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101.
Gradient-corrected density functional theory was used to investigate the adsorption of H2S on Pd(1 1 1) surface. Molecular adsorption was found to be stable with H2S binding preferentially at top sites. In addition, the adsorption of other S moieties (SH and S) was investigated. SH and S were found to be preferentially bind at the bridge and fcc sites, respectively. The reaction pathways and energy profiles for H2S decomposition giving rise to adsorbed S and H were determined. Both H2S(ad) → SH(ad) + H(ad) and SH(ad) → S(ad) + H(ad) reactions were found to have low barriers and high exothermicities. This reveals that the decomposition of H2S on Pd(1 1 1) surface is a facile process. 相似文献
102.
William Kent 《Computer Standards & Interfaces》1991,13(1-3):201-206
OSQL is the object-oriented database language developed for the Iris object-oriented database management system at Hewlett-Packard Laboratories. Its three fundamental constructs are objects, types, and functions. This paper provides an overview of the underlying concepts and some important features of OSQL. 相似文献
103.
Synthesis and properties of polystyrene/graphite nanocomposites 总被引:3,自引:0,他引:3
In this paper, graphite/polystyrene nanocomposite is synthesized by in situ polymerization of styrene in a tetrahydrofuran (THF) solution system of potassium (K)-THF-graphite intercalation compound (GIC). K-THF-GIC has proved to initiate polymerization of styrene by the anionic mechanism. Due to the interfacial interaction between the graphite nanolayers and the polymer, the composites exhibit higher glass transition temperature and higher thermal stability when compared to polystyrene. The percolation threshold in the conductivity of the composites is lesser than 8.2 wt% and the dielectric constant can reach as high as 136. 相似文献
104.
Vinh Q. Nguyen Jas S. Sanghera Brian Cole Pablo Pureza Frederic H. Kung Ishwar D. Aggarwal 《Journal of the American Ceramic Society》2002,85(8):2056-2058
Arsenic sulfide glass optical fibers typically possess extrinsic absorption bands in the infrared wavelength region associated with residual hydrogen and oxygen related impurities, despite using purified precursors. We report a purification process based on the addition of tellurium tetrachloride (TeCl4 ) to the glass. During melting, the chlorine from TeCl4 reacts with the hydrogen impurities to produce volatile products (e.g., HCl) that can be removed by subsequent dynamic distillation. The processing conditions have been modified accordingly to produce optical fibers with significantly reduced loss due to hydrogen sulfide impurity content (1.5 dB/m). 相似文献
105.
106.
Jose Ivan Escalante-Garcia Victor M. Palacios-Villanueva Alexander V. Gorokhovsky Guillermo Mendoza-Suárez Antonio F. Fuentes 《Journal of the American Ceramic Society》2002,85(7):1788-1792
Mortars of blast furnace slag blended with a geothermal silica waste at various replacement levels of 0%, 5%, 10%, 15%, and 20% were cured for up to 90 days. The binder was activated by 6 wt% Na2 O equivalent of sodium hydroxide. Lime was added as an activating agent and also to promote pozzolanic reaction with the silica. It was found that the presence of the silica waste increased the reactivity of the cementitious materials, as measured by means of nonevaporable water. The compressive strength was increased in the presence of the silica, except at the highest replacement level of 20%, the optimum silica replacement was that of 5%–10%. The microstructures of blended slag showed less porosity than those of neat slag mortars. The lime was completely consumed after 90 days of hydration. 相似文献
107.
108.
The LiPO3-Y(PO3)3 system has been studied for the first time. Microdifferential thermal analysis (μ-DTA), infrared spectroscopy (IR) and X-ray diffraction were used to investigate the liquidus and solidus relations. The only new compound observed within this system is LiY(PO3)4, melting incongruently at 1104 K. An eutectic appears at 4±1 mol% Y(PO3)3 at 933 K. LiY(PO3)4 crystallizes in the monoclinic system C2/c with a unit cell: a=16.201(4) Å, b=7.013(2) Å, c=9.573(2) Å, β=125.589(9)°, Z=4 and V=884.5 Å3, which is isostructural to LiNd(PO3)4. The infrared absorption spectrum indicates that this salt is a chain polyphosphate. 相似文献
109.
WANG Jiqing 《声学技术》2004,23(Z3)
This paper gives an overview of the research at Institute of Acoustics, Tongji University, on functional absorbers and experience acquired in practical applications over the past three decades. Experiments and analysis of the absorption characteristics of three different geometrical forms of functional absorbers, i.e., panels, cubes and tubes, were conducted with different arrangements. The resulting esthetical effects are illustrated with pictures. Several non-fiber materials are used to compose functional absorbers with advantages both in acoustic properties and in architectural features. Cost effectiveness analysis is also given in order to provide design guidelines. 相似文献
110.
An ab initio study using the local spin density approximation of the electronic and optical properties of materials where Cr transition metal substitutes for N in the GaN host semiconductor with an atomic concentration of 1.56% is presented. This material, characterized by an isolated and partially filled intermediate band, is a candidate for high-efficiency solar cells. The atomic and orbital composition of this band has been analyzed showing that is mainly made up of a t-group orbital of the transition metal. The absorption coefficient theoretical results show a sub-gap absorption with respect to the host semiconductor which could lead to an increase in solar conversion efficiency. 相似文献