Determination of the solubility parameter of poly(ethylene oxide) at 25°C by gas-liquid chromatography

The solubility parameter of poly(ethylene oxide) at 25°C has been determined using the method developed by DiPaola-Baranyi and Guillet, by the extrapolation of the values of the interaction parameter χ, at high temperatures, ranging from 70°–90°, 90°–110° and 110°–130°C down to 25°C. The values of the solubility parameter obtained, depending on the temperature ranges employed, are 9.8, 9.9 and 10.1, respectively.     

纤维素/聚乙二醇/维生素共混膜的制备与缓释性能研究

介绍了在纤维素/聚乙二醇体系中加入维生素C制备成药物缓释膜的过程,并研究了其在水中的药物缓释性能。结果表明,固液比、pH和温度这三个条件都对药物缓释有非常明显的影响。例如,药物在中性条件下的缓释一般是随着固液比的增大和温度的升高而加快的,但在高分子材料的结晶温度区域进行时也受到抑制。此外,在酸性环境中药物缓释在初始时是受到抑制而后逐渐以脉冲式进行。值得指出的是,药物缓释在碱性条件下完全不发生,并出现与缓释相反的吸附现象。     

Direct ethoxylation of fatty methyl ester over Al-Mg composite oxide catalyst

For the purpose of estimating the reaction mechanism of the direct ethoxylation of a fatty ester in the presence of an Al-Mg composite oxide catalyst, a labeled fatty methyl ester C₁₁H₂₃CO¹⁸OCH₃ containing ¹⁸O isotope was synthesized and directly ethoxylated. The product was evaluated by gas chromatography-mass spectrometry (GC-MS). The GC-MS spectra showed that the ¹⁸O isotope label was present only in the methoxy group at the molecular end of the ethoxylated fatty methyl ester. This supports the reaction mechanism of coordination anionic polymerization where the bond between the acyl and methoxy groups of the fatty methyl ester molecule was broken, caused by the bifunctional effect of the acid-base active sites; an intermediate chemisorption species was formed; and then ethylene oxide was addition-polymerized sequentially, in parallel.     

一种高度炼化一体化的乙烯发展方案

简要介绍了三种炼化一体化新技术,由此提出了一种高度炼化一体化的乙烯发展方案,与常规的炼化一体化方案进行了对比分析,表明该方案的乙烯原料更加优质且轻质化,其丙烯/乙烯比可达1.1以上。     

Study of secondary relaxations of poly(ethylene terephthalate) by photoluminescence technique

The α and β relaxation processes in two types of poly(ethylene terephthalate) with different degrees of crystallinity were studied by means of three methods, differential scanning calorimetry, dynamic-mechanical analysis and fluorescence spectroscopy. Information provided is complementary in the mean that every method sense phenomena that may occur at different times and length scales. Several probes, Coumarin 152 (C152), Coumarin 153 (C153), Coumarin 337 (C337) and 4′-dimethylamino-4-nitrostilbene (DMANS), were adsorbed in polymer films, and their fluorescence analysed over the temperature range from −150 to 150 °C. In general, a decrease in fluorescence intensity of probes as temperature increase was observed. This behaviour has been explained as a consequence of the enhancement of the free volume fraction that favoured the radiationless process of the lowest excited singlet state. Plots of fluorescence intensity versus temperature showed changes around the secondary relaxation temperatures. Therefore, good correlations between fluorescence and dynamic mechanical and calorimetric analysis were established. The obtained results indicated that the fluorescence from the probes incorporated to the material was dependent on the crystallinity of polymer. It would indicate that the fluorescence emission from those probes can be used to analyse annealing processes in semicrystalline polymers.     

IIR/EPDM共混物的物理机械性能

研究了IIR／EPDM并用体系中共混比、硫磺硫化体系以对共混性能的影响。结果表明，IIR与EPDM相容性较好，而且可以达到共硫化；IIR。EPDM质量比为75／25时，共混物的物理机械性能和老化性能较好；用硫黄、低硫高促进剂和无硫硫化体系都得到性能良好的共混物，其中以前者硫化的共混物性能最为突出。     

SO4^2-／MxOy固体超强酸催化合成1，4-二氧六环

以乙二醇为原料,采用颗粒型SO4^2-／MxOy固体超强酸倦化剂，在常压、气相条件下,固定床催化合成了1。4-二氧六环；同时考察了不同反应温度、原料配比、进料速度等条件对催化反应的影响．并对上述影响因素进行了探讨。产品经气相色谱，红外光谱及质谱分析。结果表明。原料在260℃温度条件下，以进料流速为0．12mL／min为最佳反应条件。在该实验条件下，1。4-二氧六环的生成产率达到60％-70％左右。该合成工艺应用固体超强酸催化剂具有较高的催化活性、化学稳定性好、无环境污染。是工业生产1，4-二氧六环较理想方法，具有良好的工业生产前景。     

对我国乙烯工业发展的几点思考

阐述了世界乙烯工业现状、发展特点以及新型工艺技术分析，重点对我国乙烯工业总体发展水平、生产、消费、进出口贸易作了详细的讨论。在此基础上对我国乙烯工业发展方向、方式和规划提出了建议。     

环氧乙烷及其精深加工产业现状与发展

综述了过去3年来国内外环氧乙烷生产及其精深加工产业现状和发展趋势,并初步探讨了我国今后环氧乙烷及其精深加工产业的发展趋势。     

PET/MFMB复合材料的力学性能、热性能的研究

用力学性能测定、DSC和熔体流动速率（MFR）测定法研究聚对苯二甲酸乙二酯／多功能母料（PET／MFMB）复合材料的力学性能和热性能。结果表明，当MFMB的含量为22％时，PET／MFMB复合材料的冲击强度、断裂伸长率分别出现极大值；复合材料中PET、PP的熔点比纯PET、纯PP的稍有降低，当PET／MFMB＝78／22时降低的幅度稍大；复合材料的MFR在PET／MFMB＝78／22时出现转变点。