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81.
用化学共沉淀法制备了3mol%Y_2O_3-ZrO_2超细粉末。利用热分析,x射线,透射电镜,颗粒粒度分析仪分析了粉料的相组成;颗粒形貌、大小;粉料的团聚状态;化学组成的均一性以及其烧结性能,并结合烧结试样的显微结构和力学性能对粉末的性能做出了评价。实验表明,所制备的粉料组成较为均匀;粒度分布窄;团聚体尺寸小,烧结活性高;颗粒粒度约为200(?)。粉料的相组成主要为四方相和约26%的单斜相。3Y-TZP陶瓷材料三点弯曲强度达1479.14MPa,断裂韧性为13.2MPa·m~(1/2),超塑性压缩变形达190%。 相似文献
82.
Fred J. Parker 《Journal of the American Ceramic Society》1990,73(4):929-932
The characterization and properties of ceramic composites containing the phases Al2 TiO5 , ZrTiO4 , and ZrO2 are described. The range of compositions investigated gives very low average thermal expansions (α24–1000°C as low as −2.0 × 10−6 °C−1 ) and excellent high-temperature stability. The low thermal expansions are apparently due to a combination of microcracking by the titanate phases and a contractive phase transformation by the ZrO2 . The crystal chemistry and microstructure of the product are processing dependent. Although the composites represent a complex microcracking system, the low thermal expansions and high-temperature stability make them potential candidates for commercial applications requiring thermal shock resistance. 相似文献
83.
碳,氮对氧化锆相结构稳定性的作用 总被引:3,自引:0,他引:3
利用热处理研究了碳、氮对氧化锆相结构和相变的影响。实验结果表明:碳、氢原子在高温下可以渗入到氧化锆中去,阻止了氧化锆高温相(四方相和立方相)在冷却过程中向低温相(单斜相)的转变。 相似文献
84.
Mullitization of Diphasic Aluminosilicate Gels 总被引:4,自引:0,他引:4
Recent studies have shown that the mullitization of diphasic aluminosilicate matrices comprising transitional alumina and amorphous silica occurs via a nucleation and growth process. Nucleation is preceded by a temperature-dependent incubation period. Following this incubation period, rapid nucleation of mullite occurs, producing about 1.8 × 1011 nuclei/cm3 , which remains constant throughout the rest of the transformation. Both incubation and mullite growth are thermally activated processes with apparent activation energies of 987 ± 63 and 1070 ± 200 kJ/mol, respectively. The growth rate of mullite grains under isothermal conditions is time dependent. An interpretation of these results is proposed on the basis of the nucleation and growth concepts of LaMer and Dinegar which supports the concept that the growth rate of mullite grains is controlled by the dissolution of transitional alumina into the amorphous matrix. 相似文献
85.
用于测定钢液低氧含量的双层固体电解质研究 总被引:1,自引:0,他引:1
采用“毛坯浆料法”在ZrO2(9%摩尔含量MgO)管状固体电解质基体表面制备了厚度为1-4μm的ZrO2(10%摩尔含量Y2O3)固体电解质涂层,并分别对此在本实验室和美国LeedsandNorthrup公司进行了钢液低氧含量测试,结果表明:涂层没有破坏基体的抗热震性:氧浓差电池电动势的重现性偏差由原来的±2mV;电动势的绝对值提高10mV左右;而比日本Toray公司的同类产品提高35mV,这说明 相似文献
86.
Y2O3改性的MgO—ZrO2共析陶瓷 总被引:2,自引:0,他引:2
共析MgO-ZrO2陶瓷添加Y2O3可以获得高温热稳定性和较佳的力学性能,添加2%Y2O3时断裂韧性为7.6MPa.m^1/2,弯曲强度为618MPa,用透射电子显微镜详细研究和讨论了上述材料的时效显微组织和韧化的原因。 相似文献
87.
88.
Yoshihiro Hirata Kazuyoshi Sakeda Yumi Matsushita Kinji Shimada Yoshimi Ishihara 《Journal of the American Ceramic Society》1989,72(6):995-1002
Submicrometer SiO2 -Al2 O3 powders with compositions of 46.5 to 76.6 wt% Al2 O3 were prepared by hydrolysis of mixed alkoxides. Phase change, mullite composition, and particle size of powders with heating were analyzed by DTA, XRD, IR, BET, and TEM. As-produced amorphous powders partially transformed to mullite and Al-Si spinel at around 980°C. The compositions of mullite produced at 1400° and 1550°C were richer in Al2 O3 than the compositions of stable mullite solid solutions predicted from the phase diagram of the SiO2 -Al2 O3 system. Particle size decreased with increasing Al2 O3 content. The sintered densities depended upon the amount of SiO2 -rich glassy phase formed during sintering and the green density expressed as a function of particle size. 相似文献
89.
The cubic ( c -ZrO2 ) and tetragonal zirconia ( t -ZrO2 ) phase stability regions in the system ZrO2 –Y2 O3 –Ta2 O5 were delineated. The c -ZrO2 solid solutions are formed with the fluorite structure. The t -ZrO2 solid solutions having a c/a axial ratio (tetragonality) smaller than 1.0203 display high fracture toughness (5 to 14 MPa · m1/2 ), and their instability/transformability to monoclinic zirconia ( m -ZrO2 ) increases with increasing tetragonality. On the other hand, the t -ZrO2 solid solutions stabilized at room temperature with tetragonality greater than 1.0203 have low toughness values (2 to 5 MPa · m1/2 ), and their transformability is not related to the tetragonality. 相似文献
90.
Mahyar S. Dadkhah David B. Marshall Winfred L. Morris Brian N. Cox 《Journal of the American Ceramic Society》1991,74(3):584-592
Residual strains responsible for crack tip shielding have been measured within transformation zones surrounding cracks in Mg-PSZ. Two techniques were used for strain measurement: moiré interferometry and high-resolution image matching. Both methods provide maps of differential in-plane displacements within the specimen surface intersected by the crack, the latter method with the higher resolution. The results are compared with finite-element analysis to assess surface relaxation effects, and the measured strains are used to evaluate the crack tip shielding stress intensity factor. Calculations based on the assumption that the unconstrained transformation strain is hydrostatic dilatation yielded results that were significantly smaller than the measured toughness increases. 相似文献