Flash-lamp annealing of semiconductor materials—Applications and process models

Flash-lamp annealing (FLA) on a millisecond time scale has been shown to be a promising tool in the preparation of high-quality semiconducting materials. The process imposes time varying through-thickness temperature profiles on the substrates being processed, and consequently thermal stresses. A combined thermal and optical model has been developed to predict the substrate temperature distribution and this model has been linked to a structural model to compute stresses and deflections. The paper shows how these models can be used to explore process conditions in flash lamp annealing, with particular regard to the annealing of ion implants in silicon and the crystallization of amorphous silicon layers on glass substrates.     

单壁纳米碳管/纳米铝基复合材料的增强效果

用半连续氢电弧法和活性氢等离子蒸发法分别制备出单壁纳米碳管(SWNTs)和纳米A1粉体，然后用提纯后的SWNTs和纳米A1粉体制备出SWNTs含量(质量分数)分别为0、2．5％、5．0％、7．5％和10.0％的单壁纳米碳管／纳米铝基块体复合材料．SWNTs对高强度纳米A1基体具有显著的增强作用，当SWNTs含量小于5．0％时，材料的硬度随着SWNTs含量的提高线性上升．其中5％SWNTs和纳米A1的复合增强效果最好，其硬度可达2.89GPa，大约是粗晶A1(0．15GPa)的20倍．当SWNTs含量超过5．0％时，增强效果开始缓慢的下降．讨论了单壁纳米碳管增强纳米铝基复合材料的强化机制．     

晶体硅薄膜电池制备技术及研究现状

晶体硅薄膜太阳电池近些年来得到广泛的研究和初步的商业化探索。根据所采用的晶体硅薄膜沉积工艺中温度范围的不同，晶体硅薄膜电池研究可分为高温路线和低温路线两个不同发展方向。本文分别从这两个方向综述了目前国外晶体硅薄膜电池制备技术的最新进展，最新实验室研究结果。报导了晶体硅薄膜电池商业化进展状况，指出了晶体硅薄膜电池实现产业化必须解决的问题。     

Preparation of Compound Ultrafine CeO2 by Wet-Solid-Phase Mechanochemical Modification

To satisfy practical requirements from industrial applications, an alternate route for synthesis compound ultrafine CeO2 powders by wet-solid-phase mechanochemical modification using industrial grade hydrated cerium carbonate as raw material was proposed.The effect of modifier reaction percentage, reaction time, calcining temperature and modifier amount on particle size, density, suspensibility, and hardness of compound CeO2 powder was investigated.The phase evolutions of preparation process were characterized by XRD.SEM micrograph of the final product shows that compound CeO2 powders obtained are well-dispersed, spherically-shaped, uniformly-sized and submicron-sized particles.The method is readily available in raw material, low in cost, simple in process, and has great potential for industrialization.The compound CeO2 powders of different physical properties can be synthesized by controlling the above-mentioned influence factors in preparation process.     

高压水射流技术粉碎原盐的研究

以原盐为被粉碎研究对象,通过对高压水射流粉碎原盐形貌的观察和成分分析、高压水射流原盐粉碎性能分析,以及高压水射流粉碎原盐各影响因素的正交分析,研究表明高压水射流粉碎技术对原盐具有良好的解理性且粉碎效率高、耗能低。各因素对原盐粉碎效果的影响顺序为:射流压力卤水喷嘴直径、料液混合喷嘴直径、靶面形状。     

汽轮机轴承烧瓦与轴颈的渗巴氏合金现象

简述轴承工作性质，巴氏合金应用与相组成的基本情况。论述汽轮机转子在两个电厂长期运行后，由于轴颈发生的不正常摩擦损伤，在大修改造中由无损检查、机械加工揭示出轴颈存在严重的渗巴氏合金现象，低熔点金属Sn、Sb与Cu向转子材料晶界的深层渗入最终导致了3根大型在投转子的严重开裂与报废。图11表2     

低松装密度水雾化铜粉工艺的研究

本文研究了氧化 还原法生产铜粉的新工艺 ,该工艺是通过氧化还原将水雾化铜粉加以表面改性 ,形成海绵状的粉末 ,显著降低水雾化铜粉的松装密度 ,这种铜粉既具有电解铜粉低的松装密度 ,又具有水雾化铜粉高的流动性。讨论了氧化时间、氧化温度对铜粉松装密度的影响。本工艺是一种新型环保、节能、可替代电解法生产铜粉的先进工艺     

W-Ni-Cu高比重合金注射成形烧结收缩及性能的研究

研究了W-Ni-Cu高比重合金注射成形工艺过程收缩率和性能。比较了模具尺寸、注射坯尺寸、烧结坯尺寸，及烧结阶段各方向收缩率的关系，发现实际收缩与理论预测收缩率较为一致，但在厚度方向存在与其他方向收缩不一致的情形，这与由重力作用产生的塑料流动有关；还探讨了烧结坯密度与烧结条件的关系，测定了烧结坯的力学性能及断口形貌、金相组织，烧结坯在1400℃，90min烧结达到了99％的相对密度，断裂强度600MPa以上。     

光敏树脂及其紫外光固化涂料发展新动向

按紫外光固化涂料形态分类,并着重从光敏树脂方面综述了近年来紫外光固化涂料及其光敏研究及开发的新动向。在开发油性紫外光固化涂料新品种、提高其综合性能、拓宽应用领域的同时,研究开发水性紫外光固化涂料、紫外光固化粉沫涂料是目前紫外光固化涂料的重要发展趋向:在完善线形光敏齐聚物的同时,研究水溶性光敏齐聚物、树枝形和超支化结构聚合物体系又成为紫外光固化涂料用树脂研究的新热点。     

The flame retardant mechanism of polyolefins modified with chalk and silicone elastomer

This paper presents the current understanding of the flame retardant mechanism of Casico?. The study includes the flame retardant effect of each individual component: ethylene–acrylate copolymer, chalk and silicone elastomer, as well as the formation of an intumescent structure during heating. The flame retardant properties were investigated by cone calorimetry and oxygen index tests. To obtain insight into the flame retardant mechanism, heat treatment under different conditions has also been performed. The results indicate that the flame retardant mechanism of Casico is complex and is related to a number of reactions, e.g. ester pyrolysis of acrylate groups, formation of carbon dioxide by reaction between carboxylic acid and chalk, ionomer formation and formation of an intumescent structure stabilized by a protecting char. Special emphasis is given to the formation of the intumescent structure and its molecular structure as evaluated from ¹³C MAS‐NMR and ²⁹Si MAS‐NMR, ESCA and XRD analysis. After treatment at 500°C the intumescent structure consists mainly of silicon oxides and calcium carbonate and after treatment at 1000°C the intumescent structure consists of calcium silicate, calcium oxide and calcium hydroxide. Copyright © 2003 John Wiley & Sons, Ltd.