Specific interactions in blends containing Chitosan and functionalized polymers. Molecular dynamics simulations

Chitosan (CS)/poly(vinyl alcohol) (PVA) and Chitosan/poly(2-hydroxyethyl methacrylate) (P2HEM) blends have been studied through molecular dynamic simulations. In a previous work it was found miscibility between these polymers and it was attributed to hydrogen bonding formation. However, the experimental information obtained was not enough to know which of the interacting groups of Chitosan, i.e. -CH₂OH or -NH₂, are responsible of the interaction. Therefore, we have performed molecular dynamics simulation runs of 1 ns in order to calculate radial distribution functions (RDF) for the groups tentatively involved in the interaction. The results are correlated with our previous experimental data. This way, we have obtained a more precise conclusive information about the interactions involved as function of the blends composition. For low compositions of PVA and P2HEM the interaction is predominantly with the hydroxymethyl groups of CS while as the composition of PVA and P2HEM increases, the interaction with the amine groups increases.     

日本地震简介和日建设计的抗震设计

为更好地帮助读者理解本刊各篇论文的内容,本文简要介绍日本的地震状况,日建设计对地震设计的考虑方法,以及日建设计的设计用人工模拟地震波。     

天津独流减河工程监控系统现地通信单元设计

提出一种配电网电容电流测量的新方法，在零序电压互感器的开口三角侧串联一个可调电感，通过注入一个变频恒流信号寻找配电网的谐振频率，改变可调电感的数值后寻找另一谐振频率，联立2个谐振方程求解电容电流，该方法消除了电压互感器漏抗对测量的影响。开发了配电网电容电流测量仪，经模拟试验和现场测试表明，该方法具有安全、快捷、准确等特点，适用于中性点不接地或经随调式消弧线圈接地配电网。     

注水开发后期提高油砂体采收率方法探讨

注水开发后期，研究油砂体剩余油分布规律，实施油砂体综合治理，完善油砂体注采关系是提高最终采收率的重要途径之一。按照含油面积、采出程度及生产动态特点将油砂体分为3类。根据每类砂体的不同特点，采取相应的治理措施，取得了较好效果，累积增油18．5kt，增加水驱储量1．08Mt。注水开发后期提高油砂体采收率必须以剩余油的分析研究为指导，以井网对剩余可采储量的控制为前提，以油水井措施的联动为手段，从而达到提高最终采收率的目的。     

济钢105m^2带冷机综合密封节能降耗提高冷却效率的实践

由于烧结机扩容同时工艺优化去掉热筛后，使烧结矿的料层提高，热返矿进入带冷机超负荷运行料温持续偏高，并且带来台车漏风漏料扬尘，冷却风量效率低，烧损成品皮带等问题。通过采取综合密封及改进相关冷却方式，解决了以上存在的问题，并达到节能降耗的目的。     

介孔氧化铁对正辛醇乙氧基化反应的催化性能

以十二烷基磺酸钠为模板剂、乙二胺为碱性介质,将水热法合成的氧化铁/十二烷基磺酸钠复合中孔材料在550℃、空气气氛中煅烧10h,除去模板剂,得到介孔氧化铁。通过X射线衍射、氮气吸附-脱附方法对介孔氧化铁的晶体结构和表面物性进行表征。表征结果显示,煅烧后的介孔氧化铁具有典型的六方介孔的结构特征,平均孔径为5.4nm。将介孔氧化铁用于催化正辛醇乙氧基化反应,研究结果表明,升高反应温度和初始压力、增加催化剂用量,可加快环氧乙烷的反应速率,同时产物的相对分子质量分布较窄。当平均聚合度为6.5时,正辛醇聚氧乙烯醚相对分子质量分布的选择性系数达到21.1。     

Calculation of the Thermodynamic Properties of Diatomic Substances Based on the Ornstein-Zernike Equation

The new method of calculation of intermolecular distribution functions is used to calculate various thermodynamic properties of diatomic substances (oxygen, nitrogen, ethane). Good agreement is demonstrated between the calculation and experimental data.     

The Transport Properties of Hot Electrons in a Xenon/Methane Mixture

The results are given of numerical solution of the Boltzmann equation in a binomial approximation in view of elastic and inelastic electron collisions in Xe+CH₄ mixtures and in pure methane. The electron energy distribution functions obtained are used to calculate the electron transport coefficients for E/N values of up to several Townsends, i.e., the drift velocity, mobility, average and characteristic energies, diffusion coefficient. The results of calculation for pure methane fit the available experimental data. A similarity rule is found for the electron transport coefficients in a Xe+CH₄ mixture with different concentrations of methane molecules, which enables one to determine the values of transport coefficients in a mixture with a minor (less than 30 percents) methane content.     

六盘山盆地与酒西盆地成藏条件对比

研究认为，六盘山盆地与酒西盆地具有相似的构造演化特征和油气成藏条件。中生代为走滑拉分盆地，发育张扭伸展断层系，新生代为陆内前陆盆地，发育扭压逆冲断裂系；中生代坳陷都发育生烃潜力较好的白垩系烃源岩，具有相似的烃源岩演化特征、生储盖组合条件和油气运聚特征。因此，分析酒西盆地油气藏分布特征和成藏控制因素，有利于认识和预测六盘山盆地的油气分布规律，以便指导下一步的油气勘探。