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101.
Renewable propane-1,2,3-triyl tris(9-(oxiran-2-yl) nonanoate) (EGU, 100 wt% biogenic) and a tricarboxylic acid triglyceride (CGTU) hardener (85.7 wt% biogenic) were synthesized from 10-undecenoic acid (10-UDA) and used to produce epoxy resins with 52–92 wt% biobased carbon. CGTU was prepared by thermally activated thiol-ene coupling of thioglycolic acid onto propane-1,2,3-triyl tris(undec-10-enoate), (GUD) in the absence of solvent. The characterized CGTU was used as a green hardener of blends based on EGU and a conventional bisphenol A-based epoxy pre-polymer (DGEBA) at various mass percentages (0–100 wt%) with an stoichiometric epoxy/acid equivalent ratio. Calorimetric studies revealed higher peak temperature, lower reaction heats, and longer gelation times in resins with high EGU proportion, evidencing the lower reactivity of aliphatic EGU compared with aromatic DGEBA. Cured resins were yellowish transparent rubber-like materials with glass transition temperatures (Tg) varying from −14 °C to −42 °C and tensile strength in the range of 1750 kPa–790 kPa, for 0 and 100 wt % EGU, respectively. The soluble fraction of all resins was less than 4.3%, reflecting a high level of crosslinking. Thermosets with high biobased content showed both UV-light protection and visible light transparency. 相似文献
102.
The objective of this research work was to investigate the kinetics of esterification of acetic acid with n-butanol through the variation of experimental parameters. The reaction mixture was catalyzed heterogeneously by a sulfonated catalyst in batch mode of operation. The catalyst was prepared from abundantly available agro-waste, Cajanus cajan husk by chemical activation process, which produces a carbon-based solid catalyst with high surface area. The catalyst was characterized by a Brunauer-Emmet-Teller surface analyzer and Fourier transform infrared spectroscopy to know the surface morphology. Process parameters such as contact time, reaction temperature, and catalyst loading, which can influence the extent of conversion of reactants, were studied. Furthermore, the kinetic investigation was also carried out to estimate the kinetic parameters for uncatalyzed and catalyzed reaction using the second-order pseudo-homogeneous (P-H), Eley-Rideal (E-R), and Langmuir-Hinshelwood (LH) kinetic models for this research work. The kinetic parameters such as activation energy, preexponential factor, and the thermodynamic parameters such as enthalpy and entropy were estimated for uncatalyzed and catalyzed reactions using these three models. The process conditions were optimized for catalyzed and uncatalyzed reactions to obtain the maximum product yield by minimizing root mean square error of each experimental data using the MS-excel solver tool. Thus, this study reveals the high potential of an agro-waste, Cajanus cajan husk as raw material for the synthesis of catalyst. The results show that the E-R model is more appropriate for predicting the dynamic data of an esterification reaction, as the forward rate of reaction estimated using the E-R model are more modified than P-H and L-H models. 相似文献
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Brian Dillman Julie L. P. Jessop 《Journal of polymer science. Part A, Polymer chemistry》2013,51(9):2058-2067
The effects of chain transfer agents (CTA) on cationic ring‐opening polymerization of 3,4‐epoxycyclohexylmethyl‐3′,4′‐epoxycyclohexane carboxylate (EEC) were explored. EEC was polymerized in the presence of various CTAs, and epoxide conversions monitored via Raman spectroscopy. Polymer films were prepared and analyzed by dynamic mechanical analysis. Many of the organic alcohols studied greatly enhanced epoxide polymerization rates and conversion levels. The gel fraction of polymer specimens decreased rapidly with increasing amounts of octanol (gel fraction >90% up to 0.3 equiv OH) but remained high with increasing amounts of 1,2‐propanediol (gel fraction >90% up to 0.6 equiv OH). Increasing the size of primary alcohols had little effect on the polymerization rates and conversions. The polymerization rate decreased with increasing alcohol substitution (1°>2°>3°). Acidic alcohols had very low impact on conversion and polymerization rates relative to the neat epoxy resin. The glass transition temperature was inversely related to the size and amount of CTA. © 2013 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2013 相似文献
105.
《中国化学会会志》2017,64(7):786-794
Catalytic oxidation of renewable furfural into valuable maleic acid in aqueous solutions using metalloporphyrin catalysts was investigated for the first time. The synthesized catalysts were characterized by FT‐IR , UV –vis, 1H NMR , elemental analysis, and TGA . The catalysts varied in metal active sites and functional groups, which had different effects on their catalytic activity. Furthermore, the effects of temperatures, reaction time, catalyst loading, and oxygen pressure were studied in detail. Maleic acid could be achieved in 44% yield by using FeT (p‐Cl)PPCl as catalyst under optimal conditions. Finally, FeT (p‐Cl)PPCl could be reused in five consecutive runs without a significant loss of activity. 相似文献
106.
A new polymer acceptor containing naphthalene diimide and 1,3,4‐thiadiazole for all‐polymer solar cells 下载免费PDF全文
Zhiguo Zhang Zhaoxia Liu Songting Tan Yongfang Li 《Journal of Polymer Science.Polymer Physics》2017,55(13):990-996
A n‐type conjugated polymer containing naphthalene diimide (NDI) and 1,3,4‐thiadiazole (TZ) moieties, named PNTZ, has been synthesized and applied for all‐polymer solar cells (all‐PSCs). By the incorporation of TZ unit into the polymer main chains, the lowest unoccupied molecular orbital level of this polymer has been adjusted effectively. In addition, the electron‐acceptor PNTZ shows a broad absorption spectrum in the range of 300–700 nm, and possesses complementary absorption spectrum with the electron‐donor PTB7‐Th. On the basis of PNTZ as the acceptor and PTB7‐Th as the donor, the all‐PSCs are fabricated. After optimization, the well blend morphologies with a continuous D/A interpenetrating network are observed and the best all‐PSC device exhibits a power conversion efficiency of 4.35% with a high short‐circuit current density of 13.26 mA cm?2. This research demonstrates that the TZ‐containing polymer PNTZ is a promising non‐fullerene acceptor for high efficiency all‐PSCs. © 2017 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2017 , 55 , 990–996 相似文献
107.
《Angewandte Chemie (International ed. in English)》2017,56(40):12064-12084
Magnesium metal is a superior anode which has double the volumetric capacity of lithium metal and has a negative reduction potential of −2.37 V vs. the standard hydrogen electrode. A major benefit of magnesium is the apparent lack of dendrite formation during charging which is one of the crucial concerns of using a lithium metal anode. In this Review, we highlight the foremost research in the development of electrolytes and cathodes and discuss some of the significant challenges which must be overcome in realizing a practical magnesium battery. 相似文献
108.
Song-Bai Yu Hong-Jun Zang Xiao-Li Yang Ming-Chuan Zhang Rui-Rui Xie Pei-Fei Yu 《中国化学快报》2017,28(7):1479-1484
Several types of ILs and solid acids were used as catalysts in one-pot conversion of sucrose to 5-hydroxymethylfurfural (abbreviated as 5-HMF) in a dimethyl sulfoxide (DMSO)/water mixed solvent under hydrothermal conditions. A remarkable 5-HMF yield of 91.8% was achieved catalyzed by the cesium salt of dodecatungstophosphoric acid (Cs2.3H0.7PW12O40) within 3 h at 180 ℃. The ionic liquid N-methylimidazolium hydrogen sulfate ([Hmim][HSO4]) gave the 5-HMF in 82.0% yield from sucrose. To the best of our knowledge, it was almost the highest yield of HMF from sucrose by now. Various reaction parameters including reaction temperature and time and catalyst dosage were optimized. A possible mechanism for this catalytic process was proposed. Furthermore, fructose and glucose were also investigated, good yields of 5-HMF was obtained respectively. This increases the possibility of large-scale production of 5-HMF from carbohydrates. 相似文献
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