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22.
新型硅蜡乳液的制备   总被引:3,自引:0,他引:3  
将蜂蜡用复合乳化剂乳化时加入自制的乳化助剂,制得稳定的蜡乳液,将该乳液与羟基蛙油乳液复配,制得乳白色略带蓝光硅蜡乳液,该硅蜡乳液用于绵羊服装革作顶层手感改善剂,除了获得油润的蜡感和滑爽感之外,还使成革具有抗菌和抗静电作用。  相似文献   
23.
Elasticity is discussed as an aspect of viscoelasticity, which is described by the tube model. The effects of both crosslinks and entanglements contribute to this model and a discussion of how these effects can be quantified is given. At high enough concentration, entanglements ensure the existence of elastic effects even without crosslinks, and a theory is presented on how this dynamical phase change comes about.  相似文献   
24.
The earliest investigations on rubber elasticity, commencing in the 19th century, were necessarily limited to phenomenological interpretations. The realisation that polymers consist of very long molecular chains. commencing c. 1930, gave impetus to the molecular theory of rubber elasticity (1932-). according to which the high deformability of an elastomer, and the elastic force generated by deformation, stem from the configurations accessible to long molecular chains. Theories of rubber elasticity put forward from 1934-1946 relied on the assumption that the junctions of the rubber network undergo displacements that are affine in macroscopic strain. The theory of James and Guth (1947) dispensed with this premise, and demonstrated instead that the mean positions of the junctions of a ‘phantom’ network consisting of Gaussian chains devoid of material properties are affine in the strain. The vital significance of the distinction between the actual distribution of chain vectors in a network and their distribution if the junctions would be fixed at their mean positions went unnoticed for nearly 30 years. Experimental investigations, commencing with the incisive work of Gee in 1946. revealed large departures from the relationship of stress to strain predicted by the theories cited. This discrepancy prompted extensive studies, theoretical and experimental, during succeeding years. Inquiry into the fundamentals of polymer networks, formed for example by interlinking very long polymer molecules, exposed the need to take account of network imperfections, typically consisting of chains attached at only one end to a network junction. Various means were advocated to make corrections for these imperfections. The cycle rank ζ of the network has been shown (1976) to be the fundamental measure of its connectivity, regardless of the junction functionality and pattern of imperfections. Often overlooked is the copious interpenetration of the chains comprising typical elastomeric networks. Theories that attempt to represent such networks on a lattice are incompatible with this universal feature. Moreover, the dense interpenetration of chains may limit the ability of junctions in real networks to accommodate the fluctuations envisaged in the theory of phantom networks. It was suggested in 1975 that departures from the form predicted for the elastic equation of state are due to constraints on the fluctuations of junctions whose effect diminishes with deformation and with dilation. Formulation of a self-consistent theory based on this suggestion required recognition of the non-affine connection between the chain vector distribution function and the macroscopic strain in a real network, which may partake of characteristics of a phantom network in some degree. Implementation of the idea was achieved through postulation of domains of constraint affecting the equilibrium distribution of fluctuations of network junctions from their mean positions. This led in due course to a theory that accounts for the relationship of stress to strain virtually throughout the ranges of strain accessible to measurement. The theory establishes connections between structure and elastic properties. This is achieved with utmost frugality in arbitrary parameters.  相似文献   
25.
Recent developments in rubber-toughened structural acrylic adhesives now offer sheet steel fabricators the opportunity to replace conventional metal fastening techniques such as spot welding with lower cost, durable, more versatile structural adhesive bonding. These developments, in particular much improved ability to bond oily/waxy surfaces common to the motor car industry and improved retention of fracture toughness after exposure to paint stoving temperatures, are discussed in this paper.  相似文献   
26.
复合乳化沥青的粘附性试验方法研究   总被引:1,自引:1,他引:0  
鉴于目前使用的阳离子乳化沥青粘附性试验方法难以有效评价复合乳化沥青粘附性,通过试验研究并综合考虑乳化沥青施工和路用实际情况,提出了乳化沥青水煮法试验方法和采用该方法检验复合乳化沥青粘附性时的评定标准。  相似文献   
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新型高温高密度W/O乳化钻井液的研制   总被引:1,自引:0,他引:1  
王松 《断块油气田》2002,9(6):64-66
研制了油包水乳化钻井液的基本配方,评价了其抑制性,热稳定性,以及抗水侵污能力,抗钻屑侵污能力,抗水泥侵污能力。现场应用表明,该体系具有较强的抑制作用,能很好地稳定井壁,保护油气层。  相似文献   
29.
NBR/PP热塑性弹性体研究进展   总被引:12,自引:0,他引:12  
阐述了NBR/PP共混热塑性弹性体动态硫化胶的国内外研究进展、微观相态结构、性能、应用及展望。  相似文献   
30.
环氧化天然橡胶改性软质聚氯乙烯的研究   总被引:1,自引:0,他引:1  
对环氧化度为50%的环氧化天然橡胶(ENR-50)改性软质聚氯乙烯(PVC)体系的性能进行了研究,并用动态力学和电镜分析了PVC与ENR-50的相容性。结果表明:适量的ENR-50可明显改善软质PVC的性能,而且PVC的相对分子质量越大,PVC/ENR-50共混材料的性能越好。虽然DMA测试PVC/ENR-50共混材料只有1个玻璃化转变温度(Tg),但在微观上并不完全相容。  相似文献   
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