化学防水材料的应用与发展

本文综合阐述了化学防水材料的起源、应用范围、种类及发展趋势。     

高岭土在碳热还原氮化过程中的相变

系统研究了苏州高岭土碳热还原氮化合成SiAlON过程在不同温度下的相变。对试样的XRD、SEM以及EDXA分析结果表明 ,1 30 0℃之前 ,试样中没有氮化物生成 ,物相为莫来石、石英和方石英 ;1 30 0℃时 ,高岭土开始发生氮化反应 ,生成过渡型SiAlON和β SiAlON。此时 ,石英和方石英相基本消失 ;1 4 0 0℃时 ,过渡型SiAlON、β SiAlON和X SiAlON三相共存 ,β SiAlON有所增多并有少量刚玉相生成 ;从 1 4 50℃到 1 550℃ ,Z值为 3的β SiAlON成为惟一的氮化产物 ,与少量SiC和刚玉相并存。莫来石在 1 50 0℃时完全消失     

塑料模具材料数据库系统的开发与应用

采用结构化程序和规范化数据库技术开发了塑料模具材料数据库系统，介绍了数据库系统的总体结构、主要模块功能及选材方法。该系统对材料数据信息进行了科学的分类管理，提供了高效的查询方法，实现了对塑料模具材料数据库系统的有效维护。     

PVC防水卷材的配方研究

研究了利用废旧软聚氯乙烯回收料(旧料)生产PVC塑料防水卷材的配方及其对卷材拉伸性能的影响。结果表明,PVC塑料卷材的拉伸强度和断裂伸长率随PVC树脂添加比例增加而提高,而相同添加量的SG-3型PVC树脂比SG-5型PVC树脂的拉伸性能高；在试验范围内,增塑剂用量增加,卷材的拉伸强度降低,伸长率先升后降；添加CPE能提高PVC卷材伸长率,但拉伸强度有所下降。当CaCO_3用量低于20份时,卷材的拉伸强度和伸长率随CaCO_3添加量增加而提高。PVC防水卷材的优选配方(质量份)：旧料85份,PVC树脂(SG-3型)15份,DOP 5份,CPE 3份,稳定剂(TLS)0．6份,其它助剂适量。     

Entanglement Loss in Fast-Flowing Entangled Polymer: Numerical Simulation of The Short-Chain Behavior and Interpretation of Phenomenology

Although some of the important consequences of flow-induced entanglement loss in entangled polymer rheology have recently been recognized, this specific molecular mechanism has rarely been investigated quantitatively based on experiments or molecular theories. For the first time, the amount of entanglement loss of a short entangled linear polymer (i.e., seven entanglements per chain at equilibrium) during fast-flow deformation is directly tracked in the stochastic simulation of an existing reptation model. The primary finding is that significant entanglement loss is observed in both fast elongation and fast shearing, and, contrary to some earlier conjectures, is particularly pronounced in elongational flow when polymer chain stretching formally commences. Furthermore, according to the current simulation in which three different CCR (Convective Constraint Release) schemes are considered, entanglement loss appears to have very prominent effects on the elongational rheology of an entangled linear polymer – an observation that had rarely been recognized or considered before. On the other hand, the currently explored features of flow-induced entanglement loss are tentatively linked to a wide variety of peculiar empirical properties of temporarily entangled polymer liquids. In particular, we are thus able to provide a consistent molecular explanation of the fairly well-known phenomenological effects of polydispersity and long-chain branching leading to a pronounced strain-hardening phenomenon, in view of two newly proposed effects of heterogeneous relaxations in preventing, directly or indirectly, fast entanglement loss during flows.     

沥青水下成型技术的研究与应用

介绍了沥青水下成型新工艺。该工艺采用水下低温成型,生产出类似巧克力形状的沥青,彻底解决了沥青烟污染的问题。     

纳米LaF3的介电性能

采用水溶液沉淀法制备了平均粒径17纳米的LaF3粉体,通过真空压结成形法制备了纳米LaF3块体,通过测量复阻抗谱研究了纳米LaF3块体材料的介电性能。     

环氧树脂基含水定形相变材料

以固体石蜡和液体石蜡进行复配制得低熔点石蜡，采用十二烷基苯磺酸钠（SDBS）作表面活性剂，将水分散于低熔点石蜡中，然后加入环氧树脂，制得含水型树脂基定形相变材料。显微分析显示，石蜡和水的包合体在基体中分散均匀，分散的石蜡粒径基本上在10μm以下，包合体中水呈梭型．包合体粒径分布范围窄；相变过程无脱离现象，材料生产成本低，具有良好的应用前景。     

雕塑创作中材质肌理的运用

主要分析了材质肌理在雕塑创作中的运用，通过我对泥、木、石、金属及其肌理表现的深层次的认识与分析，结合许多实例，来说明材质肌理在雕塑创作中的重要性。     

压力容器制造中材料代用的常见问题分析

就压力容器制造过程中常常遇到的材料代用问题进行综合分析,并阐述了相应观点。