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71.
Matthaios P. Kavvalakis Manolis N. Tzatzarakis Eleftheria P. Theodoropoulou Emmanouil G. Barbounis Andreas K. Tsakalof Aristidis M. Tsatsakis 《Chemosphere》2013
Imidacloprid (IMI) is a relatively new neuro-active neonicotinoid insecticide and nowadays one of the largest selling insecticides worldwide. In the present study a LC–APCI–MS based method was developed and validated for the quantification of imidacloprid and its main metabolite 6-chloronicotinic acid (6-CINA) in urine and hair specimens. The method was tested in biomonitoring of intentionally exposed animals and subsequently applied for biomonitoring of Cretan urban and rural population. 相似文献
72.
Degassing of H/He, CFCs and SF6 by denitrification: Measurements and two-phase transport simulations
Ate Visser Joris D. Schaap Hans Peter Broers Marc F.P. Bierkens 《Journal of contaminant hydrology》2009,103(3-4):206-218
The production of N2 gas by denitrification may lead to the appearance of a gas phase below the water table prohibiting the conservative transport of tracer gases required for groundwater dating. We used a two-phase flow and transport model (STOMP) to study the reliability of 3H/3He, CFCs and SF6 as groundwater age tracers under agricultural land where denitrification causes degassing. We were able to reproduce the amount of degassing (R2 = 69%), as well as the 3H (R2 = 79%) and 3He (R2 = 76%) concentrations observed in a 3H/3He data set using simple 2D models. We found that the TDG correction of the 3H/3He age overestimated the control 3He/3He age by 2.1 years, due to the accumulation of 3He in the gas phase. The total uncertainty of degassed 3H/3He ages of 6 years (± 2 σ) is due to the correction of degassed 3He using the TDG method, but also due to the travel time in the unsaturated zone and the diffusion of bomb peak 3He. CFCs appear to be subject to significant degradation in anoxic groundwater and SF6 is highly susceptible to degassing. We conclude that 3H/3He is the most reliable method to date degassed groundwater and that two-phase flow models such as STOMP are useful tools to assist in the interpretation of degassed groundwater age tracer data. 相似文献
73.
摘要以镁盐、铝盐、纯碱和烧碱为原料制备了一种多孔镁铝复合氧化物(P—Mg3.1AlO4.6),其比表面积、平均孔径和总孔容分别为206.3m2/g、8.961nm和0.4208cm3/g。研究了这种多孑L材料对水溶液中cr(VI)的吸附性能,在25~45qC时,静态吸附量为82.32~141.7mg/g;当初始浓度100mg/L、流速5mL/min、床层高度10cm和pH=6时,半穿透时间、半穿透吸附量和饱和吸附量分别为406rain、49.28ing/g和51.30Ing/g;拟合参数及误差分析表明,cr(Ⅵ)在P—M敬。AIO4.6上的静态吸附过程符合Freundlich等温方程式和伪二级动力学方程,Yoon·Nelson模型能很好地预测cr(Ⅵ)在P—Mg3.1A104.6上的动态穿透曲线。 相似文献
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S. Cavani C. Perfumo F. Faravelli M. Malacarne M. Sogliani G. Piombo G. Zerega M. Zucca F. Dagna Bricarelli M. Pierluigi 《黑龙江环境通报》2003,23(10):819-823
Here we describe a foetus with intrauterine growth retardation (IUGR), cerebral malformations and a 46,XY,der(1),t(1;6)(p36.3;q25.2) karyotype owing to a familial cryptic translocation segregating in three generations. A balanced translocation was present in the mother, the maternal uncle, the aunt and the grandmother. A female first cousin with dysmorphisms, hydrocephalus and mental retardation was a carrier of a partial trisomy 1p and a partial monosomy 6q. Multiple miscarriages were present in the family pedigree. Parents of the foetus had three other pregnancies: a male with a balanced translocation, and two foetuses with 1p36.3–pter monosomy and 6q25.2–qter trisomy. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
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为了提高人造沸石对地下水中铬(Ⅵ)的去除能力,采用氯化铝对人造沸石进行改性。确定最佳改性条件:20%氯化铝溶液,液固比12 mL/g,室温下以180 r/min振荡改性8 h;最佳除Cr(Ⅵ)条件:pH值为4~8,液固比为33.3 mL/g,室温下水浴恒温振荡2 h。改性沸石对铬(Ⅵ)的吸附符合Langmuir及Freundlich等温线方程,由Langmuir吸附等温线可得其吸附容量为5.624 mg/g。在最佳反应条件下,水样中铬(Ⅵ)浓度可由5 mg/L下降到0.026 mg/L,低于0.05 mg/L,满足GB/T 14848—93《地下水环境质量标准》Ⅲ类标准。 相似文献
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双表面活性剂修饰下纳米零价铁对水中Cr(Ⅵ)污染去除研究 总被引:1,自引:0,他引:1
为解决纳米级零价铁(nZVI)在环境中易团聚、易氧化的问题,强化其去除水中Cr(VI)的能力,选择非离子型表面活性剂聚乙烯吡咯烷酮(PVP)和阴离子表面活性剂油酸钠(NaOA)同时对nZVI进行修饰.同时,通过对比不同pH值、材料干湿状态、初始浓度及共存离子条件下的反应效果,结合材料的XRD和XPS表征、动力学实验和25℃等温线的拟合进行机理分析.结果表明:酸性条件有利于Cr(VI)的去除;材料的干湿状态对去除效率影响较大;材料去除水中Cr(VI)可在3 h内达到反应平衡,去除效率在90%以上,实验条件下最大去除量为183.1 mg·g-1,反应过程符合准二级动力学模型及Langmuir模型;反应过程中Cr(VI)大部分转化为Cr(Ⅲ). 相似文献