CARS光谱测温及仪器狭缝函数对测量的影响

设计了一种利用光参量振荡器(OPO)来代替染料激光器的宽带相干反斯托克斯喇曼散射(CARS)光谱测温实验装置。为了提高CARS测量温度的精度,测量和分析了检测系统中狭缝函数对测量结果的影响,确定了狭缝函数的具体形式。将测量结果与热电偶读数比较,发现在温度范围300K～1200K内,温度测量的不确定度小于2%。     

从头算法对甲基磺酸拉曼光谱振动频率指认

对液态的甲基磺酸进行了拉曼光谱测定。采取从头算法用各种不同的基组 (最大的基组为MP2 / 6 -311+G( 2d ,2 p) )对甲基磺酸的结构和光谱进行了计算 ,得到了甲基磺酸的结构参数及稳定构象信息。采用一个具有Ci 对称的二聚体模型解释了甲基磺酸的液态光谱。对单体和二聚体的甲基磺酸进行了简正坐标计算 ,结果表明二聚体结构是液态甲基磺酸聚积态分子的合理模型。     

CVD金刚石膜生长过程的Raman分析

采用激光Raman散射分析法对CVD金刚石膜的生长过程进行研究 ,讨论在金刚石膜生长的不同阶段 ,膜内金刚石和非金刚石成分的相对含量及其残余应力的变化情况     

宽带抽运情况下乙醇、丙酮溶液中受激拉曼散射光谱的实验研究

研究了乙醇、丙酮两种拉曼介质在宽带抽运情况下啁啾激光脉冲的受激拉曼散射频谱特性 ,得到的一级Stokes光频谱宽度与抽运光基本相当 ,且具有较高的转换效率 ,从而表明了利用“展宽—受激拉曼散射—压缩”的办法获得波长近 1μm的飞秒级超短脉冲激光信号源的实验方案具有可行性     

用于测量空间温度场的分布式光纤传感器的系统设计

文中首先介绍了喇曼散射，并对分布式光纤温度传感器进行了理论分析，最后着重介绍我们研制的一种能够实际使用的喇曼散射分布式光纤温度传感器系统的设计和应用。     

光泵腔式远红外激光器的工作参数研究

在研究光泵腔式NH3分子远红外激光频谱特性的基础上，应用量子系统的密度矩阵理论，采用迭代法和增益迭加原理计算了以TEA CO2－10R（8）泵浦的NH3分子腔式远红外激光器的最佳工作参数。提供了光泵腔式NH3分子远红外激光器（腔式NH3－OPFIRL）的工作参数之间的关系曲线。     

Films and fibers of oriented single wall nanotubes

As-produced nanotubes form a light, fragile and isotropic soot. Different efforts are made to process nanotubes into macroscopic forms of more practical use and more controlled properties. We briefly review in this paper two methods recently proposed to make films of magnetically aligned nanotubes and fibers by using an electrophoretic method. Preferential orientation of the nanotubes in the plane of the films or along the fiber axis is an important feature of the obtained materials. Then we describe in details a different, spinning like, process for making fibers out of single wall carbon nanotubes. This process consists of dispersing the nanotubes in a surfactant solution, re-condensing the nanotubes in the flow of a polymer solution to form a nanotube mesh, and then collating this mesh to a nanotube fiber. The behaviors of the surfactant-stabilized dispersions, which are also presented, are critical for this process. The degree of nanotubes alignment in dried fibers has been characterized by X-ray scattering. It is found to be smaller than the alignment obtained in the previous materials. However, the processing is simpler and faster and potentially scalable for large-scale production.     

Origin of visible photoluminescence from porous silicon as studied by Raman spectroscopy

In this paper we discuss the different models proposed to explain the visible luminescence in porous silicon (PS). We review our recent photoluminescence and Raman studies on PS as a function of different preparation conditions and isochronal thermal annealing. Our results can be explained by a hybrid model which incorporates both nanostructures for quantum confinement and silicon complexes (such as SiH _x and siloxene) and defects at Si/SiO₂ interfaces as luminescent centres.     

双光束Raman组束研究

着重研究了双光束拉曼组束改善准分子激光光束质量。通过理论计算得出，在畸变泵浦光作用下可以获得近衍射极限Ｓｔｏｋｅｓ光的放大。并在稳态和瞬态激光脉冲的条件下，讨论了Ｒａｍａｎ工作介质的选择。在此基础上进行了氯化氙准分子激光在氢气中的双光束Ｒａｍａｎ组束实验研究，近衍射极限Ｓｔｏｋｅｓ光在获得功率放大的同时，其远场分布保持不变。激光聚焦亮度提高约３０００倍。最后讨论了放大自发辐射的抑制。