layer of hydrophobic polymer in a conventional emulsion polymerization.     

基于链接关系分析的PgaeRank改进算法研究

经典的PageRank算法对所有出链网页采用平均分配链出权值的策略,这种方式会导致网页PR值计算的不准确性。通过对链出网页的重要性进行分析,优化链出权值的分配策略,实验结果表明,改进的PageRank算法使得页面排序的结果更加优化。     

Concentrated emulsion polymerization for preparation of β‐cyclodextrin‐supported chromatography columns

Concentrated inverse emulsion polymerization was used for making chromatography columns (based on crosslinked polystyrene divinylbenzene (PS‐DVB)) with pore sizes less than 10 μm. According to DSC‐thermal gravimetry thermograms, it was confirmed that the residual monomer concentration after polymerization process is negligible. For application of these columns in chiral chromatography, the β‐cyclodextrin is chemically fixed on the PS‐DVB resin pore surface. The presence of hydroxyl groups in the PS‐DVB resin after chemical modification was confirmed by FTIR spectroscopy. By chemical modification of the PS‐DVB resin, thermal stability increased up to 446°C. The structure of columns was analyzed by scanning electron microscopy (SEM). SEM evaluations showed that the porous structure of PS‐DVB resin was maintained intact after the chemical modification with β‐cyclodextrin. According to X‐ray data, presence of the crystalline domain that is related to β‐cyclodextrin is confirmed.© 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 857–863, 2006     

基于LS-SVM逆系统的无轴承异步电机解耦控制

无轴承异步电机具有非线性、多变量和强耦合的特点,要实现电机稳定悬浮和旋转运行,必须对其进行非线性动态解耦控制。为了克服逆系统方法精确建模难的局限性,采用基于最小二乘支持向量机(LS-SVM)α阶逆系统方法对无轴承异步电机进行动态解耦控制的研究。首先利用最小二乘支持向量机辨识出无轴承异步电机的逆模型,然后将它串联在原系统前,将无轴承异步电机解耦成四个独立的伪线性子系统-2个径向位移子系统、一个速度子系统和一个磁链子系统。为保证鲁棒性能,最后对解耦后的系统采用非线性内模控制策略。研究表明,LS-SVMα阶逆系统方法能够实现无轴承异步电机径向悬浮力和旋转力之间的动态解耦控制,控制系统具有良好的静态和动态性能。     

基于GA-SVM逆系统的机械臂内模控制

六自由度机械臂系统具有强耦合、多输入多输出、非线性的特性,且难以求解精确的动力学模型。针对上述问题,提出了一种基于GA-SVM逆系统的六自由度机械臂内模控制方法。将逆系统方法用于六自由度机械臂的解耦可以有效简化控制器的设计,为了避免逆系统方法复杂的解析过程,采用基于支持向量机(SVM)辨识逆系统模型以实现解耦,并用遗传算法(GA)优化SVM系统参数以提高模型的准确性。同时,为了弥补SVM辨识逆系统的误差以及抑制系统存在的扰动,设计内模控制器以保证系统的鲁棒性和稳定性。实验结果表明,该方法不需要知道六自由度机械臂的数学模型和内部结构,也能实现各关节位置的快速精确定位控制,且具有良好的鲁棒性,结构简单,需要调节的参数少,易于工程实现。