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51.
内蒙古敖包吐萤石矿床地质和地球化学特征 总被引:2,自引:0,他引:2
笔者总结了敖包吐萤石矿床的地质特征,并通过萤石的稀土元素的地球化学和Nd同位素研究,探讨了该矿床的成矿作用和成矿物质来源。敖包吐萤石矿床产出于下二叠统大石寨组火山—沉积岩与燕山中期花岗岩的接触带,为单一萤石矿床。萤石矿石的稀土元素的含量(∑REE)变化范围为(8.04~30.04)×10-6,平均为19.42×10-6;轻重稀土LREE/HREE值0.24~0.65,平均0.52;LaN/YbN为0.07~0.62,平均0.26;δEu为0.42~0.90,平均0.60,具Eu负异常和明显重稀土富集的特征。岩矿石的Nd同位素研究表明,萤石矿石的εNd(t)都表现为很大的负值,以成矿主期年龄138Ma计算的εNd(138Ma)为-7.30~-30.55,具有古陆壳的演化特征,暗示其成矿的物质来源主要是壳源物质。在Moller的Tb/La-Tb/Ca成因判别图解中,敖包吐矿床的萤石的结晶作用表现为重新活化的趋势,反映流体具有混源的特征,既有热液成因,又有沉积成因。二叠世的海相火山活动通过海底喷气和喷流的作用形成了初始矿源层,而燕山中期花岗岩浆的侵位与结晶分异,又对初始矿源层的活化和富集提供了流体和热能的来源。成矿流体在经历了长期的演化后在大石寨组的构造薄弱破碎的的部位沉淀析出,形成敖包吐萤石矿床。 相似文献
52.
江西德兴矿集区水系沉积物重金属污染的时空对比 总被引:5,自引:0,他引:5
对比研究矿山开采一定时段内区域环境污染的时空变化特征,对于动态监测矿山开采对区域环境质量的影响情况、污染趋势等,具有重要的科学意义和实际价值。本文在利用2004年野外采集与测试分析的330个水系沉积物样品重金属含量数据基础上,充分利用矿山开采早期(1989)的1:20万乐平幅(As、Hg、Cd、Cr、Zn、Cu、Pb)水系沉积物地球化学图,通过数据预处理,分别对样品采集点重金属元素含量的统计分析和地质累积指数法评价的基础上,采用GIS的三维空间分析功能,对比研究德兴地区水系沉积物重金属污染时空变化。研究结果表明,十几年来,矿山开采对区域水系沉积物已造成了严重的污染,主要集中分布在是德兴铅锌和铜钼矿区德兴河与大坞河流域及其周边地区、乐安河下游沿岸局部地区、西北煤矿区以及乐安河下游乐平附近的煤矿区。 相似文献
53.
54.
滇西沘江流域水体中重金属元素的地球化学特征 总被引:6,自引:1,他引:5
通过测定流经兰坪金顸铅锌矿区的沘江水体中Pb、Zn、Cd、As的含量和底泥中重金属元素的化学形态的含量,分析了重金属元素的分布和化学形态的变化。结果表明,沘江水遭到了Cd污染,底泥已经成为重金属元素的蓄积库,以国家土壤环境质量标准(Ⅲ级)衡量,Pb、Zn、Cd和舡分别超标3.4倍、15.8倍、106倍和2.6倍。沘江水中重金属元素含量的峰值在矿山附近的下游,而底泥中重金属元素的峰值在矿山下游30-50km的地方,矿业活动、水流变缓、pH等水体环境条件的变化都能影响水和底泥中重金属元素的含量。底泥中的Pb以碳酸盐结合态为主,Zn和Cd以铁锰氧化物结合态为主,而As以残渣态为主。Pb、Cd、Zn三种元素的环境有效态含量比较高,对沘江流域生态环境具有潜在的巨大的危害。 相似文献
55.
In northern Jiangsu coastal zone area, Guanhe River is the biggest river and has the best navigation conditions among rivers
which flow into the Yellow Sea. The grain sizes show gradual increase from the high intertidal zone to lower intertidal zone.
The heavy metal values have slight changes along both sides of the river mouth, but show an evident change perpendicular to
the tidal flat. In the latter case, they show a good correlation with grain size fluctuation, that is, the heavy metal values
gradually decline when the grain size increases from the high intertidal zone to the lower intra-tidal zone. Analyses of the
heavy metal elements show that on the Guanhe estuary surface sediment, the content of the elements Hg, As and Cu is above
background values; Pb and Zn contents are rather close to the background values; and Cd content is less than the background
values. The element Hg comes out to be harmful in a medium level to ecological environment, while the elements of Cr, As,
Cu, Pb, Zn and Cd fall in a safe range of MPL. On the whole, Guanhe estuary tidal flat is not very harmful to the ecology
in terms of the heavy metals.
__________
Translated from Marine Geology & Quaternary Geology, 2007, 27(5): 23–32 [译自: 海洋地质与第四纪地质] 相似文献
56.
57.
Geochemical studies of the trace metal concentrations in suspended particulate matter (SPM) and sediment trap material from a permanently anoxic fjord, Framvaren, South Norway in 1989 and 1993 indicate that extremely high concentrations of zinc (max = 183920 mg/kg), copper (max = 4130 mg/kg), lead (max = 2752 mg/kg), and cadmium (max= 8.1 mg/kg) sometimes (1993) occur in the SPM collected in the anoxic water layer. The highest concentrations of Zn occur just below the redoxcline at 22 m water depth (in 1993), and copper, lead and cadmium have maximum concentrations between 30 and 80 m depth, where the amount of total SPM is at a minimum (about 0.3 mg/L). On a mass per volume (g/L) basis, the maximum concentrations of Cd, Cu and Fe occur at the interface (21m) and those of Zn occur just below the redoxcline (22 m depth). The SPM and sediment trap data suggest that the metals are precipitated as sulfide minerals in the anoxic water. The presence of particulate sulfides was confirmed by SEM studies that show the occurrence of discrete metal (Cu, Fe, Pb, and Zn) sulfide particles in size from 10–20 m as well as framboidal pyrites (1–5 m in size). Higher levels of metal sulfides at intermediate depths rather than in the deep water of Framvaren (> 100 m), may be due to input of trace metals by water exchange over the sill in the upper part of the water column. In the deep water, less metal sulfide precipitation takes place due to depletion of trace metals, and the dilution of particulate metal concentrations by organic matter and by the chemogenic formation of calcite. 相似文献
58.
59.
Anna Brooks Rehema M. White David C. Paton 《International Journal of Salt Lake Research》1995,4(2):133-163
The hypermarine southern Coorong is threatened by proposals to drain relatively fresh surface water and groundwater from adjacent agricultural areas into the Coorong. These influent waters carry moderate loads of heavy metals. Acute toxicity of heavy metals toDiacypris compacta, an abundant ostracod in the Coorong, was measured in the laboratory at 18°C in a static system using Coorong water (pH 7.8 salinity 50 ppt). At 4 days (96 h) the mean values of LC50 for copper, zinc, lead and, cadmium respectively were 0.8, 2.1, 3.1 and 4.3 mg L–1, and at 8 days the respective mean LC50
s were 0.4, 0.7, 2.2 and 1.1 mgL–1. The effect of two or three metals on mortality was additive in some cases and synergistic in other cases, but generally less than additive. However, in all cases mortality was greater in the presence of two or three metals than in the presence of a single metal. According to ANZECC (1992) guidelines, maximum acceptable concentrations of heavy metals should be no higher than 0.01 x the lowest LC50 value. Using the lowest LC50 values forDiacypris compacta obtained at 8 days, maximum acceptable concentrations in the Coorong would be 4, 5, 9 and 22 gL–1 for copper, zinc, cadmium and lead respectively, the values for zinc and copper failling below those recommended by ANZECC (1992) for marine waters. Reported concentrations of copper and zinc in surface water and groundwater in areas adjacent to the Coorong sometimes exceed these values, hence drainage of these waters into the Coorong represents a significant hazard to the Coorong biota. 相似文献
60.
Mehtap Paul Meryem Seferinoğlu Gul Asiye Ayçık Åke Sandström Michael L. Smith Jan Paul 《International Journal of Mineral Processing》2006
The leaching of coal and coal/asphaltite/wood-ashes in sulfuric acid (pH 1.0, 25 °C, S/L, 1:10) was studied as a function of time; acid consumption and extracted metal concentrations are presented. Whole coals consumed acid rapidly during the first few minutes, followed by slow acid consumption. Wood-, lignite-, and asphaltite-ashes consumed acid in two stages, the rapid phase extending < 30 min and the slow phase extended up to 10 days. The rapid phase was dominated by the dissolution of Ca, K and Mg ions for wood-ash, by Ca, Al and Mg ions for lignite-ash and Ca and Mg ions for asphaltite-ash. The sulfur concentration in solution and the concentrations of Ca, Fe, K, Mg, Na, P, Al and Mn in the aqueous phase verified the neutralizing capacity of the untreated ashes as well as the formation of insoluble sulfates in the residues. The slow phase kinetics differed for different fuels and exhibited leaching of several abundant elements—Fe, Al, K, Na and Mn. Trace elements (Ba, Cd, Co, Cr, Cu, Mo, Ni, Pb, Th, U, V, Zn) sometimes required up to 32 h for maximal extraction from ashes. Suggestions are presented regarding the chemical nature of trace elements in the untreated coals and ashes and suitable residence times for economical industrial processes. We think it possible to combine bacteriological oxidation of sulfidic concentrates of acid leaching from ash of various qualities or even whole coals. 相似文献