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81.
82.
A novel mixed‐mode expanded bed adsorbent with anion‐exchange properties was explored with benzylamine as the functional ligand. The cellulose composite matrix, densified with stainless steel powder, was prepared with the method of water‐in‐oil suspension thermal regeneration. High activation levels of the cellulose matrix were obtained with allyl bromide because of the relative inertness of the allyl group under the conditions of the activation reaction. After the formation of the bromohydrin with N‐bromosuccinimide and coupling with benzylamine, the activated matrix was derived to function as a mixed‐mode adsorbent containing both hydrophobic and ionic groups. The protein adsorption capacity was investigated with bovine serum albumin as a model protein. The results indicated that the prepared adsorbent could bind bovine serum albumin with a high adsorption capacity, and it showed salt tolerance. Effective desorption was achieved by a pH adjustment across the isoelectric point of the protein. The interactions between the cell and adsorbent were studied, and the bioadhesion was shielded by the adjustment of the salt concentration above 0.1M. Stable fluidization in the expanded bed was obtained even in a 2% (dry weight) yeast suspension. The direct capture of target proteins from a biomass‐containing feedstock without extra dilution steps could be expected with the mixed‐mode adsorbent prepared in this work, and this would be especially appropriate for expanded bed adsorption applications. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2008 相似文献
83.
聚合物凝胶用Cr3+交联剂检测方法探讨 总被引:4,自引:1,他引:3
胜利油田交联聚合物驱、封堵大孔道中使用Cr3+交联的HPAM凝胶。探讨了Cr3+交联剂的检测方法。将4种商品HPAM和6种商品Cr3+交联剂在矿化度5727mg/L、钙镁含量108mg/L的胜利盐水中配制成24个HPAM/Cr3+成胶溶液,根据70℃下反应72h后在70℃测定的凝胶相对强度(要求在代码C以上),确定使用分子量1.11×107、水解度28.8%的一种HPAM,配液浓度为1300mg/L。推荐采用在70℃、振荡频率f=0.422s-1测定的复数粘度η 和储能模量G′表示凝胶的强度,给出了HPAM浓度不同、各Cr3+交联剂浓度为最低需要量的6种凝胶的η 和G′值;推荐取G′值达到0.1Pa的时间为成胶时间,由上述6种体系的G′ t曲线求出成胶时间在98~300min范围。提出其他应测定的性能包括:成胶溶液抗剪切性,凝胶热稳定性(抗热老化性),凝胶抗温性,凝胶抗盐性及岩心堵水率,对测定方法作了详略不等的讨论。特别指出,用于热老化实验的成胶溶液必须彻底除氧,否则粘时曲线的变化将无规律(给出了实例)。图7表7参3。 相似文献
84.
Eleonora M. Ungureanu Liviu Birzan George Buica Enache Cristian 《Electrochimica acta》2006,52(3):794-803
The cyclic voltammetry behavior of a series of five 1-substituted azulenes has been investigated as well as the electrochemical chlorination of these compounds. In the case of azulene compounds containing electron withdrawing groups which have higher oxidation potentials than that of the chloride ion, the electrochemical chlorination led usually to 3-chloro derivatives. The electrochemical chlorination fails for azulenes with lower oxidation potentials. Additionally some polyhalogenated compounds were obtained by controlled potential electrolyses. The paper also discusses the reaction mechanism of the electrochemical halogenation of 1-substituted azulenes. 相似文献
85.
Min-Max MPC (MMMPC) controllers [P.J. Campo, M. Morari, Robust model predictive control, in: Proc. American Control Conference, June 10–12, 1987, pp. 1021–1026] suffer from a great computational burden which limits their applicability in the industry. Sometimes upper bounds of the worst possible case of a performance index have been used to reduce the computational burden. This paper proposes a computationally efficient MMMPC control strategy in which the worst case cost is approximated by an upper bound based on a diagonalization scheme. The upper bound can be computed with O(n3) operations and using only simple matrix operations. This implies that the algorithm can be coded easily even in non-mathematical oriented programming languages such as those found in industrial embedded control hardware. A simulation example is given in the paper. 相似文献
86.
The broadband integrated services digital networks (B-ISDN) based on asynchronous transfer mode (ATM) technology can support
a wide range of applications such as voice, video, still images, and data. Compression techniques increase the effective bandwidth
utilization, but the bursty and asynchronous nature of the traffic can still lead to congestion in the network, and degradation
of image quality and quality of service (QOS). Some of the features to provide better coding schemes for ATM networks are
layered coding, resynchronization, buffering, interleaved schemes, constrained bit rate due to buffers, encapsulation with
the RTP or AAL1 for clock recovery, lapped transforms, motion compensation, and optimal bit allocation for coders based on
wavelet transforms. We review various techniques forimage and video coding such as transforms, motion compensation, vector
quantization, and subband coding. We outline the impact of the cell loss ratio (CLR), delay and cell delay variation (CDV)
on video coding: blocking effects, loss of frame synchronization, motion vectors, and vector quantization codewords. The open
problems include tuning coding parameters to the available QOS provided by the network. 相似文献
87.
The interactions of VOHPO4· 0.5H2O and (VO)2P2O7 with the ammoxidation feed and the single components such as ammonia, oxygen, water and component mixtures were studied in detail using XRD and temperature-programmed reaction spectroscopy. The aim of this work was to improve the knowledge of the formation of the active phases or active sites of the catalysts from their precursors under the condition of the ammoxidation reaction. Similar catalytic properties of various applied VPO materials were discussed in terms of the presence of similar structure elements (domains of adjacent edge-sharing VO6 octahedra-units and P-O-NH4 groups). 相似文献
88.
强韧包装纸板用落叶松半化学浆的研究 总被引:1,自引:0,他引:1
主要研究一种可以替代传统硫酸盐化学木浆,来生产强韧包装纸板或瓦楞纸箱箱板纸的落叶松碱性亚硫酸盐-蒽醌半化学浆。这种采用碱性亚硫酸盐添加蒽醌助剂的制浆方法研制的落叶松半化学浆,当纸浆得率为56.9%时,在低打浆度情况下纸浆强度性能可以达到我国2号未漂硫酸盐化学木浆的标准,而且有可能达到1号未漂硫酸盐化学木浆的标准,纸浆得率比落叶松硫酸盐木浆得率实际指标(43%)绝对值提高13%以上。用于制作强韧包装纸板或瓦楞纸箱箱板纸的落叶松碱性亚硫酸盐-蒽醌半化学浆,蒸煮终点宜于控制在得率约62%、卡伯值100左右。 相似文献
89.
重型血友病甲基因诊断新技术的研究及其应用 总被引:7,自引:1,他引:6
远用长距离DNA扩增技术成功地检测出凝血八因子FⅧ基因倒位缺陷患者,并检出该倒位的女性携带者。 相似文献
90.
The present work quantifies the relations between the structure of a chemical reaction kinetic model, its valid parameter range, and the truncation error tolerance of the model. General methods are presented to solve the three important problems of valid parameter range analysis: (1) identification of the valid parameter range of a kinetic model, (2) estimation of the error tolerance required when applying a kinetic model over a specified parameter range, and (3) improvement of existing model generation algorithms to construct more robust models. Finally, the relationship between a model's structure, its valid parameter range, and the truncation error tolerance are illustrated by the flexibility-tolerance-model graph. The new methods are applied to pyrolysis of methane/ethane mixtures. 相似文献